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91.
Discrete Quaternary (<400 ka) tephra fallout layers (mostly <1 cm thick) within the siliceous oozes of the central Mariana Trough at 18°N are characterized by medium-K to high-K subalkalic volcanic glasses (K2O=0.8–3.2 wt.%) with high large-ion lithophile elements (LILE)/high-field-strength elements (HFSE) ratios and Nb depletion (Ba/La35; Ba/Zr3.5; La/Nb4) typical for convergent margin volcanic rocks. Compositional zoning within layers ranges from basaltic to dacitic (SiO2=48–71 wt.%; MgO=0.7–6.5 wt.%); all layers contain basaltic andesites. The tephra layers are interpreted as single explosive eruptive events tapping chemically zoned reservoirs, the sources being the Mariana arc volcanoes (MAV) due to their proximity (100–400 km) and similar element ratios (MAV: Ba/La=36±7; Ba/Zr=3.5±0.9). The glasses investigated, however, contrast with the contemporaneous basaltic to dacitic lavas of the MAV by being more enriched in TiO2 (1.2 wt.%; MAV0.8 wt.%), FeO* (10 wt.%, MAV8–9 wt.%), K2O (1.1 wt.%; MAV0.8 wt.%) and P2O5 (0.4 wt.%; MAV0.2 wt.%). (Semi-)Incompatible trace elements (including Rare Earth Elements (REE)) of the basaltic-andesitic and dacitic glasses match those of the dacitic MAV lavas, which became enriched by fractional crystallization. Moreover, the glasses follow a tholeiitic trend of fractionation in contrast to MAV transitional trends and have a characteristic P2O5 trend that reaches a maximum of 0.6 wt.% P2O5 at 57 wt.% SiO2, whereas MAV lavas increase linearly in P2O5 from 0.1 to 0.3 wt.% with increasing silica. Both explosive and effusive series are interpreted to have evolved in common magma reservoirs by convective fractionation. Similar parental magmas are suggested to have separated into coexisting Si-andesitic to dacitic and basaltic melts by in situ crystallization. The differentiated melt is interstitial in an apatite-saturated crystalline mush of plag+px±ox±ol at the cooler chamber margins in contrast to the less differentiated basaltic to basaltic-andesitic magmas, which are not yet saturated in apatite and occupy the chamber interior. Reinjection of interstitial melt into the chamber interior and mixing with larger melt fractions of the interior liquid (mixing ratios about 1: 8–9) can explain the paradoxical behavior of apatite-controlled P and MREE variation in the basaltic andesite glasses and their MAV dacite-like fractionation patterns. The process may also account for the exclusively tholeiitic trend of fractionation of the glass shard series, but in situ crystallization alone cannot cause their absolute enrichment in (semi-)incompatible elements. The newly mixed melt is suggested to form the basaltic end member of the glass shard series. However, it must have become physically separated from the main MAV magma body (possibly by density-driven convective fractionation) in order to allow for further evolution of the contrasting geochemical paths as well as differentiation.  相似文献   
92.
Volcán Alcedo is one of the seven western Galápagos shields and is the only active Galápagos volcano known to have erupted rhyolite as well as basalt. The volcano stands 4 km above the sea floor and has a subaerial volume of 200 km3, nearly all of which is basalt. As Volcán Alcedo grew, it built an elongate domal shield, which was partly truncated during repeated caldera-collapse and partial-filling episodes. An outward-dipping sequence of basalt flows at least 250 m thick forms the steepest (to 33°) flanks of the volcano and is not tilted; thus a constructional origin for the steep upper flanks is favored. About 1 km3 of rhyolite erupted late in the volcano's history from at least three vents and in 2–5 episodes. The most explosive of these produced a tephra blanket that covers the eastern half of the volcano. Homogeneous rhyolitic pumice is overlain by dacite-rhyolite commingled pumice, with no stratigraphic break. The tephra is notable for its low density and coarse grain size. The calculated height of the eruption plume is 23–30 km, and the intensity is estimated to have been 1.2x108 kg/s. Rhyolitic lavas vented from the floor of the caldera and from fissures along the rim overlie the tephra of the plinian phase. The age of the rhyolitic eruptions is 120 ka, on the basis of K-Ar ages. Between ten and 20 basaltic lava flows are younger than the rhyolites. Recent faulting resulted in a moat around part of the caldera floor. Alcedo most resently erupted sometime between 1946 and 1960 from its southern flank. Alcedo maintains an active, transient hydrothermal system. Acoustic and seismic activity in 1991 is attributed to the disruption of the hydrothermal system by a regional-scale earthquake.  相似文献   
93.
The tephra fallout from the 12–15 August 1991 explosive eruption of Hudson volcano (Cordillera de los Andes, 45°54 S-72°58 W; Chile) was dispersed on a narrow, elongated ESE sector of Patagonia, covering an area (on land) of more than 100 000 km2. The elongated shape of the deposit, together with the relatively coarse mean and median values of the particles at a considerable distance from the vent, were the result of strong winds blowing to the southeast during the eruption. The thickness of the fall deposit decreases up to 250 km ESE from Hudson volcano, where it begins to thicken again. Secondary maxima are well developed at approximately 500 km from the vent. Secondary maxima, together with grainsize bimodality in individual layers and in the bulk deposit suggest that particle aggregation played an important role in tephra sedimentation. The fallout deposit is well stratified, with alternating fine-grained and coarsegrained layers, which is probably a result of strong eruptive pulses followed by relatively calm periods and/or changes in the eruptive style from plinian to phreatoplinian. The tephra is mostly composed of juvenile material: the coarse mode (mostly pumice) shifts to finer sizes with distance from the volcano; the fine mode (mostly glass shards) is always about 5/6 phi. Glass shards and pumice are mostly light gray to colorless. However, considerable amounts of dark, poorly vesiculated, blocky shards, suggest a hydromagmatic component in the eruption. A land-based tephra volume of 4.35 km3 was estimated, and a total volume of 7.6 km3 arose from an extrapolation, which took into account the probable volume sedimented in the sea. Bulk density ranges from 0.9 to 1.10 gr/cm3 (beyond 110 km from the vent). Rather uniform density values measured in crushed samples (2.45–2.50 gr/cm3 at all distances from the vent) reveal a relatively homogeneous composition. Mean and median sizes decrease rapidly up to 270 km from the vent; beyond that point they are more or less constant, whereas the maximum size (1 phi) shows a steady decrease up to 550 km. A concomitant improvement in sorting is observed. This is attributed to sorting due to wind transport combined with particle aggregation at different times and distances from the vent. The Hudson tephra fallout shares some strikingly similar features with the Mount St. Helens (18 May 1980) and Quizapu (1932) eruptions.  相似文献   
94.
The results of stratigraphic and tephrostratigraphic analyses of several pyroclastic levels, collected along the coastal sector of the Cilento region (southern Italy), are presented. Some of these levels are here described for the fist time, others, already known in literature, were reconsidered in order to better understand their stratigraphic position and to point out the possible volcanic sources.  相似文献   
95.
A tephrostratigraphy for Erebus volcano is presented, including tephra composition, stratigraphy, and eruption mechanism. Tephra from Erebus were collected from glacial ice and firn. Scanning electron microscope images of the ash morphologies help determine their eruption mechanisms The tephra resulted mainly from phreatomagmatic eruptions with fewer from Strombolian eruptions. Tephra having mixed phreatomagmatic–Strombolian origins are common. Two tephra deposited on the East Antarctic ice sheet, ~ 200 km from Erebus, resulted from Plinian and phreatomagmatic eruptions. Glass droplets in some tephra indicate that these shards were produced in both phreatomagmatic and Strombolian eruptions. A budding ash morphology results from small spheres quenched during the process of hydrodynamically splitting off from a parent melt globule. Clustered and rare single xenocrystic analcime crystals, undifferentiated zeolites, and clay are likely accidental clasts entrained from a hydrothermal system present prior to eruption. The phonolite compositions of glass shards confirm Erebus volcano as the eruptive source. The glasses show subtle trends in composition, which correlate with stratigraphic position. Trace element analyses of bulk tephra samples show slight differences that reflect varying feldspar contents.  相似文献   
96.
Optically stimulated luminescence (OSL) dating of perennially frozen loess was tested on quartz grains extracted from deposits associated with the late Pleistocene Dawson tephra in western Yukon Territory, Canada. OSL samples were obtained from ice-rich loess bracketing the Dawson tephra, while radiocarbon (14C) samples were collected from the bulk sediments directly underlying the tephra and from a ground-squirrel burrow 2.7 m below the tephra. Here we report the OSL characteristics and ages of the extracted quartz grains, as well as additional radiocarbon ages for samples described in Froese [2002. Age and significance of the late Pleistocene Dawson tephra in eastern Beringia. Quaternary Science Reviews 21, 2137–2142; 2006. Seasonality of the late Pleistocene Dawson tephra and exceptional preservation of a buried riparian surface in central Yukon Territory, Canada. Quaternary Science Reviews 25, 1542–1551]. We refine the time of Dawson tephra deposition to between 25,420±70 and 25,290±80 14C a BP. Bayesian analysis of constraining radiocarbon ages places the deposition of the Dawson tephra at between 30,433 and 30,032 cal a BP. Linear modulation (LM) OSL analysis of multi-grain aliquots of quartz showed that the initial part of the decay curve is dominated by a rapidly bleached (‘fast’) component; these samples, however, had relatively dim continuous wave (CW) OSL signals at the multi-grain aliquot (each composed of 80 grains) and single-grain scales of analysis. The single-aliquot regenerative-dose protocol was applied to multi-grain aliquots and single grains to obtain equivalent dose (De) values for samples collected from below and above the Dawson tephra. The De values were examined graphically and numerically, the latter using the central age, minimum age, and finite mixture models. For multi-grain aliquots, the central age model gave weighted mean De values between 30 and 50 Gy, which greatly underestimated the expected De of 74–81 Gy for both samples studied. Possible reasons for these underestimations are discussed, and a solution proposed based on single-grain analysis. Measurements of single grains produced De values in agreement with the expected De, and yielded OSL ages of 28±5 and 30±4 ka for the samples taken from above and below the Dawson tephra, respectively. Examination of individual grains with differing luminescence behaviors showed that a significant number of the measured quartz grains exhibited anomalous luminescence properties that would have compromised the results obtained from multi-grain aliquots. We therefore recommend analysis of individual grains to overcome the age-shortfall from multi-grain analysis of these and similar samples of quartz.  相似文献   
97.
以2~4 cm为间隔,对冲绳海槽北部的CSH1孔岩心(17.36 m)进行了岩石磁学研究.根据岩心上部的两个特征火山灰层和浮游有孔虫组合分析建立了钻孔的时间框架,沉积物底部年龄可能为50 ka.除了在三个火山灰层和近表层向下的快速降低外,整个钻孔磁学参数的变化甚小,未能反映出50 ka来的气候变化.与大多数沉积物不同,该钻孔大多数层位的S值(S=-IRM-0.3T/SIRM,它代表了低矫顽力磁性矿物的含量)小于0.9,指示钻孔沉积物中存在相当比例的高矫顽力磁性矿物.代表性沉积物样品的磁化率-温度(K-T)曲线除了存在580℃磁铁矿的居里温度之外,还显示200~350℃的居里温度,指示样品中存在铁硫化物(胶黄铁矿-磁黄铁矿).这与加热过程中有刺鼻的臭味、加热后的沉积物变黑对铁硫化物的指示相吻合.自生成因的铁硫化物的存在以及表层磁性参数的快速降低,都明确表明沉积物遭受了早期成岩作用.除了三个火山灰层以外钻孔的其他层位无特征磁学变化,表明沉积物后来受到的改造作用强烈,磁学参数所蕴含的原始气候信号被破坏.在这一系列氧化-还原过程中消耗了沉积物中的有机质和水溶液中的硫酸盐,造成了沉积物中铁、锰元素的重新溶解和沉淀等.  相似文献   
98.
Tephrostratigraphic correlations commonly rely on geochemical composition supported by additional constraints (e.g., multiple stratigraphically ordered tephra, geochronological-stratigraphical constraints, and isotopic determinations), which provide key clues to restrict the number of possible candidates and disambiguate the correlation of a specific tephra among compositionally similar volcanic sources/tephra. However, such additional data may not be available or acquirable, leaving the geochemical data as sole, but challenging viable approach. In this study, two geochronologically poorly constrained late Pleistocene tephra from the eastern Adriatic –from a sand profile on Mljet Island (M-53/2) and from a marine sediment core from Pirovac Bay (PROS 721)– were correlated to known eruptions using only geochemical data (major and trace elements of glass shards), which were treated using both log ratio transformed and raw data. After the statistical treatment of the geochemical data using bivariate plots, linear discrimination analyses and selbal algorithm, the tephra M-53/2 and PROS 721 were suitably correlated with the widespread tephra generated during the Campi Flegrei eruptions of Massereia del Monte (Y-3 marine tephra, 29.0 ± 0.8 ka) and Neapolitan Yellow Tuff (14.5 ± 0.4 ka), respectively. This study showed that the correlation was hardly tenable when using the raw data, as opposed to compositional approach, which yielded satisfactory results. As a consequence, the distribution of Massereia del Monte/Y-3 tephra extended far toward the northeast, while a better chronological model, for reconstructing the paleoenvironmental changes at the Pirovac Bay location and the Holocene sea-level dynamics, could be obtained.  相似文献   
99.
Comparatively few Icelandic tephra horizons dated to the early part of the Holocene have so far been detected outside Iceland. Here, I present several tephra horizons that have been recorded in a Holocene peat sequence on the Faroe Islands. Geochemical analyses show that at least two dacitic and one rhyolitic tephra layers were erupted from the Katla volcanic system on southern Iceland between ca. 8000 and 5900 cal. yr BP. The upper two layers can be correlated with the SILK tephras described from southern Iceland, whereas the third, dated to ca. 8000 cal. yr BP, has a geochemistry virtually identical to the rhyolitic component of the Vedde Ash. The results suggest that the Late Weichselian and early Holocene eruption history of the Katla volcano was probably more complex than inferred from Iceland. A new, early Holocene rhyolitic tephra dated to ca. 10 500 cal. yr BP probably originates in the Snæfellsnes volcanic centre in western Iceland. These new findings may play an important role in developing a Holocene tephra framework for northwest Europe. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
100.
Tephra fingerprinting techniques contributing to volcanology and palaeoenvironmental studies have been developed using a combination of laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS). In particular, femtosecond LA-ICP-MS can determine major- and trace element abundances in individual glass shards. On the basis of the major oxide and trace element composition of the glass shards, using those methods, we re-examined the identification of four lower Pleistocene tephras originating from north-east Japan. All trace element abundances exhibited the typical pattern of tephras from the Hokkaido–Tohoku area, and major element concentrations were distinct. As a result, we re-examined the correlation of the widespread Tmg-R4 tephra (2.0 Ma), and newly defined the widespread Kd44-Naka tephra (1.968–1.781 Ma), both originating from the Sengan geothermal region. Furthermore, we re-examined identifications of Sr-Asn-Kd8 (1.219 Ma) and Sr-Kc-U8 (0.922–0.910 Ma) in central Japan, both derived from the Aizu volcanic region. The extensive distributions of the former two tephras suggest the occurrence of two large caldera-forming eruptions (Volcanic Explosivity Index 7) during a short period. Also, the distributions and volumes of the latter two tephras are broader and larger than those previously assumed. The results provide insight into large volcanic eruption history and terrestrial and marine palaeoenvironmental history.  相似文献   
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