Diamond in metasedimentary crustal rocks from Pohorje,Eastern Alps: a window to deep continental subduction          下载免费PDF全文

M. Janák  N. Froitzheim  K. Yoshida  V. Sasinková  M. Nosko  T. Kobayashi  T. Hirajima  M. Vrabec 《Journal of Metamorphic Geology》2015,33(5):495-512

We report the first finding of diamond and moissanite in metasedimentary crustal rocks of Pohorje Mountains (Slovenia) in the Austroalpine ultrahigh‐pressure (UHP) metamorphic terrane of the Eastern Alps. Microscopic observations and Raman spectroscopy show that diamond occurs in situ as inclusions in garnet, being heterogeneously distributed. Under the optical microscope, diamond‐bearing inclusions are of cuboidal to rounded shape and of pinkish, yellow to brownish colour. The Raman spectra of the investigated diamond show a sharp, first order peak of sp³‐bonded carbon, in most cases centred between 1332 and 1330 cm^?1, with a full width at half maximum between 3 and 5 cm^?1. Several spectra show Raman bands typical for disordered graphitic (sp²‐bonded) carbon. Detailed observations show that diamond occurs either as a monomineralic, single‐crystal inclusion or it is associated with SiC (moissanite), CO₂ and CH₄ in polyphase inclusions_. This rare record of diamond occurring with moissanite as fluid‐inclusion daughter minerals implies the crystallization of diamond and moissanite from a supercritical fluid at reducing conditions. Thermodynamic modelling suggests that diamond‐bearing gneisses attained P–T conditions of ≥3.5 GPa and 800–850 °C, similar to eclogites and garnet peridotites. We argue that diamond formed when carbonaceous sediment underwent UHP metamorphism at mantle depth exceeding 100 km during continental subduction in the Late Cretaceous (c. 95–92 Ma). The finding of diamond confirms UHP metamorphism in the Pohorje Mountains, the most deeply subducted part of Austroalpine units.  相似文献   

北太平洋副热带模态水盐度的年代际变化     

胡睿坤  边志刚  刘子洲  刘聪  翟方国  顾艳镇 《中国海洋大学学报(自然科学版)》2020,(2):9-21

副热带模态水(Subtropical Mode Water;STMW)在气候变化中起着重要作用。本文利用全球高分辨率数值模拟结果,研究了北太平洋STMW核心层盐度(Core Layer Salinity;CLS)的年代际变化及其物理机制。结果表明,CLS存在显著的年代际变化,其空间分布则与背景流场分布特征有关。侵蚀区CLS滞后生成区CLS约1~2年,这主要是海流平流输运引起的。生成区内,STMW的季节循环一般可分为生成期(12-4月)、隔离期(5-6月)和侵蚀期(7-11月),生成期混合层盐度(Mixed Layer Salinity;MLS)决定着隔离期和侵蚀期的CLS,而MLS年代际变化则主要由同太平洋年代际涛动存在负相关性的海表面淡水通量的变化引起。  相似文献   

Phase equilibria modelling and LASS monazite petrochronology: P–T–t constraints on the evolution of the Priest River core complex,northern Idaho          下载免费PDF全文

L. M. Stevens  J. A. Baldwin  J. M. Cottle  A. R. C. Kylander‐Clark 《Journal of Metamorphic Geology》2015,33(4):385-411

Phase equilibria modelling, laser‐ablation split‐stream (LASS)‐ICP‐MS petrochronology and garnet trace‐element geochemistry are integrated to constrain the P–T–t history of the footwall of the Priest River metamorphic core complex, northern Idaho. Metapelitic, migmatitic gneisses of the Hauser Lake Gneiss contain the peak assemblage garnet + sillimanite + biotite ± muscovite + plagioclase + K‐feldspar ± rutile ± ilmenite + quartz. Interpreted P–T paths predict maximum pressures and peak metamorphic temperatures of ~9.6–10.3 kbar and ~785–790 °C. Monazite and xenotime ²⁰⁸Pb/²³²Th dates from porphyroblast inclusions indicate that metamorphism occurred at c. 74–54 Ma. Dates from HREE‐depleted monazite formed during prograde growth constrain peak metamorphism at c. 64 Ma near the centre of the complex, while dates from HREE‐enriched monazite constrain the timing of garnet breakdown during near‐isothermal decompression at c. 60–57 Ma. Near‐isothermal decompression to ~5.0–4.4 kbar was followed by cooling and further decompression. The youngest, HREE‐enriched monazite records leucosome crystallization at mid‐crustal levels c. 54–44 Ma. The northernmost sample records regional metamorphism during the emplacement of the Selkirk igneous complex (c. 94–81 Ma), Cretaceous–Tertiary metamorphism and limited Eocene exhumation. Similarities between the Priest River complex and other complexes of the northern North American Cordillera suggest shared regional metamorphic and exhumation histories; however, in contrast to complexes to the north, the Priest River contains less partial melt and no evidence for diapiric exhumation. Improved constraints on metamorphism, deformation, anatexis and exhumation provide greater insight into the initiation and evolution of metamorphic core complexes in the northern Cordillera, and in similar tectonic settings elsewhere.  相似文献   

Significance of shallow core transects for reef models and sea‐level curves,Heron Reef,Great Barrier Reef          下载免费PDF全文

Gregory E. Webb  Luke D. Nothdurft  Jian‐Xin Zhao  Bradley Opdyke  Gilbert Price 《Sedimentology》2016,63(6):1396-1424

A sequence of shallow reef cores from Heron Reef, Great Barrier Reef, provides new insights into Holocene reef growth models. Isochron analysis of a leeward core transect suggests that the north‐western end of Heron Reef reached current sea‐level by ca 6·5 kyr bp and then prograded leeward at a rate of ca 19·6 m/kyr between 5·1 kyr and 4·1 kyr bp (pre‐1950) to the present reef margin. A single short core on the opposing margin of the reef is consistent with greater and more recent progradation there. Further to the east, one windward core reached modern sea‐level by ca 6·3 kyr bp , suggesting near ‘keep‐up’ behaviour at that location, but the opposing leeward margin behind the lagoon reached sea‐level much more recently. Hence, Heron Reef exhibited significantly different reef growth behaviour on different parts of the same margin. Mean reef accretion rates calculated from within 20 m of one another in the leeward core transect varied between ca 2·9 m and 4·7 m/kyr depending on relative position in the prograding wedge. These cores serve as a warning regarding the use of isolated cores to inform reef growth rates because apparent aggradation at any given location on a reef varies depending on its location relative to a prograding margin. Only transects of closely spaced cores can document reef behaviour adequately so as to inform reef growth models and sea‐level curves. The cores also emphasize potential problems in U‐series dates for corals within a shallow (ca 1·5 m) zone beneath the reef flat. Apparent age inversions restricted to that active diagenetic zone may reflect remobilization and concentration of Th in irregularly distributed microbialites or biofilms that were missed during sample vetting. Importantly, the Th‐containing contaminant causes ages to appear too old, rather than too young, as would be expected from younger cement.  相似文献   

Smoothing and re-roughening processes: The geometric evolution of a single fault zone     

《Journal of Structural Geology》2016

The geometry of a fault zone exerts a major control on earthquake rupture processes and source parameters. Observations previously compiled from multiple faults suggest that fault surface shape evolves with displacement, but the specific processes driving the evolution of fault geometry within a single fault zone are not well understood. Here, we characterize the deformation history and geometry of an extraordinarily well-exposed fault using maps of cross-sectional exposures constructed with the Structure from Motion photogrammetric method. The La Quinta Fault, located in southern California, experienced at least three phases of deformation. Multiple layers of ultracataclasite formed during the most recent phase. Crosscutting relations between the layers define the evolution of the structures and demonstrate that new layers formed successively during the deformation history. Wear processes such as grain plucking from one layer into a younger layer and truncation of asperities at layer edges indicate that the layers were slip zones and the contacts between them slip surfaces. Slip surfaces that were not reactivated or modified after they were abandoned exhibit self-affine geometry, preserving the fault roughness from different stages of faulting. Roughness varies little between surfaces, except the last slip zone to form in the fault, which is the smoothest. This layer contains a distinct mineral assemblage, indicating that the composition of the fault rock exerts a control on roughness. In contrast, the similar roughness of the older slip zones, which have comparable mineralogy but clearly crosscut one another, suggests that as the fault matured the roughness of the active slip surface stayed approximately constant. Wear processes affected these layers, so for roughness to stay constant the roughening and smoothing effects of fault slip must have been approximately balanced. These observations suggest fault surface evolution occurs by nucleation of new surfaces and wear by competing smoothing and re-roughening processes.  相似文献   

Shale Gas Formation and Occurrence in China: An Overview of the Current Status and Future Potential     

ZOU Caineng  YANG Zhi  PAN Songqi  CHEN Yanyan  LIN Senhu  HUANG Jinliang  WU Songtao  DONG Dazhong  WANG Shufang  LIANG Feng  SUN Shash  HUANG Yong  WENG Dingwei 《《地质学报》英文版》2016,90(4):1249-1283

Shale gas is one of the most promising unconventional resources both in China and abroad. It is known as a form of self-contained source-reservoir system with large and continuous dimensions. Through years of considerable exploration efforts, China has identified three large shale gas fields in the Fuling, Changning and Weiyuan areas of the Sichuan Basin, and has announced more than 540 billion m~3 of proven shale gas reserves in marine shale systems. The geological theories for shale gas development have progressed rapidly in China as well. For example, the new depositional patterns have been introduced for deciphering the paleogeography and sedimentary systems of the Wufeng shale and Longmaxi shale in the Sichuan Basin. The shale gas storage mechanism has been widely accepted as differing from conventional natural gas in that it is adsorbed on organic matter or a mineral surface or occurs as free gas trapped in pores and fractures of the shale. Significant advances in the techniques of microstructural characterization have provided new insights on how gas molecules are stored in micro- and nano-scale porous shales. Furthermore, newly-developed concepts and practices in the petroleum industry, such as hydraulic fracturing, microseismic monitoring and multiwell horizontal drilling, have made the production of this unevenly distributed but promising unconventional natural gas a reality. China has 10–36 trillion m~3 of promising shale gas among the world's whole predicted technically recoverable reserves of 206.6 trillion m~3. China is on the way to achieving its goal of an annual yield of 30–50 billion m~3 by launching more trials within shale gas projects.  相似文献   

庐枞LZSD-1孔科学钻孔钻头选择与使用     

余善平 《安徽地质》2016,26(1):36-37

受中国地质科学院地质研究所的委托,安徽省地质矿产勘查局313地质队承担《华东庐枞盆地科学钻探选址预研究》3000m科学钻探工程任务,该钻孔为大陆科学钻探选址预研究项目中6个钻孔之一,主要目的是通过钻探揭示和验证与成矿有关的岩体、基底、盖层的空间分布,建立地壳结构模型和异常解释的标尺,为大陆万米钻探提供选址依据。本文主要介绍了在施工过程中的钻头选用情况,仅供同行参考。  相似文献   

高压下天然菱铁矿的压缩性和电子结构研究     

高静  巫翔  秦善  张硕  杨科  李晓东 《岩石矿物学杂志》2016,35(2):276-282

采用同步辐射光源和金刚石对顶砧(DAC)技术,对天然菱铁矿的压缩性和电子结构进行了原位X射线衍射(XRD)和X射线吸收近边结构谱(XANES)测试研究。在室温下随着压力逐渐升高至50.2 GPa,菱铁矿保持方解石型结构不变,但是逐渐向Na Cl型结构转变;刚性[CO3]2-基团平行于ab-平面定向排列使c轴的压缩性大于a轴。菱铁矿在44.6~47.1 GPa之间发生电子由高自旋态(HS)向低自旋态(LS)的转变,表现为体积塌陷8%。HS菱铁矿的等温状态方程参数为K0=112(5)GPa和K'0=4.6(3)。首次采用XANES技术对菱铁矿中Fe2+的电子结构进行了研究,结果表明:随着压力升高至37.3 GPa,Fe2+的配位和局域对称并未发生明显变化;此后电子结构开始转变,Fe2+的3d轨道分裂能降低,电子跃迁概率增大,呈现LS特性。  相似文献   

辽南金州拆离断层带中花岗质岩石的变形:显微构造、组构与年代学分析   总被引：1，自引：0，他引：1  

蒋浩  刘俊来  张雎易  郑媛媛 《岩石学报》2016,32(9):2707-2722

花岗岩(脉)在中下地壳韧性剪切带中普遍发育,如何正确鉴别剪切带中剪切前、剪切期及剪切后花岗岩(脉)以及正确理解剪切过程中构造变形与岩浆作用之间的关系一直是一个重要课题。本文以辽南金州拆离断层带为研究对象,选取中部地壳伸展作用过程中具有不同变形表现的花岗岩(脉)开展宏观-微观构造观察、石英EBSD组构分析及锆石LA-ICP-MS年代学测试等工作,从而进一步丰富构造-岩浆关系判别准则。剪切前花岗岩(脉)多变形强烈且具有后期固态变形叠加在早期高温岩浆组构之上的特点,而剪切期的花岗岩由于侵位的时间不同,岩石的变形程度也会不同。剪切晚期侵入的岩脉遭受了较弱的晶内塑性变形,而剪切早期的岩脉可以显示岩浆流动或结晶后高温至中温固态变形。从组构特点上看,剪切前和剪切期花岗质岩石石英c轴组构大多表现为中高温组构叠加有低温组构的特点。剪切后的花岗质岩石仅发生微弱的晶内变形或未变形而显示低温或无规律的组构特征。对五个典型的样品进行年代学测试,其结果符合相应的期次划分类型。应用宏观构造、显微构造与组构分析,结合年代学测试综合分析,对于辽南变质核杂岩构造-岩浆活动性进行了精细划分,包括134~130Ma初始伸展阶段,130~115Ma峰期伸展与强烈岩浆活动阶段,以及115Ma前后伸展作用结束。  相似文献   

我国地质钻探现状和发展前景分析          下载免费PDF全文

王达  李艺  周红军  刘跃进  张林霞  孙建华 《探矿工程》2016,43(4):1-9

我国经济社会发展已步入“新常态”。作为地质调查和矿产勘查工作重要技术支撑的地质钻探行业,资金投入显著减少,地质钻探工作量大幅下滑,常规钻探施工产能过剩;另一方面,地质钻探新的服务领域不断扩大,包括深部科学钻探,地热能及非常规能源勘查,海洋、灾害防治、生态环境、地外天体、极地方面的钻探等。如何应对地勘行业出现的问题,是全行业共同面对的挑战。在对当前及今后一段时期地质钻探工程面临的困难、挑战和机遇等进行调研分析的基础上,对我国地质钻探未来的发展前景进行了预测,认为地质钻探工作量将进一步减少,新领域、新业态的钻探工程及先进钻探技术和装备需求将进一步加大,更加贴近国家需求,更加注重环保理念。  相似文献