厦门海域水体中有机锡的存在形态与含量分布   总被引：1，自引：0，他引：1  

赵冬梅  王新红  马建强  洪华生 《热带海洋学报》2007,26(4):76-81

利用固相萃取-气相色谱-火焰光度检测(SPE-GC-FPD)对厦门海域表、底层海水中的有机锡化合物进行了分析检测。其中表层海水中检出的有机锡化合物以二丁基锡(DBT)为主,底层海水中以三丁基锡(TBT)为主,且TBT的浓度显著高于表层水。表层海水中总有机锡浓度在129.1—4 826.8 ng(Sn).L-1之间,底层海水则分布在321.6—1 954.5ng(Sn).L-1之间。结果显示,厦门港内及同安湾附近海域水体中的有机锡浓度远高于九龙江口及厦门西南海域,这与厦门海域船舶活动和网箱养殖密切相关。通过对鼓浪屿站点表层海水中有机锡化合物15 h的连续监测,推测光照对水体中有机锡的降解影响显著。  相似文献   

南海表层沉积物中钙质超微化石分布特征   总被引：9，自引：0，他引：9  

王勇军  陈木宏  陆钧  向荣  张兰兰  张丽丽 《热带海洋学报》2007,26(5):26-34

为系统描述钙质超微化石在南海表层沉积中的分布特征,对遍布南海的175个样品进行了实验分析。发现不同地区钙质超微化石绝对丰度相差很大,从0—3.8×1010个.g-1不等。平面上将钙质超微化石丰度分为3个区。共鉴定出钙质超微化石21属28种,以Emiliania huxleyi、Florisphaera profunda和Gephyrocapsa oceanica为优势种,其中Florisphaera profunda占据绝对优势。南海钙质超微化石分布具有两个明显特征:一是14°N线南北两边钙质超微化石的分布存在差异;二是南海钙质超微化石丰度以南沙群岛和西沙群岛两片海域为最高,并有东北-西南走向的分布趋势。对影响钙质超微化石分布的水深、上升流与营养盐、陆源物质稀释作用、碳酸盐溶解作用等因素作了讨论,并根据钙质超微化石随水深的变化推测南海碳酸盐补偿深度应在4 000m左右。  相似文献   

In situ and satellite observations of the eastward migration of the Western Alboran Sea Gyre     

M.M. Flexas  D. Gomis  S. Ruiz  A. Pascual  P. Len 《Progress in Oceanography》2006,70(2-4):486

During October 2003 an intensive oceanographic survey (BIOMEGA) was carried out in the Alboran Sea, coinciding with a migration event of the Western Alboran Sea Gyre (WAG). The observations gathered during that cruise constitute the first field evidence of a migrated stage of the WAG. In this work we present the main differences between the 3D hydrodynamic fields observed during BIOMEGA and those corresponding to a WAG located at its usual position. The migration of the gyre was followed by satellite (altimetry and sea surface temperature) imagery. The causes of the gyre migration are explored in terms of the quasi-geostrophic tendency equation, in particular of the dynamics governing scales larger than the Rossby radius of deformation. It is shown that the steady state gyre must be almost equivalent barotropic and that the key process to break down the stationarity would be a density advection at gyre scale. The mechanisms to explain the migration of the WAG proposed by previous authors are discussed in light of the explanation proposed in this work.  相似文献   

THE INTRINSIC ACIDITY CONSTANTS AND SPECIFIC SURFACE AREA OF MARINE SOLID PARTICLESII. THE RELATIONSHIP BETWEEN THE INTRINSIC ACIDITY CONSTANT AND THE TERNARY SURFACE COMPLEX     

王修林  张正斌  刘莲生 《中国海洋湖沼学报》1992,(1)

This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.  相似文献   

蒸发皿中水面蒸发氢氧同位素分馏的实验研究   总被引：3，自引：0，他引：3       下载免费PDF全文

包为民  胡海英  王涛  瞿思敏 《水科学进展》2008,19(6):780-785

气象要素与蒸发密切相关,通过室内外不同气象条件下的器皿水蒸发实验,获得了水面蒸发氢氧稳定同位素分馏因子与气象要素的关系。实验结果表明,随着蒸发的进行,剩余水体中逐渐富集重同位素;自由水体蒸发同位素分馏在垂线上有分层现象,表层水体同位素值比垂线平均的同位素值略富集;不同温度条件下的室内蒸发实验中,温度越高,液-气间分馏系数越小,相应于同一剩余水体体积比,剩余水体稳定同位素值则越低。室外器皿水自由蒸发实验中得出的蒸发线方程斜率较大地偏离了当地降水线,表明实验期间水体蒸发分馏作用较明显。该研究为进一步揭示水体蒸发分馏规律提供了可靠的实验依据。  相似文献   

基于BP神经网络的地图数字化误差纠正     

张菊清  聂建亮  杨淑靖 《测绘科学》2008,33(3):107-109

由于在数字化采集过程中不可避免地会引入系统误差和异常误差,因此消除和削弱这些误差的影响是提高空间数据质量的关键。然而由于图纸变形不均匀,扫描误差又极其复杂,用常规的多项式拟合技术只能消除部分有规律的系统误差,很难完全消除它们对地图数字化坐标的影响。BP神经网络是一个高度非线性映射系统,能以任意精度逼近。结合地图数字化坐标改正的特点,本文给出了基于BP神经网络地图数字化坐标误差纠正的方法,并通过实例验证了该方法的有效性。  相似文献   

一种改进的周跳多项式拟合方法   总被引：8，自引：3，他引：5  

李明  高星伟  徐爱功 《测绘科学》2008,33(4)

多项式拟合探测周跳受相位观测值所含误差的影响,随着采样数的增加,其探测周跳的能力随之降低,通常将观测数据分成若干段来进行处理。这样不可避免的增加工作强度,降低工作效率。本文根据多项式拟合探测周跳的基本原理,对多项式进行改进。经实验证明,利用改进后的多项式进行拟合能够有效地弥补传统方法的不足,使周跳的探测与修复更加稳定可靠。  相似文献   

正交距离圆曲线拟合方法   总被引：2，自引：0，他引：2  

丁克良  刘全利  陈翔 《测绘科学》2008,(Z1)

在分析圆曲线拟合准则基础上,提出采用正交最小二乘法拟合圆曲线。该方法以圆曲线正交距离残差平方和极小为准则。基于间接平差原理详细推导了相关模型和算法,并以实际算例说明了该方法的效果。  相似文献   

根据多卫星高度计海面高数据推算南中国海及菲律宾海域重力异常(英文)   总被引：1，自引：0，他引：1  

Isaac Dadzie  Jiancheng Li  Yonghai Chu 《地球空间信息科学学报》2008,11(3):174-179

t Gravity anomalies on a2.5 ×2.5 arc-minute grid in a non-tidal system were derived over the South China and Philippine Seas from multi-satellite altimetry data. North and east components of deflections of the vertical were computed from altimeter-derived sea surface heights at crossover locations, and gridded onto a 2.5 × 2.5 arc-minute resolution grid. EGM96-derived components of deflections of the vertical and gravity anomalies gridded into 2.5 × 2.5 arc-minute resolutions were then used as reference global geopotential model quantities in a remove-restore procedure to implement the Inverse Vening Meinesz formula via the 1D-FFT technique to predict the gravity anomalies over the South China and Philippine Seas from the gridded altimeter-derived components of deflections of the vertical. Statistical comparisons between the altimeter-derived and the shipboard gravity anomalies showed that there is a root-mean-square agreement of 5.7 mgals between them.  相似文献   

高灵敏度机载L波段微波辐射计探测海表盐度     

赵凯  史久新  张汉德 《遥感学报》2008,12(2):277-283

海水盐度是研究大洋环流和全球气候变化的重要参数,L波段(1400-1427MHz)微波辐射计是进行海水盐度遥感的最有效工具.在该频段内,微波辐射亮度温度对海水盐度变化的灵敏度为0.5K/psu,而用于海洋研究的盐度分辨率为0.1-0.2psu,要求微波辐射计的灵敏度优于0.1K.高灵敏度机载L波段微波辐射计,应用数字增益波动自动补偿和温度补偿技术,保证了系统的稳定性,并采用高效的滤波技术有效地抑制了全球定位信号(GPS)对接收机的干扰,灵敏度达到0.08K.进行了多次航空和海上对比遥感试验,获得了分辨率优于0.2psu、误差精度0.42psu的测量结果.  相似文献