Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Predicting quantiles of water quality from catchment characteristics     

Danlu Guo  Shuci Liu  Dhananjay Singh  Andrew W. Western 《水文研究》2021,35(1):e13996

Water quality is often highly variable both in space and time, which poses challenges for modelling the more extreme concentrations. This study developed an alternative approach to predicting water quality quantiles at individual locations. We focused on river water quality data that were collected over 25 years, at 102 catchments across the State of Victoria, Australia. We analysed and modelled spatial patterns of the 10th, 25th, 50th, 75th and 90th percentiles of the concentrations of sediments, nutrients and salt, with six common constituents: total suspended solids (TSS), total phosphorus (TP), filterable reactive phosphorus (FRP), total Kjeldahl nitrogen (TKN), nitrate-nitrite (NO_x), and electrical conductivity (EC). To predict the spatial variation of each quantile for each constituent, we developed statistical regression models and exhaustively searched through 50 catchment characteristics to identify the best set of predictors for that quantile. The models predict the spatial variation in individual quantiles of TSS, TKN and EC well (66%–96% spatial variation explained), while those for TP, FRP and NO_x have lower performance (37%–73% spatial variation explained). The most common factors that influence the spatial variations of the different constituents and quantiles are: annual temperature, percentage of cropping land area in catchment and channel slope. The statistical models developed can be used to predict how low- and high-concentration quantiles change with landscape characteristics, and thus provide a useful tool for catchment managers to inform planning and policy making with changing climate and land use conditions.  相似文献   

基于灯光数据的京津冀城市多标度异速分析     

龙玉清  陈彦光 《地理科学进展》2019,38(1):88-100

城镇体系的时空演化是一个复杂的动力学过程,具有无尺度性,其特征可以采用异速标度指数定量描述。论文以京津冀为例,基于1992—2013年夜间灯光数据的校正结果,提取城镇夜间灯光信息,采用多标度异速分析方法,分析京津冀城镇体系的相对发展特征及其空间分异格局。研究发现：①京津冀大城市的增长空间局限日益显著。虽然大城市如京津唐的绝对发展水平高,但接近环境承载量的极限,22 a间增长快速的是大城市交接地带的小城市(如三河、迁安、廊坊等)。②相对增长速度快的城市从东北到西南呈现带状分布——政府选择发展的“雄安新区”就在这个轴带上。由此可以得出两个结论：其一,京津冀城市演化的趋势相对均衡化,空间结构异质性逐步减弱,整个城镇体系的发展趋于相对平衡状态;其二,大、小城市“两极”贯通或许是增强城镇体系功能的有效途径。京津冀的空间格局优化不能仅仅考虑主要的、规模大的中心城市,而应该基于等级结构协调整个城镇网络体系。  相似文献   

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N   总被引：1，自引：0，他引：1  

荣坤波  曾志刚  殷学博  陈帅  王晓媛  齐海燕  马瑶 《海洋学报(英文版)》2018,37(9):67-81

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.  相似文献   

基于SODA资料的南海表层风能输入的空间分布与长期趋势研究     

杨倩  崔超然  张宇  刘志宇  管玉平  黄瑞新 《热带海洋学报》2018,37(6):41-48

海面风不仅是驱动上层海洋运动的主要动力, 其能量也是维持海洋表层流动的主要机械能来源。为了分析南海表层流风能输入的变化, 用SODA(Simple Ocean Data Assimilation)(1901—2010)资料估算了风向南海表层流(表层地转流+表层非地转流)的能量输入。结果表明, 风向南海表层流、表层地转流和表层非地转流输入的能量总体均呈减少趋势, 110年间分别减小了约56%、65%和49%。导致风能输入减小的最主要因素是风应力的减弱(减小了35%)。由于南海受季风系统的控制, 风向表层流及其各成分输入的能量呈现出显著的季节性变化。冬季风能输入最强, 高值区位于南海西部及北部区域, 呈一个显著的“回力镖”状结构。这些结果对深入认识南海环流具有理论意义。  相似文献   

环塔里木盆地绿洲城市发展与水环境质量协调度     

孜比布拉·司马义  杨胜天  杨晓东  王蕾  肖合来提·巴义 《中国沙漠》2020,40(1):88-96

解决好新疆环塔里木盆地绿洲城市发展与水环境质量之间的关系，对"一带一路"倡议顺利实施及新疆社会稳定具有十分重要的作用。基于2004-2017年环塔里木盆地绿洲城市发展与水环境变化状况，构建城市发展与水环境质量的综合评价模型及二者的协调度模型，以探讨环塔里木盆地绿洲城市发展、水环境质量变化及二者的协调关系。结果表明：2004-2017年，（1）环塔里木盆地绿洲城市发展综合指数呈现出逐年稳定上升的趋势，经济发展和城镇空间规模扩大是环塔里木盆地绿洲城市发展的主要形式；（2）环塔里木盆地绿洲城市的水环境质量综合指数呈现出逐年降低的趋势，水环境质量形势严峻；（3）环塔里木盆地绿洲城市发展-水环境质量系统的协调度呈现倒U型的稳定发展趋势，但总体上两者的协调度较低，城市发展和水环境质量之间的矛盾日益突出。  相似文献   

基于MODIS数据的湖北省地级以上城市城区地表温度变化分析     

李韶颖  车风  邵军  陈涛  周婧娟 《测绘与空间地理信息》2020,(2):76-78

基于MODIS数据,以湖北省地级以上城市城区为研究对象,通过对湖北省13个地级以上城市城区边界矢量数据与地表温度因子进行套合处理,采用叠置分析方法对2000、2015、2017年湖北省地级以上城市城区的地表温度进行统计,并分析城镇化建设对城区地表温度产生的影响。  相似文献   

贵州夜郎湖表层水体地球化学昼夜变化及其影响因素     

王家录  任娟  王勇  李维杰  娄昭  陈佳 《热带地理》2020,40(2):335-345

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。  相似文献   

关中平原城市群植被覆盖的时空特征与影响因素   总被引：2，自引：0，他引：2       下载免费PDF全文

王治国  白永平  车磊  陈志杰  乔富伟 《干旱区地理》2020,43(4):1041-1050

植被是全球及区域生态系统环境变化的重要指标,也是对人类社会活动有重要贡献的资源之一。为了研究关中平原城市群不同区域植被覆盖变化对自然和人文因子的响应,以划分为三个区域的植被作为研究对象,选取2000—2017年MODIS-NDVI遥感数据,运用趋势分析、探索性空间数据分析与地理探测器等方法,从时序演进与空间分布方面研究了18 a内植被覆盖的演化及分布特征,定量分析影响植被覆盖的主导因子。遥感数据要通过投影转换、拼接、最大值合成等方法进行处理,再运用Python程序进行影像批量裁剪,将遥感数据和气象数据进行分区统计,最后对该处理数据进行讨论研究。结论表明：（1） 研究期内关中平原城市群植被覆盖呈显著上升趋势,NDVI平均值增速为0.077·（10 a）^–1,阶段性变化特征明显,其中2005—2007阶段和2011—2013阶段极显著增加,最大上升速率达到了0.05·a^–1。（2） 空间上总体呈现“南高北低”的分布特征,研究区总体得到改善;高值区主要分布在南部秦岭北坡,受气候因子的影响更大,植被覆盖增加速度缓慢,达到轻度改善水平;低值区聚集在黄土高原边缘地区,植被增加趋势明显;中部关中平原极少部分地区植被覆盖出现了轻度退化或严重退化,以西安市及临近城市最为典型。（3） 热点区主要分布在秦岭山区及关中平原中部地区,冷点区则集中于黄土高原边缘地区,植被覆盖总体以增长为主。热点区格网数量持续增多,2013年达到最大为45.07%;冷点区域数量不断减少,2017年减少到9.82%;次热点区与次冷点区主要分布在中部平原地带及北部地区,由连片分布转化为零散分布,且总量不断减少。（4） 自然因素对植被覆盖的影响最为突出,其中气温和降水为影响植被覆盖的主导因子,决定力q值分别为0.955和0.931,且气温的影响大于降水的影响;人文因子影响力较为显著,GDP因子决定力q值达到0.387。研究可为当地改善植被覆盖环境提供理论依据。  相似文献   

On the orthogonality of surface wave eigenfunctions in cylindrical coordinates     

M. G. Bostock 《Geophysical Journal International》1990,103(3):763-767

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