Changes to cadmium associations in canal sediments on drying and oxidation     

Samantha R. Cook John M. Chamock Andrew Parker 《中国地球化学学报》2006,25(B08):247-247

The mainly 19th Century canal system in the UK, largely managed by British Waterways, has been increasingly brought back into operation over the last few decades, and is now widely used for both leisure, and, increasingly, transport. Both initial and routine dredging of the canal sediment is carried out and these sediments are generally disposed of to land. Because many of the canals were connected with primary industries, their sediments can locally be significantly contaminated with heavy metals, and the behaviour of these metals under differing redox conditions, when introduced into a new environment （i.e., on land） is of importance for environmental risk-assessment purposes. Canal sediments are often rich in sulfidic mineral phases, and we have attempted to quantify the influence of these sulfidic phases on the release and retention of metals in dredged canal sediments, using a combination of traditional chemical techniques （e.g. sequential extraction） and X-ray absorption spectroscopy （XAS）. Sediment samples have been collected from urban fresh-water canals, one in the British Midlands and one in Northern France. It appears from XAS that Cd is largely associated with oxygen in air-dried sediment, and with sulphur in vacuum-dried sediment.  相似文献   

Subsidence due to peat oxidation and impact on drainage infrastructures in a farmland catchment south of the Venice Lagoon   总被引：1，自引：0，他引：1  

G. Gambolati  M. Putti  P. Teatini  G. Gasparetto Stori 《Environmental Geology》2006,49(6):814-820

Large agricultural areas reclaimed in the past century, south of the Venice Lagoon, have experienced significant land subsidence due to oxidation of peat organic soils. This has exposed the region to flood hazard particularly during severe storms and has contributed to increase the marginal management cost of the infrastructures (ditches, levees, pumping stations) designed to operate the drainage system. Direct measurements and indirect evidence from the channel network suggest a land settlement between 1.5 and 2 m over the past 70 years. This paper provides an overview of the problem with important information on its most recent evolution.  相似文献   

A review of the adjoint-state method for computing the gradient of a functional with geophysical applications   总被引：8，自引：0，他引：8  

R.-E. Plessix 《Geophysical Journal International》2006,167(2):495-503

  相似文献   

环境样品中痕量元素的化学形态分析Ⅰ．分析技术在化学形态分析中的应用   总被引：21，自引：7，他引：21  

何红蓼 李冰杨红霞  倪哲明 《岩矿测试》2005,24(1):51-58

文章介绍了形态分析的基本概念,常用的联用分析技术,如气相色谱原子吸收光谱、气相色谱原子荧光光谱、气相色谱微波诱导等离子体原子发射光谱、气相色谱电感耦合等离子体质谱、高效液相色谱电感耦合等离子体质谱等在环境样品(水、土壤、沉积物)中痕量元素化学形态(价态、金属有机化合物等)分析中的应用,土壤和沉积物中污染元素的顺序提取步骤,以形态分析发展动态。引用文献72篇。  相似文献   

吐哈盆地十红滩铀矿床水文地球化学特征   总被引：6，自引：0，他引：6  

乔海明  张天太  张复新  尚高峰  宋哲 《铀矿地质》2005,21(6):345-352

本文根据水化学资料的研究,探讨了十红滩铀矿床含矿含水层高矿化度地下水的成因,分析了高矿化度水对铀溶解迁移的影响及碳酸盐的形成机理.  相似文献   

新疆绿色电气石颜色成因研究   总被引：5，自引：0，他引：5       下载免费PDF全文

王进军陶晓风  王武军 《岩石矿物学杂志》2005,24(4):319-323

新疆绿色电气石颜色成因比较特殊,为了更好地了解其颜色的形成,主要采用化学分析、吸收光谱、穆斯堡尔谱等测试手段对绿色电气石颜色成因进行研究。化学分析结果显示每个样品中均含有少量不同过渡元素离子,如Fe2 、Ti4 、Cr3 等,影响着绿色的形成;利用吸收光谱测试方法确定了致色离子的吸收带位置及主要离子的种类、价态,并根据化学成分计算出相应的化学式,利用穆斯堡尔谱确定了铁离子在晶体中的占位。综合运用上述测试方法,确定了绿色电气石的颜色成因。  相似文献   

中国大陆科学钻探主孔声发射法现今地应力状态的确定   总被引：9，自引：0，他引：9       下载免费PDF全文

王连捷李朋武  崔军文丁原辰 《中国地质》2005,32(2):259-264

对中国大陆科学钻探主孔的岩心进行了声发射测量,确定了301～1531m深度的最大主应力。并与钻孔崩落法(深度1269～1655m)测量结果进行了对比,结果表明,声发射测量所得测值基本上落在钻孔崩落法测值的趋势线上,两种方法所得结果一致,说明测量结果可信。测量结果表明科学钻探主孔地应力大小随深度增加,在浅部301m最大主应力为13.4MPa,在深部1655m为55.2MPa。随深度的增加率为0.0279MPa/m。最大主应力方向为N54°±3.3°E,且方向不随深度变化。  相似文献   

大气热力学的若干新发展          下载免费PDF全文

曹鸿兴 《应用气象学报》2005,16(4):554-416

对自20世纪80年代以来的大气热力学发展进行了综合评述, 阐述了如城市热岛效应、全球增暖等非传统大气热力学问题; 基于大气非平衡态热力学的非线性理论, 提出应发展突显热力学作用的数值模式, 并阐述其必要性和可能性。  相似文献   

IAP/LASG全球海-陆-气耦合系统模式的纬向平均大气气候态分析(英文)     

Zhang Tao  Guo Yufu  Wu Guoxiong 《大气科学进展》2002,19(6):1091-1102

分海洋和陆地两种情况来讨论IAP/LASG全球海-陆-气耦合系统模式（GOAL）四个版本的结果,并与观测资料进行对比分析。一些重要的大气变量包括表面空气温度,海平面气压和降水率用来评估GOALS模式模拟当代气候和气候变率的能力。总的来说,GOALS模式的四个版本都能够合理地再现观测到的平均气候态和季节变化的主要特征。同时评估也揭示了模式的一些缺陷。可以清楚地看到模拟的全球平均海平面气压的主要误差是在陆地上。陆地上表面空气温度模拟偏高主要是由于陆面过程的影响。值得注意的是降水率模拟偏低主要是在海洋上,而中高纬的陆地降水在北半球冬天却比观测偏高。 通过模式不同版本之间的相互比较研究,可以发现模式中太阳辐射日变化物理过程的引入明显地改善了表面空气温度的模拟,尤其是在中低纬度的陆地上。太阳辐射日变化的引入对热带陆地的降水和中高纬度的冬季降水也有较大改进。而且,由于使用了逐日通量距平交换方案（DFA）,GOALS模式新版本模拟的海洋上的温度变率在中低纬度有了改善。 比较观测和模拟的年平均表面空气温度的标准差,可以发现GOALS模式四个版本都低估了海洋和陆地上的温度变率,文中还对影响观测和模拟温度变率差异的可能原因进行了探讨。  相似文献   

DMS and SO2 at Baring Head, New Zealand: Implications for the Yield of SO2 from DMS     

Warren J. de Bruyn  Mike Harvey  Jill M. Cainey  Eric S. Saltzman 《Journal of Atmospheric Chemistry》2002,41(2):189-209

Atmospheric dimethyl sulfide (DMS) and sulfur dioxide (SO₂) concentrations were measured at Baring Head, New Zealandduring February and March 2000. Anti-correlated DMS and SO₂ diurnalcycles, consistent with the photochemical production of SO₂ from DMS, were observed in clean southerly air off the ocean. The data is used to infer a yield of SO₂ from DMS oxidation. The estimated yields are highly dependent on assumptions about the DMS oxidation rate. Fitting the measured data in a photochemical box model using model-generated OH levels and the Hynes et al. (1986) DMS + OH rate constant suggests that theSO₂ yield is 50–100%, similar to current estimates for the tropical Pacific.However, the observed amplitude of the DMS diurnal cycle suggests that the oxidation rate is higher than that used by the model, and therefore, that theSO₂ yield is lower in the range of 20–40%.  相似文献