H~+,Li~+,Mg~(2+)∥Cl~-—H_2O四元水盐体系在-10℃时的平衡溶解度相图     

王继顺  高世扬  刘铸唐  王波 《盐湖研究》1993,(2)

本文利用等温溶解度法测定了H~+,Li~+,Mg~(2+)//Cl~-—H_2O四元水盐体系在—10℃±0.1℃时的溶解度并绘制了等温相图。相图由HCl·MgCl_2·7H_2O、MgCl_2·8H_2O、HCl·6H_2O和LiCl·2H_2O四个相区构成,只有一个零变量点I:LiCl·2H_2O+MgCl_2·6H_2O+HCl·MgCl_2·7H_2O+L_(?)利用坐标变换和直线外推法,对溶解度数据进行处理后,用湿渣结线法解决了低温平衡固相较难确定的问题。  相似文献   

FTIR studies of reactions between the nitrate radical and haloethenes     

I. M. W. Noremsaune  J. Hjorth  C. J. Nielsen 《Journal of Atmospheric Chemistry》1995,21(3):223-250

Products and mechanisms for the gas-phase reactions of NO₃ radicals with CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂,cis-CHCl=CHCl andtrans-CHCl=CHCl in air have been studied. The experiments were carried out at 295±2 K and 740±5 Torr in a 480-L Teflon-coated reaction chamber and at 295±2 K and 760±5 Torr in a 250-L stainless steel reactor. NO₃ was generated by the thermal dissociation of N₂O₅. Experiments with¹⁵NO₃ and CD₂CDCl have also been performed. The initially formed nitrate peroxynitrates decay into carbonyl compounds, nitrates, HCl and ClNO₂. In adidtion, there are indications of nitrooxy acid chlorides being produced. The reactions with CH₂=CCl₂ and CHCl=CCl₂ are more complex due to release of chlorine atoms which eventually lead to formation of chloroacid chlorides.A general reaction mechanism is proposed and the observed concentration-time profiles of reactants and products are simulated for each compound. The rate constants for the initial step of NO₃ addition to the chloroethenes are determined as: (2.6±0.5, 9.4±0.9, 2.0±0.4 and 1.4±0.4) × 10^–16 cm³ molecule^–1 s^–1 for CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂ andcis-CHCl=CHCl, respectively.  相似文献   

Investigation of NaCl deliquescence in porous substrates using RH-XRD     

Kirsten Linnow  Herbert Juling  Michael Steiger 《Environmental Geology》2007,52(2):317-327

We report on the use of X-ray diffractometry under controlled conditions of temperature and relative humidity (RH-XRD) for the investigation of NaCl deliquescence in the pore space of glass filter frits, which were used as model substrates. The study confirms that RH-XRD is an appropriate experimental technique for the in situ observation of phase transformation in porous materials. It is used for an investigation of both the deliquescence kinetics and the deliquescence humidity within pores of different median pore diameter. Several major influences affecting deliquescence rates in the pore space close to the surface of a porous material are discussed. It appears that quite short-term variation of ambient relative humidity, e.g., typical daily fluctuations, might induce damaging deliquescence–crystallization cycles within the pore space of building materials. In agreement with theoretical considerations it was found that confinement of NaCl crystals in pores with median diameters in the range 1.4–70 μm does not affect the deliquescence humidity of the salt.  相似文献   

青海盐湖氯化镁资源开发   总被引：8，自引：2，他引：8       下载免费PDF全文

乌志明  李法强 《盐湖研究》2001,9(2):61-65

青海盐湖中有丰富的氯化镁资源 ,由氯化镁可生产多种镁产品 ,特别是以青海盐湖卤水提钾老卤中的镁资源开发镁产品 ,既可获得经济效益 ,又可治理氯化镁老卤造成的危害与污染 ;开展高值镁产品的研究可为盐湖开发的纵深发展打基础  相似文献   

柴达木盆地东台吉乃尔盐湖盐类沉积特征及成盐年代的初步研究   总被引：3，自引：0，他引：3  

张辉  韩凤清  梁青生 《化工矿产地质》2001,23(2):83-85

东台吉乃尔盐湖经过长期的成盐演化和成矿过程 ,最终形成了以氯化钠化学沉积为主的蒸发盐 ,晶间卤水富含B、Li等多种元素卤水矿床 ,根据 1998年对该湖干盐滩中部所打的CK1孔钻孔剖面( 12m)及测试的几个14 C年龄 ,初步证实该盐湖上部盐层是在约 10 0 0 0aBP形成 ,未经碳酸盐和硫酸盐成盐阶段 ,盐湖形成初期即进入氯化物成盐阶段。  相似文献   

三元体系RECl_3（RE＝Dy，Yb）－HOAc－H_2O（30℃）的研究     

李亚红  王惠  王林溪 《盐湖研究》1996,(Z1)

测定了三元体系ＲＥＣｌ３（ＲＥ＝Ｄｙ，Ｙｂ）－ＨＯＡｃ－Ｈ２Ｏ（３０℃）的平衡态的溶度数据并绘制了相应的溶度图。在两个体系中分别得到了ＤｙＣｌ３·６Ｈ２Ｏ和ＹｂＣｌ３·６Ｈ２Ｏ两种固相。依据ＨＯＡｃ对ＤｙＣｌ３·６Ｈ２Ｏ和ＹｂＣｌ３·６Ｈ２Ｏ有盐抗作用这一结论得到了一种制备ＤｙＣｌ３·６Ｈ２Ｏ和ＹｂＣｌ３·６Ｈ２Ｏ的ＨＣｌ—ＨＯＡｃ法。同时，在分析测定酸的重量百分浓度时，利用“差减法”得到了Ｈ＋的准确含量。  相似文献   

WINDOW FACTOR ANALYSIS:THEORETICAL DERIVATION AND APPLICATION TO FLOW INJECTION ANALYSIS DATA   总被引：1，自引：0，他引：1  

EDMUND R.MALINOWSKI 《地理学报(英文版)》1992,(1)

Window factor analysis(WFA)is a self-modeling method for extracting the concentration profiles ofindividual components from evolutionary processes such as flow injection,chromatography,titrationsand reaction kinetics.The method takes advantage of the fact that each component lies in a specificregion along the evolutionary axis,called the‘window’.Theoretical equations are derived.The methodis used to extract the concentration profiles and spectra of seven bismuth species from data obtained byGemperline and Hamilton,who injected bismuth perchlorate into a flowing stream of hydrochloric acid.  相似文献   

Biomass Burning in Southern Africa: Individual Particle Characterization of Atmospheric Aerosols and Savanna Fire Samples   总被引：2，自引：0，他引：2  

Xiande Liu  Piet Van Espen  Freddy Adams  Jan Cafmeyer  Willy Maenhaut 《Journal of Atmospheric Chemistry》2000,36(2):135-155

Ambient atmospheric aerosols and savanna fireparticulate emission samples from southern Africa werecharacterised in terms of particle classes and theirnumber abundance by electron probe X-ray microanalysis(EPXMA). About ten particle classes were identifiedfor each sample. The major classes werealuminosilicates and sea salts for ambient coarse(2–10 m equivalent aerodynamic diameter (EAD))samples, and K-S and S-only particles for ambient fine(<2 m EAD) samples. The K-S particles are oneof the major products of biomass burning. The EPXMAresults were found to be consistent with the resultsfrom bulk analyses on a sample by sample basis. Forsavanna fire fine samples, quantitative EPXMA revealedthat many particles had a composition of simple saltssuch as KCl. Some particles had a deviatingcomposition in the sense that more ionic species wereinvolved in sustaining the balance between cations andanions, and they were composite or mixed salts.Because of extensive processing during the atmospherictransport, the composition of the K-S particles in theambient samples was different from K₂SO₄,and such particles were enriched with S. The finepyrogenic KCl particles and the fine sea-saltparticles were much depleted in chlorine.  相似文献   

姑婆山复式岩体的基本特征及其与成矿作用的关系   总被引：5，自引：0，他引：5  

王建辉  蒋柏昌  孔祥伟  唐奎保 《矿产与地质》2006,20(1):47-53

姑婆山复式岩体由晚侏罗世里松岩体、姑婆山岩体及早白垩世新路岩体组成。复式岩体为壳幔混合源成因。据岩石地球化学判断和分析,姑婆山岩体和新路岩体为含锡岩体;整个姑婆山复式岩体为含钨岩体,里松岩体和姑婆山岩体为含稀有、稀土岩体。上述矿产的形成与岩石中挥发份F、B及放射性U、T h等元素的高含量有关。  相似文献   

离子色谱法测定五氧化二铌和五氧化二钽中痕量氟氯和硫酸根离子的前处理方法     

刘肖 滕曼蔡亚岐  牟世芬 《岩矿测试》2006,25(4):319-322

采用马弗炉将样品与NaOH混合进行熔融煅烧，热去离子水提取、离心、稀释后过OnGuard Ⅱ H柱和过滤膜进行前处理，抑制型电导离子色谱法检测，测定了Ta2O5和Nb2O5的氟离子、氯离子和硫酸根离子。该方法对三种被测阴离子的检测限（s／N=3）在0．15～0．70μg／g（以固体样品实际浓度计）或0．136～0．623μg／L（以溶液浓度计），标准曲线线性范围均在两个数量级以上，方法的精密度（RSD，n=7）小于5．46％，回收率为88％～106％，具有灵敏度高、选择性好、重现性佳、对环境友好等特点，用于实际样品的检测，结果令人满意。  相似文献