The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)     

Matteo Lelli  Roberto Cioni  Luigi Marini 《Environmental Geology》2008,56(1):139-158

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

Luigi Marini (Corresponding author)Email:

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Pressures of Crystallization of Icelandic Magmas   总被引：1，自引：0，他引：1  

Kelley  Daniel F.; Barton  Michael 《Journal of Petrology》2008,49(3):465-492

Iceland lies astride the Mid-Atlantic Ridge and was createdby seafloor spreading that began about 55 Ma. The crust is anomalouslythick (20–40 km), indicating higher melt productivityin the underlying mantle compared with normal ridge segmentsas a result of the presence of a mantle plume or upwelling centeredbeneath the northwestern edge of the Vatnajökull ice sheet.Seismic and volcanic activity is concentrated in 50 km wideneovolcanic or rift zones, which mark the subaerial Mid-AtlanticRidge, and in three flank zones. Geodetic and geophysical studiesprovide evidence for magma chambers located over a range ofdepths (1·5–21 km) in the crust, with shallow magmachambers beneath some volcanic centers (Katla, Grimsvötn,Eyjafjallajökull), and both shallow and deep chambers beneathothers (e.g. Krafla and Askja). We have compiled analyses ofbasalt glass with geochemical characteristics indicating crystallizationof ol–plag–cpx from 28 volcanic centers in the Western,Northern and Eastern rift zones as well as from the SouthernFlank Zone. Pressures of crystallization were calculated forthese glasses, and confirm that Icelandic magmas crystallizeover a wide range of pressures (0·001 to 1 GPa), equivalentto depths of 0–35 km. This range partly reflects crystallizationof melts en route to the surface, probably in dikes and conduits,after they leave intracrustal chambers. We find no evidencefor a shallow chamber beneath Katla, which probably indicatesthat the shallow chamber identified in other studies containssilica-rich magma rather than basalt. There is reasonably goodcorrelation between the depths of deep chambers (> 17 km)and geophysical estimates of Moho depth, indicating that magmaponds at the crust–mantle boundary. Shallow chambers (<7·1 km) are located in the upper crust, and probablyform at a level of neutral buoyancy. There are also discretechambers at intermediate depths (11 km beneath the rift zones),and there is strong evidence for cooling and crystallizing magmabodies or pockets throughout the middle and lower crust thatmight resemble a crystal mush. The results suggest that themiddle and lower crust is relatively hot and porous. It is suggestedthat crustal accretion occurs over a range of depths similarto those in recent models for accretionary processes at mid-oceanridges. The presence of multiple stacked chambers and hot, porouscrust suggests that magma evolution is complex and involvespolybaric crystallization, magma mixing, and assimilation. KEY WORDS: Iceland rift zones; cotectic crystallization; pressure; depth; magma chamber; volcanic glass  相似文献   

Geochronology of Pliocene volcanism in the Dzhavakheti Highland (the Lesser Caucasus). Part 1: Western part of the Dzhavakheti Highland     

V. A. Lebedev  S. N. Bubnov  O. Z. Dudauri  G. T. Vashakidze 《Stratigraphy and Geological Correlation》2008,16(2):204-224

Isotopic-geochronological study of the Pliocene magmatic activity in western part of the Dzhavakheti Highland (northwestern region of the Lesser Caucasus) is carried out. The results obtained imply that the Pliocene magmatic activity lasted in this part of the highland approximately 2 million years from 3.75 to 1.75–1.55 Ma. As is established, the studied volcanic rocks correspond in composition mostly to K-Na subalkaline and more abundant normal basalts. Time constraints of main phases in development of basic volcanism within the study region are figured out. We assume that individual pulses of silicic to moderately silicic volcanism presumably took place in the Dzhavakheti Highland about 3.2 and 2.5 Ma ago.  相似文献   

西藏冈底斯带措勤地区则弄群火山岩锆石U-Pb年代学格架及构造意义   总被引：29，自引：12，他引：17  

朱弟成  周肃  莫宣学  赵志丹  许继峰  周长勇  孙晨光  王立全  陈海红  董国臣 《岩石学报》2008,24(3)

大规模的则弄群火山岩呈带状近东西向展布于西藏冈底斯带中北部地区.对出露状况较好的措勤地区则弄群火山岩进行了锆石U-Pb定年,以建立其年代学格架便于区域对比.措勤地区则弄群火山岩多数锆石具有生长振荡环带,部分锆石显示核边结构.在措勤达雄北西部上覆于中二叠统下拉组灰岩的1件则弄群英安岩样品的LA-ICP-MS锆石U-Ph年龄为130±1Ma,1件则弄群流纹岩样品的SHRIMP锆石U-Pb年龄为129±3Ma;在措勤达雄北东部与下白垩统多尼组碎屑岩呈断层接触的1件则弄群英安岩样品中的锆石具有两组LA-ICP-MS锆石U-Pb年龄,最年轻的一组(包括增生边)为121±1Ma,较老的一组(包括核部)为131±1Ma;在措勤南西部1件则异群流纹岩样品的LA-ICP-MS锆石U-Pb年龄为111±1Ma,与措勤地区花岗岩类的侵位时代相当.这些高质量的锆石U-Pb年代学数据表明,措勤地区的则弄群火山作用很可能开始于约130Ma,停息于约110Ma,持续时间约20Ma.区域对比表明,东西延伸约1000km的则弄群火山作用同时发生在约130Ma.区域上目前的年代学数据结合同时代岩浆作用的分布特征表明,冈底斯带中北部地区早白垩世岩浆作用不太可能由新特提斯洋壳向北的低角度或平板俯冲产生.  相似文献   

试论雁荡山岩石地貌     

陶奎元  沈加林  姜杨  余明刚 《岩石学报》2008,24(11):2647-2656

雁荡山岩石地貌由叠嶂、方山、石门、柱峰、锐峰、岩洞、天生桥和峡谷、涧溪、瀑、潭、湖等岩石地貌组合而成。其形成的地质学、岩石学基础是白垩破火山岩相与构造。不同类型地貌景观反映了这一破火山构造。断裂切割、重力崩塌与流水侵蚀是形成此类地貌的主要外动力地质作用。雁荡山岩石地貌在形态、成因和审美学意义上均有别于我国砂砾岩岩石地貌、碳酸岩岩石地貌和花岗岩岩石地貌。雁荡山地貌可作为流纹质火山岩地貌的代表。  相似文献   

火山玻璃风化层的透射电镜研究   总被引：2，自引：0，他引：2  

张秉良  洪汉净  刘辉  盘晓东 《矿物学报》2008,28(3)

利用透射电镜(TEM)和X射线能谱(EDX)研究了长白山天池火山1000年和4000年前两次大喷发产生的火山玻璃风化层特征.TEM分析显示,4000年前大喷发浮岩中的火山玻璃风化层平均厚度3.7 mm,1000年前大喷发浮岩中的火山玻璃风化层平均厚度为1.0 mm.EDX分析显示,两次大喷发浮岩中的火山玻璃风化层化学组成与火山玻璃相比富Al、Fe,而si减少.火山玻璃风化层富Al发生在Al的浓度较高的中到弱酸溶液中(pH=5～6),火山玻璃表面形成含有少量的非晶质的Al、Si、Fe物质,这些非品质的次生物质是火山玻璃风化早期阶段形成的.天池火山喷发物中火山玻璃的微观特征的差异可能与火山喷发年代和喷发后的环境有关,研究天池火山不同期次喷发物中火山玻璃的微观特征具有一定的理论和实际应用价值.  相似文献   

辽宁省海洋环境保护与海岸带可持续开发利用     

刘现明 《海岸工程》1995,14(4):33-36

在分析综合辽宁省海岸带调查和沿海经济贝类污染监测资料基础上，根据辽宁海岸带水质，沉积物和生物污染现状及发展趋势。针对所存在的问题，讨论了辽宁省海洋污染特别是赤潮对海洋资源的破坏，并在组织机构，地方立法，海岸带环境保护规划，污染源控制与整体环境改进，监测方案等方面提出了建设海上辽宁、加强辽宁省海洋环境保护与海岸可持续开发利用的建议。  相似文献   

浙江省海岛沿岸水域微生物生态分布   总被引：2，自引：0，他引：2  

史君贤  陈忠元 《海洋学研究》1996,14(2):35-43

文章报道了浙江海岛沿岸水域中异养细菌、氨化细菌和反硝化细菌的数量分布及异养细菌的种群组成。结果表明：本调查海区异养细菌的数量较多，其数量分布范围在２．０４×１０４～８．３６×１０６个／ｄｍ３之间；氨化细菌数量分布范围在３．０×１０３～１．１×１０６个／ｄｍ３之间；反硝化细菌的数量分布范围在３．０×１０２～１．１－１０６个／ｄｍ３之间。细菌的数量与环境中营养盐的浓度之间存在密切关系。在不同的海区异养细菌的种群组成存在一定的差异，在浙北海区，革兰氏阴性菌所占比例为４１．６％，在浙中海区为４６．９％，在浙南海区为６４．９％。  相似文献   

南海区重点岸段海岸侵蚀现状成因分析与防治对策   总被引：4，自引：0，他引：4  

刘孟兰  郑西来  韩联民  林端  罗一丹  方宏达  柯东胜  彭晓娟  陈嘉辉 《海洋通报》2007,26(4):80-84

在2003年与2006年对南海区琼州海峡两岸重点岸段(雷州市徐闻县龙塘镇赤坎村岸段、海南省海口市镇海村岸段和新海村岸段)的海岸侵蚀进行了现场监测,测量了侵蚀的长度、宽度和面积。对两年现场测量结果进行比较分析,结果表明:海岸侵蚀长度的平均速度为200m/a,宽度的平均速度为20m/a,面积的平均速度为4000m2/a。应用了地质分析、水动力分析、极端海洋气候影响分析等新的理论和方法重点分析了海岸侵蚀的成因,并提出了一些对策,供相关部门参考。  相似文献   

亚热带沿海景观的旅游保护性开发及建设探讨--以福建沿海为例     

翁毅  周永章  张伟强  储德平 《台湾海峡》2006,25(2):285-294

依据地貌学和风景学的角度,福建沿海景观以闽江口和九龙江口为界可分为3个景观亚区,并具有多样性与复杂性、动态性与脆弱性和关联性与分异性等特征.本文运用景观生态的原理研究沿海景观的构成与格局,在沿海景观的分类和特征概括的基础上,探讨福建沿海景观旅游开发与建设的模式.通过维护沿海景观系统的稳定,优化沿海各景观亚区的分布格局,提高沿海景观的整体舒适性和挖掘文化景观的内涵等应对措施以实现福建沿海旅游的科学发展.  相似文献