Vulnerability of groundwater in Quaternary aquifers to organic contaminants: a case study in Wuhan City,China   总被引：5，自引：0，他引：5  

Yanxin Wang  Broder J. Merkel  Yilian Li  Hui Ye  Surong Fu  Dana Ihm 《Environmental Geology》2007,53(3):479-484

More than 30 organic contaminants were detected in shallow groundwaters at Wuhan, the largest city in central China. Seriously contaminated groundwaters were from densely populated, industrial and commercial areas. Abnormal concentrations were found in groundwater from Hankou, downtown Wuhan: trimethylbenzene up to 29 μg/L, tetramethylbenzene up to 866 μg/L, and trichloroethene up to 9.5 μg/L. Benzene, Toluene, Ethylene and Xylene (BTEX) contamination of groundwater is serious and widespread at Wuhan, ranging between 0.14 and 25.0 μg/L. Considering the hydrogeological conditions of most Chinese cities, DRAMIC, a modified version of the widely used DRASTIC model, was proposed by the authors for assessing vulnerability of groundwater to contamination. The factors D, R, A and I in DRAMIC model are the same as in DRASTIC. The factor topography is ignored. The factor soil media is substituted by a new factor aquifer thickness (M) and the factor hydraulic conductivity of the aquifer by a new factor impact of contaminant (C). The equation for determining the DRAMIC Index is: DRAMIC = 5D _R + 3R _R + 4A _R + 2M _R + 5I _R + 1C _R. The calculated DRAMIC Index can be used to identify areas that are more likely to be susceptible to groundwater contamination relative to each other. The higher the DRAMIC Index is, the greater the groundwater pollution potential. Applying DRAMIC, a GIS-based vulnerability map for Wuhan city was prepared. Interestingly, places such as downtown Hankou, where enhanced concentrations of BTEX have been detected, correspond quite well with those with higher DRAMIC ratings.  相似文献   

Effect of system variables and particle size on physical characteristics of air sparging plumes     

Daniel M. Baker  Craig H. Benson 《Geotechnical and Geological Engineering》2007,25(5):543-558

Air was injected through a well in a thin transparent tank filled with saturated glass beads to study how the size and air saturation of air sparging plumes are affected by particle size and gradation; operational parameters such as injection pressure, well depth, injection pressure pulsing; and well outlet configuration. V-shaped air plumes with an apex between 40° and 60° were obtained for all tests. The air pressure required to initiate sparging agreed closely with the sum of the air entry pressure and the hydrostatic pressure, with higher initiation pressures required in the fine and well-graded beads. Higher air flow rates and air saturations were obtained in coarser beads at a given pressure, and the variation in flow rate was consistent with estimated air permeabilities. Peak average air saturations were 28–56% for the coarse-medium beads, 10% for the well-graded beads, and 8% for the fine beads. Air saturation and the radius of influence increased modestly (<40%) as the normalized injection pressure exceeded 0.1. Radius of influence increased by approximately a factor of two as the well depth increased, but leveled off once the ratio of radius of influence to well depth reached 0.60–1.05. Pulsing of injection pressure had no effect on the initiation pressure, air flow rate, or air saturation, but increased the size of the air plume and the radius of influence slightly (<15%). Well outlet configuration had only a slight affect the radius of influence (<10%), air saturation (<10%), or air flow rate (<12%). Dye testing showed that water surrounding the air plume circulated during continuous and pulsed sparging. However, pulsed sparging resulted in greater and more defined circulation of water within and adjacent to the air plume, which should reduce mass transfer limitations during sparging.  相似文献   

Coastal processes and environmental hazards: the Buenos Aires (Argentina) and Venetian (Italy) littorals   总被引：1，自引：0，他引：1  

Jorge Pousa  Luigi Tosi  Eduardo Kruse  Dardo Guaraglia  Maurizio Bonardi  Andrea Mazzoldi  Federica Rizzetto  Enrique Schnack 《Environmental Geology》2007,51(8):1307-1316

The Buenos Aires (Argentina) and Venice (Italy) coastlands have experienced significant saltwater contamination of the phreatic aquifer, coastal erosion, hydrodynamic changes and relative sea level rise processes due to natural and man-induced factors. These factors expose coastal areas to morpho-hydro-geological hazards, such as soil desertification, frequency and degree of flooding, littoral erosion, and the silting of river mouths and channels. Man-made interventions and actions, such as beach mining, construction of coastal structures and exploitation of aquifers without an adequate knowledge of the hydrology setting and an adequate management program, worsen these natural hazards. Uncontrolled human activity induces environmental damage to the overall coastal plains. The coastal plains play an important role in the social/economic development of the two regions based on land use, such as agriculture, horticulture, breeding, and tourism, as well as industry. Results of investigations on saltwater contamination, sea level rise and morphological changes recently performed in these two coastal areas are presented here.  相似文献   

Potential hyperaccumulation of Pb, Zn, Cu and Cd in endurant plants distributed in an old smeltery, northeast China   总被引：1，自引：0，他引：1  

Shuang Cui  Qixing Zhou  Lei Chao 《Environmental Geology》2007,51(6):1043-1048

The absorption and accumulation of Pb, Zn, Cu and Cd in some endurant weed plant species that survived in an old smeltery in Liaoning, China, were systematically investigated. Potential hyperaccumulative characteristics of these species were also discussed. The results showed that metal accumulation in plants differed with species, tissues and metals. Endurant weed plants growing in this contaminated site exhibited high metal adaptability. Both the metal exclusion and detoxification tolerance strategies were involved in the species studied. Seven species for Pb and four species for Cd were satisfied for the concentration time level standard for hyperaccumulator. Considering translocation factor (TF) values, one species for Pb, seven species for Zn, two species for Cu and five species for Cd possessed the characteristic of hyperaccumulator. Particularly, Abutilon theophrasti Medic, exhibited strong accumulative ability to four heavy metals. Although enrichment coefficients of all samples were lesser than 1 and the absolute concentrations didn’t reach the standard, species mentioned above were primarily believed to be potential hyperaccumulators.  相似文献   

Changes of oceanographic characteristics and the state of pollution in the Izmit bay following the earthquake of 1999     

Enis Morkoc  Legovic Tarzan  Oya Okay  Huseyin Tufekci  Vildan Tufekci  Leyla Tolun  Fatma Karakoc 《Environmental Geology》2007,53(1):103-112

The Izmit Bay is an elongated semi-enclosed bay in the Marmara Sea. It is being increasingly polluted by both domestic and industrial waste discharge since 1970’s. A monitoring program was conducted between 1999-2000 to document the state of pollution in the bay. This includes the effect of Marmara (Izmit) earthquake (magnitude 7.4) that occurred in August 1999. A stable two-layer ecosystem exists in the bay throughout the year due to continuous inflows of the saltier Mediterranean and brackish Black Sea waters to the Marmara basin. Therefore, the principal biochemical characteristics of the bay are governed by the two-layer flow system over the basin. Dissolved oxygen (DO) is generally at a saturated levels in the surface layer which is 10 to 15 m thick, but it is depleted to 60–70 μM in the lower layer, exhibiting a steep gradient in the sharp halocline. When the earthquake occurred, great loads of industrial wastes were released into the bay surface waters, which enhanced primary production in the upper layer and thus large export of particulate organic matter to lower layer and eventually to the bottom. Accordingly, DO was consumed and anoxic condition was established even in the upper layer/halocline interface, the halocline and bottom waters of the eastern and central bay. In this period, concurrent increases were observed in phosphate and ammonia contents at the halocline and in deep waters whilst the nitrate was almost consumed via denitrification processes in the anoxic water. Recently, the industrial C, N and P loads increased by as much as 8 fold within five years (1995–2000) whilst domestic inputs increased by 50%. Total organic matter discharged to the bay increased more than double within the last 15 years. Besides, most factories in the region release toxic wastes into the bay after only partial treatment.  相似文献   

水溶性污染物在土壤中转化的原位实验方法   总被引：3，自引：0，他引：3  

杨胜科  王文科  李翔  李永涛  姜桂华 《西北地质》2002,35(2):20-23

建立了一种研究水溶性污染物在土壤中运转化的原位实验方法，该方法已成功地应用于研究黄土中氨氮的运移转化规律，克服了土柱实验存在的破坏土壤结构及氧化还原电位发生变化等所引起的实验误差。  相似文献   

Response of alpine chironomid communities (Lake Chuna, Kola Peninsula, northwestern Russia) to atmospheric contamination   总被引：1，自引：0，他引：1  

Boris Ilyashuk  Elena Ilyashuk 《Journal of Paleolimnology》2001,25(4):467-475

A short sediment core from the deepest part of an alpine lake (Lake Chuna, Kola Peninsula, northwestern Russia), covering about the past 200 yrs of sediment accumulation, was analysed for chironomid head capsule remains. The lake has been receiving acidic precipitation and heavy metals loading from the atmosphere since the 1940's. A total of 22 chironomid taxa were recorded. The most important taxa were typical elements of oligotrophic lakes, i.e.Micropsectra insignilobus, Paratanytarsus penicillatus, Stictochironomus spp. and Heterotrissocladius marcidus. Based on the cluster analyses results for the reconstructed environmental variables and chironomid communities, three developmental stages were distinguished from the lake history: (1) Natural ontogeny stage (before ~1945); (2) Initial stage of anthropogenic ontogeny (~1945-~1982); and (3) Anthropogenic ontogeny stage (~1982-~1996). During the first period, the changes in the chironomid fauna were characterized as an anthropogenically undisturbed community, with M. insignilobus dominating (46-66%). The changes during the second period reflected the initial phase of anthropogenic succession associated with the beginning of acidification and heavy metal pollution. The main species showed opposite distributional patterns in this period; the abundance of the group M. insignilobus/Stictochironomus spp. decreased, whereas the abundance of P. penicillatus/H. marcidus increased. The third period was characterized by a major shift in the faunal assemblages, from M. insignilobus to other dominant species including P. penicillatus (19-30%). The increases of Orthocladiinae relative abundance and total organic content in the uppermost sediment layers may be explained by a decrease in lake productivity. The decreases of cold-stenothermal taxa Stictochironomus spp. and M. insignilobus in the uppermost sediment layers can be explained by the global warming during the 20th century. The lake ecosystem is likely to be affected by both inputs of airborne contaminants and climate changes.  相似文献   

石家庄市地下水中氮污染分析   总被引：25，自引：1，他引：25  

毕二平  李政红 《水文地质工程地质》2001,28(2):31-34

通过对石家庄市地下水中“三氮”污染状况的分析，发现硝酸盐是地下水中的主要氮污染物，利用氮同位素方法分析了地下水中硝酸盐氮的来源，讨论了人类开采地下水和施放环境物质对地下水中氮聚集的影响，在人类活动影响强度小的地区，地下水中的硝酸盐污染强度大大低于市区。NO3-浓度与硬度变化趋势表明：氮污染与硬度等指标值升高有一定的联系，但在不同的水文地球化学环境中，在迁移和转化等方面又有着自己的特性。  相似文献   

Trace metals in acid sediments and waters, Pimpama catchment, southeast Queensland, Australia   总被引：2，自引：1，他引：2  

M. Preda  M. E. Cox 《Environmental Geology》2001,40(6):755-768

The Pimpama River floodplain has developed over the last several thousand years as a result of sea-level fluctuations that shaped the lower catchment and enabled the formation of sedimentary pyrite. The subsequent production of sulfuric acid due to the oxidation of this pyrite enhances the breakdown of metal-bearing sediments and can lead to leaching of major and trace metals into the waters of the region. The seasonal pattern of rainfall and current land-use activities are important aspects that intensify the natural production of acid and influence the release and distribution of metals. To identify the source and migration of metals in the Pimpama catchment and to understand the impact of pyrite oxidation on the distribution of metals in sediments and waters, several components of the drainage system were analyzed: bedrock, sediments from river bed and bank, and water. The elements analyzed in this study (V, Cr, Co, Ni, Cu, Zn and Pb) are all present in the bedrock material which explains their occurrence in the unconsolidated sediments of the floodplain. These metals concentrate in the upper section of the sedimentary sequence and their presence is related to clay minerals such as smectite, organic matter and iron phases. However, Zn, Mo and Co occur in higher amounts than the local background and within standard shale. This comparison suggests that the diagenetic processes alone cannot explain the higher concentrations and it is concluded that these metals also have an anthropogenic source. The formation of sulfuric acid creates conditions for higher mobility of some metals, such as Cr, Co, Ni, Cu, Zn, but does not affect less mobile ones such as Mo and Pb. Over the longterm, the production of acid influences the breakdown of mineral phases and enhances the process of weathering. Over the short term, every rain event leaches acid from sediments and mobilizes metals resulting in a substantial reduction in the quality of river water. Received: 2 October 1998 · Accepted: 16 February 1999  相似文献   

Generation of Deccan Trap magmas   总被引：1，自引：0，他引：1  

Gautam Sen 《Journal of Earth System Science》2001,110(4):409-431

Deccan Trap magmas may have erupted through multiple centers, the most prominent of which may have been a shield volcano-like structure in the Western Ghats area. The lavas are predominantly tholeiitic; alkalic mafic lavas and carbonatites are rare. Radioisotope dating, magnetic chronology, and age constraints from paleontology indicate that although the eruption started some 68 Ma, the bulk of lavas erupted at around 65–66 Ma. Paleomagnetic constraints indicate an uncertainty of ± 500,000 years for peak volcanic activity at 65 m.y. in the type section of the Western Ghats. Maximum magma residence times were calculated in this study based on growth rates of “giant plagioclase” crystals in lavas that marked the end phase of volcanic activity of different magma chambers. These calculations suggest that the > 1.7 km thick Western Ghats section might have erupted within a much shorter time interval of ∼ 55,000 years, implying phenomenal eruption rates that are orders of magnitude larger than any present-day eruption rate from any tectonic environment. Other significant observations/conclusions are as follows: (1) Deccan lavas can be grouped into stratigraphic subdivisions based on their geochemistry; (2) While some formations are relatively uncontaminated others are strongly contaminated by the continental crust; (3) Deccan magmas were produced by 15–30% melting of a Fe-rich lherzolitic source at ∼ 3–2 GPa; (4) Parent magmas of the relatively uncontaminated Ambenali formation had a primitive composition with 16%MgO, 47%SiO₂; (5) Deccan magmas were generated much deeper and by significantly more melting than other continental flood basalt provinces; (6) The erupted Deccan tholeiitic lavas underwent fractionation and magma mixing at ∼ 0.2 GPa. The composition and origin of the crust and crust/mantle boundary beneath the Deccan are discussed with respect to the influence of Deccan magmatic episode.  相似文献