ICP-AES法测定金属硅中硼磷铝锰钙镁铁等28种微量和痕量元素     

乔爱香  江冶  李如燕 《江苏地质》2021,45(4):450-454

采用ICP-AES法对金属硅中的B、P、Al、Mn、Ca、Mg、Fe等28种微量和痕量元素进行分析。根据元素的化学性质制定预处理方法,优化ICP-AES光谱仪测试样品的最佳工作条件。在缺少金属硅标准物质的情况下,选择硅含量较高的国家一级岩石标准物质（GBW07106）进行试验,该标准物质的回收率在95.0%～104.4%之间,相对标准偏差RSD在0.21%～4.01%之间。实际分析工作表明,该方法准确、快速,符合DZ/T 0130—2006的要求。  相似文献   

三峡库区紫色土微量元素含量的变化   总被引：3，自引：3，他引：0  

董杰  杨达源  周彬  陈可锋  胥勤勉 《地理科学》2006,26(5):592-596

以三峡库区典型坡面紫色土为例,对土壤中微量元素的含量及其在不同坡度、不同利用方式下的变化进行初步研究。结果表明,库区紫色土中Fe、Mn、Ni、Zr、Sr和Ti的含量相对较多,Mo的含量较为丰富,Zn和Pb的含量相对较低。Pb、Cu和Co的含量在一定坡度范围内随坡地坡度的增大而减少,Zr和Cr的含量则增加。紫色土中Cu、Pb、Co、Ti、Zr、Ni、Cr、Sr等微量元素的含量随坡度的变化具有一定的相关性。耕作土和非耕作土中微量元素含量差异明显,人为活动是引起库区紫色土微量元素含量变化的主要因素。  相似文献   

河北省北部晶质石墨矿层岩(矿)石地球化学特征与成因分析     

翟大兴  石姝华  郑丽超  杨四路  邢金蕊  韩冀春  刘少普 《地球学报》2024,45(3):375-385

晶质石墨是一种新兴战略矿产。近年在河北省北部发现了多处大中型晶质石墨矿床,主要赋矿层位于新太古代崇礼上岩群、古元古代红旗营子岩群等,具有良好的成矿潜力。通过系统的野外地质调查与采样、分析测试工作,详细研究了赋矿层位的岩相学、地球化学特征,并对碳质来源进行了分析。结果表明:赋矿岩石主要为含石墨黑云斜长变粒岩、片麻岩与透辉岩,原岩恢复以砂泥质碎屑岩、钙质沉积岩为主。主量元素含量变化较大, SiO₂含量为38.90%～80.42%, CaO+MgO为2.05%～31.93%, Al₂O₃为1.50%～15.34%;稀土元素含量为79.1～321.4μg/g, PAAS标准化分布模式一般具有右倾或较平坦分布特征, δCe略具负异常,部分具有δEu异常。微量元素特征指示沉积环境为滨浅海环境,部分地区存在富氧条件,局部为还原环境或存在热液加入。石墨中碳同位素值为–26.0‰～–20.7‰,主要来源于生物成因有机碳;大理岩碳同位素值为–3.8‰～1.1‰,主要来源于碳酸盐岩成因无机碳。区内晶质石墨矿层分布受到地层、岩性、岩相控制,含矿...  相似文献   

南海西南部晚更新世以来元素地球化学特征的古环境意义   总被引：3，自引：0，他引：3  

乔培军  邵磊  杨守业 《海洋地质与第四纪地质》2006,26(4):59-65

对南海西南部近湄公河三角洲中陆坡上的MD01-2392站样品进行的地球化学分析表明,该站的沉积物主要为湄公河带来的陆源碎屑,并且其物源四十万年来没有发生明显变化。分别用元素TiO2、CaO估算出沉积物中陆源碎屑的含量及CaCO3的含量,结果显示CaCO3在间冰期时高,而在冰期时低,表现出“大西洋旋回”的特征。陆源碎屑含量与CaCO3含量相反,显示出南海CaCO3旋回属于稀释旋回。元素的Ti标准化值表明,该站沉积物源区在冰期时化学风化弱,而在间冰期时相对较强,说明间冰期时物源区存在相对温暖湿润的气候环境。  相似文献   

湖相介形类壳体微量元素在古环境重建中的应用     

姜高磊  刘林敬  毛欣 《海洋地质与第四纪地质》2020,40(2):192-199

湖相介形类壳体微量元素(本文主要指Mg和Sr)是重建古环境的重要指标之一,可以定性或定量地反映湖水信息。自20世纪80年开始应用以来,经过30余年的发展取得了很大进展。在古环境重建过程中主要存在两类影响因素:(1)其宿生水体中M/Ca比值(M主要指Mg和Sr)的影响因素:季节变化、微环境差异和湖泊演化过程,这类因素通过对宿生水体中M/Ca比值来影响介形虫壳体中的M/Ca比值,进而造成古环境重建结果的误差增大或可靠性降低;(2)介形类壳体微量元素分配系数的影响因素:宿生水体中M/Ca比值、温度、碱度等,这类因素能够直接影响介形类壳体分泌、钙化的生命-化学过程的因素,是定量重建的重要影响因素。加强现代介形类生活习性和微量元素组成变化过程的研究可以消除或减小以上影响因素对古环境重建的影响,提高介形类壳体化石中微量元素组成在古环境重建研究中的精度和可靠性。  相似文献   

应用P-T-t理论再认识辽河群变质作用     

郭伟静  郭洪芳 《地质与资源》2006,15(3):230-237

辽河群是出露于辽宁省东部的独具特色的古元古代变质岩系,赋存丰富的矿产资源,研究历史悠久.但对有关辽河群变质作用的一些重要问题上看法诸多,很难取得一致意见.本文应用P-T-t轨迹理论重新认识这些问题,认为引起辽河群变质作用的根本原因是大陆碰撞造山带使辽河群俯冲到地下深处;辽河群变质作用在时间上和空间上有独特的演化特征;辽河群变质作用与不同规模的构造或不同层次的构造的关系是不一样的.  相似文献   

滇西姚安金矿床磷灰石化学特征及指示意义     

郑瑜林  张长青  刘欢  孙嘉  张盼盼 《矿床地质》2021,40(1):156-168

姚安金矿床位于金沙江-哀牢山富碱斑岩带中段,大地构造位置处于扬子板块西缘与三江特提斯造山带结合部位,其成矿与新生代富碱岩浆-岩浆热液密切相关.野外调查发现矿化仅存在于黑云母正长斑岩体内,而与黑云母正长斑岩空间关系密切的石英正长斑岩却未发现矿化.为探讨黑云母正长斑岩与石英正长斑岩岩体含矿性差异,运用电子探针、LA-ICP...  相似文献   

70年来中国化学海洋学研究的主要进展   总被引：5，自引：3，他引：2  

宋金明  王启栋  张润  陈建芳  陈敏  徐忠胜 《海洋学报》2019,41(10):65-80

我国的海洋化学工作者通过70年来,特别是近30年来的化学海洋学研究,实现了我国与世界先进水平进入同步发展的快车道,其显著的特点是:(1)化学海洋学研究从元素地球化学分布系统转向了以揭示深层次海洋生物地球化学过程为核心的研究;(2)化学海洋学研究实现了多领域、多视点的综合交叉研究;(3)更加关注了人为影响与自然变化共同作用下的海洋生态环境变化研究,对近海和海岸带而言,更加注重从海陆统筹一体化角度探析化学物质的分布迁移特征。本文从生源要素的海洋生物地球化学过程、微/痕量元素与同位素的海洋化学研究、生物过程作用下的化学海洋学过程等角度,重点总结归纳和分析了30年来我国海洋化学研究的重要进展和发展状况,以期对化学海洋学的进一步研究提供借鉴和启迪。  相似文献   

Isotopic,trace element and nutrient characterization of coastal waters from Ubatuba inner shelf area,south-eastern Brazil     

P.P. Povinec  J. de Oliveira  E.S. Braga  J.-F. Comanducci  J. Gastaud  M. Groening  I. Levy-Palomo  U. Morgenstern  Z. Top 《Estuarine, Coastal and Shelf Science》2008

Stable isotopes, tritium, radium isotopes, radon, trace elements and nutrients data were collected during two sampling campaigns in the Ubatuba coastal area (south-eastern Brazil) with the aim of investigating submarine groundwater discharge (SGD) in the region. The isotopic composition (δD, δ¹⁸O, ³H) of submarine waters was characterised by significant variability and heavy isotope enrichment. The stable isotopes and tritium data showed good separation of groundwater and seawater groups. The contribution of groundwater in submarine waters varied from a few % to 17%. Spatial distribution of ²²²Rn activity concentration in surface seawater revealed changes between 50 and 200 Bq m⁻³ which were in opposite relationship with observed salinities. Time series measurements of ²²²Rn activity concentration in Flamengo Bay (from 1 to 5 kBq m⁻³), obtained by in situ underwater gamma-spectrometry showed a negative correlation between the ²²²Rn activity concentration and tide/salinity. This may be caused by sea level changes as tide effects induce variations of hydraulic gradients, which increase ²²²Rn concentration during lower sea level, and opposite, during high tides where the ²²²Rn activity concentration is smaller. The estimated SGD fluxes varied during 22–26 November between 8 and 40 cm d⁻¹, with an average value of 21 cm d⁻¹ (the unit is cm³/cm² per day). The radium isotopes and nutrient data showed scattered distributions with offshore distance and salinity, which implies that in a complex coast with many small bays and islands, the area has been influenced by local currents and groundwater–seawater mixing. SGD in the Ubatuba area is fed by coastal contaminated groundwater and re-circulated seawater (with small admixtures of groundwater), which claims for potential environmental concern with implications on the management of freshwater resources in the region.  相似文献   

Otolith chemical signature and growth of Chaetodon speculum in coastal areas of New Caledonia     

M. Labonne  E. Morize  M. Kulbicki  D. Ponton  L. Marec 《Estuarine, Coastal and Shelf Science》2008

Coral reefs are one of the most diverse ecosystems on Earth. They are currently exposed to increasing levels of anthropogenic perturbations. Several recent reviews point to the lack of good indicators for these perturbations especially to monitor their effects on fish populations or fish assemblages. The SW lagoon of New Caledonia is an ideal location to test indicator species in this context as contrasting sites are present within a small geographical range. This study analysed fish from four sites, one with heavy industrial pollution, another dominated by domestic waste, a third with historic mining activities, and the fourth as a control. The butterfly fish, Chaetodon speculum, was chosen to determine C. speculum's potential as an indicator species due to its link to coral, its sedentary behaviour and its wide geographical distribution. The size distribution, growth rate, age distribution and whole otolith composition were analysed at each site. Age and mean growth rate were analysed from daily increments of the otoliths. The concentrations of eight elements (Li, Mg, Co, Ni, Cu, Rb, Sr, and Ba) were measured by ICP-MS in the otoliths of a subset of individuals. The sites under anthropogenic impact were distinct from the control site by fish size frequencies, age distributions, and the chemical content of their otoliths. The chemical elements Mg, Co, Ni, Cu, and Rb showed differences amongst sites. Fish belonging to the sites furthest from Nouméa could be discriminated in nearly 80% of samples or 60% of the cases when otolith weight or fish age respectively were taken into account. Ni concentrations of the otoliths were also higher in the bays where water concentrations of this element were known to be higher, but these differences were no longer significant once corrected for otolith weight. These results should be mitigated by the fact that: (1) despite significant differences between sites in age distribution and size frequencies there were no differences in growth rates or body condition; (2) differences in age or size were not correlated to perturbation levels; and (3) discrimination between sites based on chemical levels in the otoliths, even though significant, was not sufficient to identify the origin of the fish at a level useful for screening tests. The hypothesis that environmental differences between sites would be reflected in the otolith chemical composition is therefore not fully supported by our results.  相似文献