The hydrothermal synthesis of AlPO4-n which is a functional material of aluminophosphate, was conducted from two kinds of aluminum dross discharged in an aluminum regeneration factory. The effect of structure-directing agent (SDA) on the formation behavior of AlPO4-n from aluminum dross, the suitable condition to obtain AlPO4-n efficiently, and the pore structure and gas adsorption property were investigated in this study.AlPO4-5 and AlPO4-34 are mainly formed from aluminum dross as a raw material, and it is possible to make AlPO4-5 successfully as a main product by adjusting the amount of triethylamine (TEA) as SDA. The gas adsorption amount with AlPO4-5 is the following order; ammonia > dipropylamine > benzene, and it is found that this order mainly corresponds with the polarity of molecule among them. 相似文献
Abstract: A genetical relationship between skarn formation and mineralization is investigated for the Kamioka skarn deposits which are the largest Zn-Pb producer in Japan. In the Mozumi deposit, one of main deposits in the Kamioka mining area as well as Tochibora and Maruyama, clinopyroxene skarn was generally subjected to later replacement by garnet or magnetite–calcite–quartz during the Zn-Pb mineralization. The replacement of hedenbergitic clinopyroxene by andraditic garnet resulted in the formation of diopsidic clinopyroxene relicts. With the progress of replacement, the S/So value (So: an estimated area occupied by an original clinopyroxene grain in a thin section, S: a total area of relict clinopyroxene fragments) which is an index of the degree of replacement decreases from 0. 7 to 0. 1, and the hedenbergite mole percent of relict clinopyroxene decreases drastically from about 65 to less than 40. A close association of andraditic garnet and sphalerite suggests that heden-bergitic clinopyroxene skarn played an important role to reduce the relatively oxic ore-forming fluid enriched in Zn2+ and SO42– and to precipitate sphalerite from the fluid. Ferrous iron in the hedenbergitic clinopyroxene skarn was oxidized to form andraditic garnet. Besides this garnet formation, the mineral assemblage of magnetite–calcite–quartz replaced the clinopyroxene skarn at the time of mineralization. In both cases, the reduction of relatively oxic ore-forming fluid by hedenbergitic clinopy-roxene skarn at the later stage brought about the precipitation of sulfide minerals. In contrast, these types of later replacement are not found in the Tochibora deposit. Instead, graphite-bearing crystalline limestone and relatively fresh clinopyroxene skarn are common. Mineralized clinopyroxene skarn has high graphite carbon contents relative to barren one, suggesting that the amount of graphite in the skarn was an important controlling factor for mineralization. It is very likely that the graphite played a role of reducing agent during the mineralization in the Tochibora deposit. 相似文献
The objective of the present paper is to show that groundwater is a general geologic agent. This perception could not, and
did not, evolve until the system nature of basinal groundwater flow and its properties, geometries, and controlling factors
became recognized and understood through the 1960s and 1970s.
The two fundamental causes for groundwater's active role in nature are its ability to interact with the ambient environment
and the systematized spatial distribution of its flow. Interaction and flow occur simultaneously at all scales of space and
time, although at correspondingly varying rates and intensities. Thus, effects of groundwater flow are created from the land
surface to the greatest depths of the porous parts of the Earth's crust, and from a day's length through geologic times. Three
main types of interaction between groundwater and environment are identified in this paper, with several special processes
for each one, namely: (1) Chemical interaction, with processes of dissolution, hydration, hydrolysis, oxidation-reduction,
attack by acids, chemical precipitation, base exchange, sulfate reduction, concentration, and ultrafiltration or osmosis;
(2) Physical interaction, with processes of lubrication and pore-pressure modification; and (3) Kinetic interaction, with
the transport processes of water, aqueous and nonaqueous matter, and heat. Owing to the transporting ability and spatial patterns
of basinal flow, the effects of interaction are cumulative and distributed according to the geometries of the flow systems.
The number and diversity of natural phenomena that are generated by groundwater flow are almost unlimited, due to the fact
that the relatively few basic types are modified by some or all of the three components of the hydrogeologic environment:
topography, geology, and climate. The six basic groups into which manifestations of groundwater flow have been divided are:
(1) Hydrology and hydraulics; (2) Chemistry and mineralogy; (3) Vegetation; (4) Soil and rock mechanics; (5) Geomorphology;
and (6) Transport and accumulation. Based on such a diversity of effects and manifestations, it is concluded that groundwater
is a general geologic agent.
Received, December 1998 · Revised, January 1999 · Accepted, January 1999 相似文献
Salinization is the process whereby the concentration of dissolved salts in water and soil is increased due to natural or
human-induced processes. Water is lost through one or any combination of four main mechanisms: evaporation, evapotranspiration,
hydrolysis, and leakage between aquifers. Salinity increases from catchment divides to the valley floors and in the direction
of groundwater flow. Salinization is explained by two main chemical models developed by the authors: weathering and deposition.
These models are in agreement with the weathering and depositional geological processes that have formed soils and overburden
in the catchments. Five soil-change processes in arid and semi-arid climates are associated with waterlogging and water. In
all represented cases, groundwater is the main geological agent for transmitting, accumulating, and discharging salt. At a
small catchment scale in South and Western Australia, water is lost through evapotranspiration and hydrolysis. Saline groundwater
flows along the beds of the streams and is accumulated in paleochannels, which act as a salt repository, and finally discharges
in lakes, where most of the saline groundwater is concentrated. In the hummocky terrains of the Northern Great Plains Region,
Canada and USA, the localized recharge and discharge scenarios cause salinization to occur mainly in depressions, in conjunction
with the formation of saline soils and seepages. On a regional scale within closed basins, this process can create playas
or saline lakes. In the continental aquifers of the rift basins of Sudan, salinity increases along the groundwater flow path
and forms a saline zone at the distal end. The saline zone in each rift forms a closed ridge, which coincides with the closed
trough of the groundwater-level map. The saline body or bodies were formed by evaporation coupled with alkaline-earth carbonate
precipitation and dissolution of capillary salts.
Received, May 1998 · Revised, July 1998 · Accepted, September 1998 相似文献
The potential of marble dust as a stabilizing additive to red tropical soils was evaluated. The evaluation involved the determination of the geotechnical properties of three different red tropical soils in their natural state as well as when mixed with varying proportions of marble dust. The parameters tested included the particle size distribution, specific gravity, Atterberg limits, the standard compaction characteristics, the compressive strength and the California bearing ratio (CBR). The strength tests were repeated after normal 28 day curing of the treated samples and also after accelerated 24 h curing at temperatures of 40°C, 60°C and 80°C.
Results showed that the geotechnical parameters of red tropical soils are improved substantially by the addition of marble dust; plasticity was reduced by 20 to 33% and strength and CBR increased by 30 to 46% and 27 to 55% respectively. The highest strength and CBR values were achieved at 8% marble dust. Results also showed that normal 28 day curing improved the strength of the marble dust-treated soil with over 80% strength gain achieved after 7 to 10 days of normal curing. Higher strength development was realised following accelerated 24 h curing at 60°C.
Although these results imply marked improvement in the geotechnical parameters of red tropical soils, the higher strength developed is not enough for the improved soil to be used as a base material in the construction of heavily trafficked flexible pavements. The improved material may, however, be successfully used as base material for lightly trafficked roads and as a sub-base material for heavily trafficked roads. 相似文献
On the basis of previous work, this paper designs an intelligent agent based on virtual geographic environment (VGE) system that is characterized by huge data, rapid computation, multi-user, multi-thread and intelligence and issues challenges to traditional GIS models and algorithms. The new advances in software and hardware technology lay a reliable basis for system design, development and application. 相似文献