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91.
Contradictory results are reported for the behaviour of quaternary ammonium compounds (QACs) in sewage treatment plants (STPs). QACs may sorb onto activated sludge. Only little information is available with respect to effects of QACs against bacteria in STPs. Only 5 to 15 % of bacteria present in sewage sludge can be detected by means of culture dependent microbiological methods. The shift of the bacterial populations due to effects of test compounds have not been studied up to now with culture independent methods. The microbial populations shift was studied in situ using culture independent chemotaxonomy profiling ubiquinones and polyamines. Additionally, toxic effects of QACs against bacteria present in the test vessels of the Zahn‐Wellens test (OECD 302 B) were assessed with a toxicity control in the test. The ubiquinone profiles representing changes in Gram‐negative populations mainly showed that the activated sludge was affected only in test vessels containing benzalkonium chloride. According to chemotaxonomy Acinetobacter or/and some members of Pseudomonas spp. have been selected by benzalkonium chloride after some adaptation period (8 to 12 days).  相似文献   
92.
A two‐dimensional simulation model of travel distances of individual particles in a gravel‐bed river is presented. The model is based on a number of rules, which include particle size, entrainment, trajectory, distance of movement and entrapment. Particle interactions are controlled by resistance fields defined about each obstacle and critical elevation defined in the model. Resistance fields, particle dropping and critical elevation rules control particle interactions. The interaction rules cause the particles to develop pebble clusters, stone cells and transverse structures (transverse ribs). The simulated travel distances of individual particles are consistent with reported field results. Individual particle travel distances were simulated using two different models; one without interactions between the individual particles and the stationary bed and one with interactions. The case without interactions demonstrates the random nature of sediment transport, and narrow ranges of travel distances. Wider ranges of travel distances, similar to those for natural situations, were obtained for the cases with interactions. The more intense the interaction between the mobile stones and the stationary ones, the wider the range of distances of travel for a given particle size. Modelling the mean travel distance yielded a result similar to that published previously, which was based on empirical data. Well developed bed‐surface structures were obtained for relatively poorly sorted sediment with intense interactions between particles. Transverse structures developed when relatively large particles were allowed to move. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
93.
The main landforms within the glacially scoured Precambrian rocks of the Swedish west coast are closely connected to the principal structural pattern and have lately been explained as mainly a result of etch processes, probably during the Mesozoic and with a possible second period of etching during the Neogene. To explore the effect of multiple glacial erosion on the rock surfaces, an island with two different lithologies and with striae from different directions was selected for a detailed study, focusing on the shape of roches moutonnées. Air‐photo interpretation of bedrock lineaments and roches moutonnées combined with detailed field mapping and striae measurements are used to interpret the structural and lithological control on the resulting shape. The study reveals a significant difference in shape between roches moutonnées in augen‐granite and orthogneiss. Low elongated and streamlined roches moutonnées occur in the gneiss area, striated by a Late Weichselian ice flow from the NE. This ice flow is subparallel with both the local dominant trend of topographically well‐expressed joints and the schistosity of the gneiss. Frequently, there are no signs of quarrying on the lee‐sides of the gneiss roches moutonnées and hence they resemble the shape of whalebacks, or ruwares, as typically associated with the exposed basal weathering surface found in tropical areas. The granite roches moutonnées were formed by an older ice flow from the ESE, which closely followed the etched WNW–ESE joint system of the granite. Late Weichselian ice flow from the NE caused only minor changes of the landforms. On the contrary, marks of the early ESE ice flow are poorly preserved in the gneiss area, where it probably never had any large effect as the flow was perpendicular to both schistosity and structures and, accordingly, also to the pre‐glacial relief. The study demonstrates that coincidence between ice flow direction and pre‐glacially etched structures is most likely to determine the effects of glacial erosion. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
94.
It is critical to understand and quantify the temporal and spatial variability in hillslope hydrological data in order to advance hillslope hydrological studies, evaluate distributed parameter hydrological models, analyse variability in hydrological response of slopes and design efficient field data sampling networks. The spatial and temporal variability of field‐measured pore‐water pressures in three residual soil slopes in Singapore was investigated using geostatistical methods. Parameters of the semivariograms, namely the range, sill and nugget effect, revealed interesting insights into the spatial structure of the temporal situation of pore‐water pressures in the slopes. While informative, mean estimates have been shown to be inadequate for modelling purposes, indicator semivariograms together with mean prediction by kriging provide a better form of model input. Results also indicate that significant temporal and spatial variability in pore‐water pressures exists in the slope profile and thereby induces variability in hydrological response of the slope. Spatial and temporal variability in pore‐water pressure decreases with increasing soil depth. The variability decreases during wet conditions as the slope approaches near saturation and the variability increases with high matric suction development following rainfall periods. Variability in pore‐water pressures is greatest at shallow depths and near the slope crest and is strongly influenced by the combined action of microclimate, vegetation and soil properties. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
95.
This research is grounded in notions of differential economic restructuring across employment sectors and geographic space, as well as migration selectivity by occupation. A series of unconstrained competing‐destinations models were employed to analyze the response by workers in thirteen occupational categories to sectoral employment change, average wages, and distance. As was hypothesized, workers in occupations that require high levels of education and skills are more responsive, in terms of migration, to economic opportunities in alternative labor‐market areas. However, the results do not support the hypothesis that highly educated and skilled workers migrate longer distances. Further investigation suggests that opportunities for highly educated and skilled workers may be clustering in relatively few areas that are in relatively close proximity.  相似文献   
96.
油气化探中甲烷碳同位素应用、存在问题与对策研究   总被引:5,自引:2,他引:5  
阐述了在地表油气化探实践当中甲烷碳同位素对地表土壤烃气成因判别的有效性,但有时也会遇到判断错误的情况。通过对应用实例的分析,指出因忽略了土壤中异常甲烷是一种混合成因甲烷,从而导致判断失误。为全面解决这一问题,提出了同时选送数量相当的背景土壤样品和异常样品进行甲烷同位素测定,然后通过教学方法计算出真实反映来源于油气藏中的甲烷的碳同位素值的对策方案。  相似文献   
97.
大庆油田部分三元复合驱抽油井结垢现象比较严重。井中结垢损害抽油设备,增加了生产成本。通过运用XRD,IR,SEM和化学分析手段对抽油井垢的研究发现,垢的主要化学成分为CaO和SiO2,其含量分别为67%和28%,油井垢中的主要矿物成分是罕见矿物——六方球方解石。六方球方解石呈微晶状(1—10μm),并常常以微晶聚集的球粒状出现,同时伴生有无定形SiO2。呈游离态的SiO2和有机质对于六方球方解石的形成起到了重要作用。  相似文献   
98.
华南热水成因硅质岩建造的稀土元素地球化学特征   总被引:11,自引:2,他引:11  
本文在华南地区若干个重要层位热水成因硅质岩建造的稀土元素地球化学数据的基础上,讨论了热水成因硅质岩的REE特征及其与形成环境的关系。指出典型热水沉积建造的δCe为负异常,而δEu为正异常,且LREE>HREE;这种热水成因的硅质岩REE总量普遍较低,且有从热水喷口向外REE总量增高的趋势。热水成因硅质泥岩与正常沉积成因硅质泥的混合存在使稀土元素分布状况变得更复杂。  相似文献   
99.
白秧坪铜银多金属矿床主要产于白垩系下统景星组石英砂岩、粉砂岩中,矿石铅同位素组成特征与景星组砂岩的铅同位素组成比较接近,表明壳源物质参与了成矿作用。作ZartMan图解和△γ—△β图解表明,矿石铅属于壳幔混合来源。矿石铅μ值介于9.43—9.65之间,Th/U比值介于3.72—3.87之间,表明矿石铅为壳幔混合铅。该矿床硫同位素组成表明,硫来源于深部地幔硫遭受地壳硫的混入。该矿床的成矿作用发生于开放体系之中,成矿物质来源为深部幔源物质混合了壳源物质。  相似文献   
100.
河南东濮凹陷古近系沙河街组盐岩沉积特征及成因   总被引:13,自引:6,他引:13       下载免费PDF全文
东濮凹陷是渤海湾盆地的一个次级构造单元,其古近系的两个沉积旋回发育了四套盐岩,分别位于沙河街组第三段的第四亚段(S34)、第三亚段(S33)、第二亚段(S32)和沙河街组的第一段(S1)。主要分布在凹陷北部。每套盐岩又由若干个盐韵律组成,每一单韵律由盐岩和泥岩组成。两套等时对比标志层(深湖沉积)之间盐岩与砂泥岩存在着相变关系。盐岩是在深盆背景下干旱成因的,盐类物质来自地下深处上涌的卤水,分层卤水是盐形成的基本形式,上涌通道是基底大断裂,动力基础是岩浆活动。盐的阻隔作用使其对下部地层的温度、压力均有影响,这种影响有利于加快盐下地层中的有机质成熟与演化。盐又是良好的盖层,且在高温、高压下盐呈塑性状态。勘探实践看出东濮凹陷的岩性油气藏与盐岩的沉积有密切的关系,因此搞清盐岩的分布规律对东濮凹陷下步勘探有着极为重要的意义。  相似文献   
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