能量色散X射线荧光光谱法测定卤水中痕量溴铷砷   总被引：3，自引：4，他引：3  

樊兴涛  詹秀春  巩爱华 《岩矿测试》2004,23(1):15-18

用模拟卤水建立了能量色散X射线荧光光谱法测定卤水中溴、铷、砷痕量元素含量的方法.实验表明,方法可以直接取样测定,适用于大批量样品的测试分析.方法的精密度RSD(n＝15)小于1%,加标回收率为86.8%～101.6%.卤水中溴、铷、砷的测定结果与比色法、原子吸收和原子荧光法结果相符.  相似文献   

发射光谱载体蒸馏法测定地质样品中微量硼铍锡银   总被引：2，自引：2，他引：2  

李滦宁  赵淑杰  王烨 《岩矿测试》2004,23(1):30-32

选择了适合的缓冲剂,利用载体蒸馏法将被测元素与基体元素分离,使Be转变为易挥发的氟化物与B、Sn、Ag同时蒸发;降低了谱线背景及元素检出限;加入内标元素Au、Bi,提高了方法的准确度和精密度;采用普通 3mm×3mm×0.7mm杯型电极,装样量少,操作简单。方法检出限(wB/10-6)分别可达B1.5、Be0.3、Sn0.8、Ag0.02;准确度(Δlog C)基本在-0.05～0.05,精密度(RSD,n=8)为2.9%～17%。  相似文献   

高倍稀释熔融制样X射线荧光光谱测定钨砂和铬铁矿中主含量   总被引：4，自引：5，他引：4  

吴秀兰  朱明达  张志峰  王伊琴 《岩矿测试》2004,23(1):73-74

用X射线荧光光谱测定钨砂中WO3和铬铁矿中Cr2O3,通过高倍稀释熔融玻璃片制样法,采用高纯WO3或Cr2O3作单一标准样测量X射线荧光强度计数,然后同未知样品测量所得X射线荧光强度计数相比,即可计算出WO3和Cr2O3的测量值.方法用于钨砂矿和铬铁矿中WO3和Cr2O3的测定,结果与标准值相符.  相似文献   

大兴安岭地区浅覆盖层对地面伽马能谱测量的影响   总被引：1，自引：2，他引：1  

刘菁华  王祝文  郝立波  田钢 《物探与化探》2004,28(2):111-113

讨论在大兴安岭地区进行地质填图中浅覆盖层对伽马能谱测量的影响问题。通过放射性元素的取样分析、岩石—土壤的矿物分析以及实测剖面分析,得知了伽马能谱测量的影响因素,从而为应用伽马能谱测量解决地质填图中的问题提供了依据。  相似文献   

The magmatic to hydrothermal transition and its bearing on ore-forming systems   总被引：1，自引：0，他引：1  

Werner E. Halter  James D. Webster 《Chemical Geology》2004,210(1-4):1-6

The exsolution of volatile phases from silicate magmas controls physical and chemical magma properties and influences large-scale geologic phenomena and processes having major societal and economic implications including the release of climate-altering gases to the atmosphere, the explosivity of volcanic eruptions, hydrothermal alteration, and the generation of magmatic–hydrothermal mineralization. These volatile phases exsolve from a wide variety of magmas and cover a very broad spectrum of compositions.

The transition from the orthomagmatic to the hydrothermal stages has important bearing on these fundamentally important geologic phenomena, and this report summarizes the published results of a dozen scientific investigations on the magmatic–hydrothermal transition as applied to volcanic eruption and magmatic–hydrothermal mineralization. These studies involve a variety of analytical and experimental methodologies, and many focus on fluid and melt inclusions from mineralized magmatic systems. A primary goal of each study is to better understand the role of magmatic volatiles and the importance of the magmatic–hydrothermal transition on these geologic processes.  相似文献   

Holocene calcrete crust deposits on the moraine of Batura Glacier, northern Pakistan     

Tetsuya  Waragai 《Island Arc》2005,14(4):368-377

Abstract   Calcretes can be observed on the surface of old moraines around Batura Glacier in the upper Hunza Valley, Karakoram Mountains, Pakistan. They develop as a calcareous crust cementing small gravels under boulders. In order to understand the genesis of the calcrete crust, a variety of methods were employed: (i) study of mineralogy and geochemistry of a calcrete crust precipitated on the lateral moraine using X-ray diffractometer and electron probe microanalysis; (ii) analysis of solute chemistry of surface water and ice bodies around the Batura Glacier; and (iii) accelerator mass spectrometry ¹⁴C dating of the crust itself. The results indicate that the calcrete crust has definite laminated layers composed of a fine-grain and compact calcite layer, and a mineral fragment layer. The chemical composition of the calcite layer is approximately 60% CaO and 1% MgO. The mineral fragment layer consists of rounded grain materials up to 0.2 mm in diameter. It shows a graded bedding structure with fine grains of quartz, albite and muscovite. Meanwhile, as the Paleozoic Pasu limestone is distributed around the terminal of Batura Glacier, Ca cations dissolve in the melt water of the glacier. Accordingly, the calcrete crust is precipitated by decreases in CO₂ partial pressure from glacier ice and evaporation of the melt water, including high concentration of Ca²⁺ at ephemeral streams and small ponds stagnating between the moraine and glacial ice. On the basis of the AMS ¹⁴C age, the calcrete is considered to have formed approximately 8200 calibrated years bp under the Batura glacial stage.  相似文献   

Developing efficient scalar and vector intensity measures for IDA capacity estimation by incorporating elastic spectral shape information     

Dimitrios Vamvatsikos  C. Allin Cornell 《地震工程与结构动力学》2005,34(13):1573-1600

Scalar and vector intensity measures are developed for the efficient estimation of limit‐state capacities through incremental dynamic analysis (IDA) by exploiting the elastic spectral shape of individual records. IDA is a powerful analysis method that involves subjecting a structural model to several ground motion records, each scaled to multiple levels of intensity (measured by the intensity measure or IM), thus producing curves of structural response parameterized by the IM on top of which limit‐states can be defined and corresponding capacities can be calculated. When traditional IMs are used, such as the peak ground acceleration or the first‐mode spectral acceleration, the IM‐values of the capacities can display large record‐to‐record variability, forcing the use of many records to achieve reliable results. By using single optimal spectral values as well as vectors and scalar combinations of them on three multistorey buildings significant dispersion reductions are realized. Furthermore, IDA is extended to vector IMs, resulting in intricate fractile IDA surfaces. The results reveal the most influential spectral regions/periods for each limit‐state and building, illustrating the evolution of such periods as the seismic intensity and the structural response increase towards global collapse. The ordinates of the elastic spectrum and the spectral shape of each individual record are found to significantly influence the seismic performance and they are shown to provide promising candidates for highly efficient IMs. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

石墨炉原子吸收光谱法测定土壤样品中镉   总被引：5，自引：0，他引：5  

卞莉  曹萍 《吉林地质》2005,24(2):115-117

采用磷酸氢二铵作基体改进剂塞曼扣背景石墨炉原子吸收光谱法测定土壤样品中镉，方法检出限DL=0．012μg／g，精密度RSD在3．55％～7．33％，满足了土壤样品中镉测定的镉质量要求。  相似文献   

Contesting ‘Local’ Commemoration of the Second World War: the case of the Changi Chapel and Museum in Singapore     

Hamzah Muzaini  Brenda S. A. Yeoh 《The Australian geographer》2005,36(1):1-17

This paper concerns the performance of national war memory at the Changi Chapel and Museum, a site honouring the many prisoners interned in Japanese-Occupied Singapore—especially at Changi—during the Second World War. In the light of the global nature of ‘the Changi story’, and the predominantly transnational nature of its present in situ memorialisation, we first examine how the Singapore state has sought to ‘localise’ the site to make it equally appealing to Singaporeans, as a place where a sense of their ‘shared history’ may be invoked. We then explore the Singaporeans' views about the site and its reconfiguration as a national icon, arguing how the state's task of ‘localising’ the site has been a vexed process due to myriad factors such as ethnic and religious plurality, and the already foreign-centric bias of prevailing knowledge about Changi. Following that, we show how this performance of national memory is also inflected by Australia's national remembrance of the same event. More broadly, we highlight the contested process of ‘localising’ such war memoryscapes as national iconography, suggesting how it may be more fruitful to conceive them as ‘international memoryscapes’, or places to which all individuals can relate regardless of race or national affiliations.  相似文献   

Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths   总被引：5，自引：1，他引：5  

Marcel Guillong  Kathrin Hametner  Eric Reusser  Stephen A. Wilson  Detlef Günther 《Geostandards and Geoanalytical Research》2005,29(3):315-331

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.  相似文献