Tephrological implications of beam size—sample‐size effects in electron microprobe analysis of glass shards     

John B. Hunt  Peter G. Hill 《第四纪科学杂志》2001,16(2):105-117

This paper concerns the potential consequences of varying procedures for the determination of tephra geochemistry by electron microprobe. Application of electron probe microanalysis to tephrostratigraphical methods has increasingly facilitated the resolution and refinement of Quaternary chronology associated with records of proxy‐environmental or proxy‐climatic change. The geographical range over which tephras are recovered has expanded significantly with the identification and analysis of crypto (or hidden) tephras in areas far removed from tephra sources. These tephras are dominated by glass shards, which, in many distal environments, may be either small in size (μm) or may be highly pumiceous with low glass:void ratios and thin (<10 μm) shard walls. We demonstrate that reducing the size of the electron beam used to analyse shard geochemistry cannot be used reliably to permit analysis of thin glass walls. This approach distorts the geochemical data, creating analytical differences that may generate inappropriate tephrogeochemical fingerprints. Additional distortion of the geochemical fingerprint in the form of hybrid analyses may be encountered in glass fragments containing micron‐sized crystalline phases such as feldspar. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

Age and extent of the Ilopango TBJ Tephra inferred from a Holocene chronostratigraphic reference section, Lago De Yojoa, Honduras   总被引：1，自引：0，他引：1  

Peter J. Mehringer Jr.  Andrei M. Sarna-Wojcicki  Payson Sheets 《Quaternary Research》2005,63(2):199-205

Eruption of central El Salvador's Ilopango Volcano early in the first millennium A.D. caused death, cultural devastation, and exodus of southern Mesoamericans. It also left a time-stratigraphic marker in western El Salvador and adjacent Guatemala—the Ilopango Tierra Blanca Joven, or TBJ tephra. Mineral suites and major element abundances identify a silicic volcanic ash in cores from Lago de Yojoa, Honduras, as Ilopango TBJ. This extends its reported range more than 150 km to the northeast. Analyses of glass from the TBJ tephra from the Chalchuapa archaeological site, El Salvador, and from Lago de Yojoa, Honduras, establish the first major element reference fingerprint for the TBJ tephra. The Lago de Yojoa cores also hold two previously undated trachyandesitic tephra layers originating from the nearby Lake Yojoa Volcanic Field. One fell shortly before 11,000 ¹⁴C yr B.P. and the other about 8600 ¹⁴C yr B.P.  相似文献   

Deformation structures and an alteration zone linked to deposition of volcanogenic sulphate in an ancient playa (Oligocene of Nebraska, USA)     

DAVID B. LOOPE  JOSEPH A. MASON†  HUIMING BAO‡  RICHARD M. KETTLER  C. WILLIAM ZANNER¶ 《Sedimentology》2005,52(1):123-139

Historic, sulphur-rich volcanic eruptions have altered global climate for as much as five years, and much larger events are known from the geologic record. At Scotts Bluff, Nebraska, Early Oligocene strata of the lower Arikaree Group contain a tephra bed with abundant calcite pseudomorphs after gypsum. Previous work has shown sulphate from the pseudomorphs in this tephra bears a high ¹⁷O anomaly indicative of oxidation of sulphur gases by ozone or hydrogen peroxide in the atmosphere. Possible sources of the tephra were caldera eruptions at about 28 Ma in the San Juan volcanic field of south-western Colorado (∼500 km SW of the study site) and the eastern Great Basin (∼1000 km WSW). The present sedimentological study shows that tephra and volcanogenic sulphate were deposited and preserved within a small, surface-discharging playa that developed on the irregular upper surface of aeolian siltstones of the subjacent White River Group. Sulphate solutions (including perhaps sulphuric acid) percolated downward within the vadose zone, dissolving early formed smectite cement within underlying volcaniclastic sandstones, reddening these rocks along an irregular alteration front. Preserved fine-scale stratification within the sandstones precludes the possibility that reddening took place during pedogenesis. Displacive growth of gypsum at the playa centre folded tephra beds and forced tephra into underlying sandstones, forming elongate cones. The large mass fraction of gypsum (now replaced by calcite) in the playa sediments suggests a huge, long-distance delivery of sulphate aerosols. Some of the sulphate and tephra may have come from the same eruption, or the fine-grained tephra may simply have aided preservation of dry-fog sulphate derived from an unrelated, effusive eruption of lava.  相似文献   

湖光岩玛珥湖火山灰的成分及其来源   总被引：7，自引：0，他引：7       下载免费PDF全文

郭正府  刘嘉麒  储国强  J.F.W.Negendank 《第四纪研究》2002,22(3):266-272

湖光岩玛珥湖沉积物中的火山灰保存了其原始形貌、原生的沉积和成分特征,是进行岩芯沉积物对比和定年的理想材料之一。除了对火山灰进行常规的定年外,通过精确测定火山灰中玻璃碎屑(玻屑)的成分,并与已知时代的火山喷发物成分对比确定火山灰的年龄已成为火山灰年代学研究的重要领域之一,因为它能够区分年龄差别在同位素定年误差之内的数层火山灰。本文利用电子探针分析了湖光岩玛珥湖岩芯火山灰中玻屑的成分,经与全球年龄已知火山喷发物的成分对比和分析,认为该火山灰的年龄为74000aB.P.,在此基础上,讨论了湖光岩玛珥湖岩芯74000aB.P.以来沉积速率的变化趋势。  相似文献   

火山碎屑空降沉积的二维数值模拟   总被引：2，自引：5，他引：2       下载免费PDF全文

赵谊  张程远  席道瑛 《地震地质》2002,24(3):377-386

从大气中火山灰扩散的二维微分方程出发 ,采用Suzuki(1983)对火山空降碎屑灾害数值模拟的数学模型 ,研制出用于单个火山一次性喷发事件的碎屑物空降沉积分布的实用程序。介绍了编程的基本思想 ,讨论了编程过程中所遇到的实际问题 ,同时结合长白山火山物理研究工作给出的长白山火山动力学参数 ,对长白山火山喷发空降碎屑厚度分布进行了具体模拟应用 ,针对实际模拟结果对程序提出了改进意见 ,并对Suzuki火山碎屑空降沉积模型进行了讨论  相似文献   

Plinian fall deposits from Vulsini Volcanic District (Central Italy)     

G. Nappi  B. Capaccioni  M. Mattioli  E. Mancini  L. Valentini 《Bulletin of Volcanology》1994,56(6-7):502-515

Stratigraphic investigations of the Vulsini Volcanic District indicate the existence of five prominent plinian fall deposits, deposited over a period of about 0.34 Ma. The oldest deposit (Basal pumices) crops out mainly in the peripheral areas and is one of the largest plinian events in the Vulsini District, with a volume of about 9 km³ and a calculated column height exceeding 30 km. Subcircular patterns of isopachs and isopleths around the Bolsena lake indicate emplacement in wind-free conditions and suggest a source vent location in the northernmost sector of the present Bolsena lake, where it is possible that an older central volcanic structure existed. The four younger plinian fall deposits are related to Bolsena activity. The oldest of these, named the Ponticello and Orvieto-Bagnoregio pumices, are mainly distributed on the north-eastern sector of the Vulsini District. Their volumes are an order of magnitude lower than that of the basal unit, and the estimated column heights do not exceed 20 km. The younger Ospedaletto pumice deposit has a NE-SW dispersal axis, whereas the youngest Casetta pumice deposit is found only in the north-eastern sector of the district. Their estimated volumes are respectively 1.2 and 0.1 km³, whereas the inferred vent areas appear to be located slightly to the east of the Ponticello and Orvieto-Bagnoregio pumice deposit source areas. The chronology of the Ospedaletto and Casetta pumices indicates that the final plinian activity from the Bolsena complex is contemporaneous with the Latera activity. The decreasing volumes from the oldest to the youngest units, together with the progressive shifting northeastwards of the source vents, may be related to the volcano-tectonic subsidence of the Bolsena area. The source vents for the post-Basal pumices events are mainly clustered just north of Bolsena village where the greatest displacement during subsidence occurred. Accordingly, source vent shifting appears to be related to the progressive opening of normal faults from the inner to the outer margin of the Bolsena depression.  相似文献   

Diatom responses to late Quaternary vegetation and climate change,and to deposition of two tephras in an alpine and a sub-alpine lake in Yoho National Park,British Columbia     

Michael Hickman  Mel A. Reasoner 《Journal of Paleolimnology》1994,11(2):173-188

The late Quaternary diatom records from alpine Opabin Lake (altitude 2285 m a.s.l.) and sub-alpine Mary Lake (altitude 2054 m a.s.l.), located in Yoho National Park, British Columbia (lat. 51 ° 21N; long. 116 ° 20), have been analyzed, and changes in these records have been used to reconstruct lake histories. The results have also been related to independently inferred vegetation and climate changes. Following deglaciation, when both lakes were receiving high inputs of clastic materials, benthic diatom taxa dominate the records of these two shallow lakes with small species ofFragilaria being particularly prominent. During the early to mid-Holocene period, when treeline was at a higher elevation than today, the diatom flora of both lakes became more diverse with previously minor species becoming more prominent.Cyclotella radiosa occurs in cores from both Mary Lake, and much deeper, neighbouring Lake O'Hara during the warm early Holocene, and may reflect this warmer climate, a longer ice-free season than presently, and perhaps less turbid water, or its presence may reflect a subtly higher nutrient status of the lake water during this period. The Neoglacial is marked by increased amounts of sediments originating from glacial sources in Opabin Lake, which undoubtedly led to very turbid water, and by the presence ofEllerbeckia arenaria f.teres andCampylodiscus noricus v.hibernica in Opabin Lake; however, these species are absent from Mary Lake which has not been influenced by either glacial activity since the recession of the glaciers prior toc. 10 000 years BP or water originating from Opabin Lake. The impact of the two tephras during the Holocene was dramatic in terms of increased diatom production, as exemplified by the increases in diatom numbers, but there was little effect upon species composition. The diatom records and changes in the diatom:cyst ratio suggest that the chemical status of these two small, shallow lakes has changed little during the Holocene, other than after deposition of the two tephras. These results provide evidence that shallow alpine and high sub-alpine lakes are sensitive recorders of past environmental changes.  相似文献   

Rock magnetic property of gravity core CSH1 from the northern Okinawa Trough and the effect of early diagenesis     

GE Shulan  SHI Xuef  WU Yonghu  LEE Tehquei  XIONG Yingqian  SAITO Yoshiki 《海洋学报(英文版)》2007,26(5):54-65

Detailed rock magnetic investigations were undertaken at 2~4 cm interval for the gravity core CSH1(with a length of 17.36 m) from the northern Okinawa Trough.Time-scale of the core was constructed by two characteristic tephras and foraminferal assemblages,indicating an age of 50 ka for the bottom of the core.Except for three tephras and abrupt decrease in surface,there are little changes in all kinds of rock magnetic parameters that can be correlated to the climate change for the last 50 ka.Different from the common sediments,most S-ratios(S equals the negative ratio of IRM-0.3T to SIRM,which is an indicator of low coercivity content)of the sediments are smaller than 0.9,which implies a substantial amount of magnetic minerals with high coercivity.The existence of iron sulphide(greigite or pyrrhotite) is revealed by representative susceptibility-temperature curves showing 200~350 ℃ Curie temperature in addition to 580 ℃ of magnetite,and also by awful smell during heating and dark heating products.Both the occurrence of authigenic iron sulphide and quick decrease of magnetic parameters near the surface clearly show that sediments from Core CSH1 have undergone early diagenesis.The featureless magnetic changes of the whole core except for three tephras mean that the post-depositonal alteration is so strong that most original signals have been destroyed.For the same reason,the organic matter in sediment and sulphate in pore water must have been consumed along with dissolution,precipitation of iron and manganese happening sequencially during the redox reaction series.Great caution must be taken when using these altered chemical parameters for the interpretation of climatic changes.  相似文献   

冲绳海槽北部的全新世火山碎屑沉积   总被引：1，自引：0，他引：1  

刘焱光  曹东林  张德玉  孙吉林  石学法 《海洋科学进展》2007,25(1):34-45

分析了冲绳海槽北部的CSH1岩芯沉积物中矿物组成、化学元素质量分数和粒度的变化规律,研究结果表明,在全新世期间,日本九州岛发生了2次大规模火山喷发活动,造成大量的火山物质沉积在冲绳海槽北部。从岩芯最上部的沉积物中可识别出2层火山碎屑沉积,它们都具有沉积物粒径突然变粗、SiO2和Na2O等化合物的质量分数突然增加以及粘土矿物、挥发份、Fe2O3、MgO、CaO和Sr的质量分数迅速下降等特征。沉积物粒度数据的端员分析结果表明,冲绳海槽北部全新世沉积物中的硅酸盐碎屑是由陆源碎屑物质和火山灰按不同的比例混合而成的。有火山物质混入的沉积物的粒度分布多呈现双峰模式,粒度众数值分别为74.3和7.81μm。浮游有孔虫壳体的AMS14C测年结果表明,2层火山碎屑所对应的火山喷发年代分别为7 210和10 870 cal.aBP。其中前者与K-Ah火山的喷发时间一致,后者可能与Kuju火山在12~10 cal.kaBP期间的喷发有关。  相似文献   

The Rocourt Tephra, a widespread 90–74 ka stratigraphic marker in Belgium     

Andr Pouclet  Etienne Juvign  Stphane Pirson 《Quaternary Research》2008,70(1):105-120

A new study of the stratigraphy and composition of the Rocourt Tephra is performed at five sites in Belgium and brackets the age of the tephra between 90.3 and 74 ka. The volcanic glass grains have a typical shape of phreatomagmatic eruption products. A large set of tephra minerals were analyzed, namely clinopyroxene, orthopyroxene, amphibole, and Cr-spinel. The compositions of these minerals have been compared with the lava xenocrysts, megacrysts, and phenocrysts of the proximate Eifel volcanic province for which the origin has been determined (mantle xenoliths, high-pressure cumulates, and middle- to low-pressure magmatic phases). This allowed us to determine the likely origin of the tephra minerals. The Rocourt Tephra source could be a West Eifel volcano that was fed by a deep-seated magma batch rich in high- to middle-pressure minerals.  相似文献