圆盘固相萃取富集-气相色谱法测定地表水中有机氯和有机磷农药   总被引：4，自引：2，他引：2  

何淼  饶竹 《岩矿测试》2008,27(1):12-16

采用环境友好的圆盘固相萃取新技术富集水体中有机氯农药和有机磷农药,分别用微池电子捕获检测器(μECD)和火焰光度检测器(FPD)气相色谱法检测,实现了水中有机氯和有机磷农药残留物的测定。结果表明,16种有机氯农药的平均回收率为64.7%~102%,精密度(RSD,n=6)为2.9%~15%;13种有机磷农药的平均回收率为65.9%~104%,精密度(RSD,n=6)为1.7%~17%。方法快速、灵敏、低污染,可用于水体中多种有机氯农药和有机磷农药的残留分析。  相似文献   

流体包裹体成分测定的低温相变和显微拉曼光谱分析技术研究进展   总被引：2，自引：1，他引：1  

葛云锦  陈勇  周瑶琪 《岩矿测试》2008,27(3):207-210

论述了包裹体低温分析技术的原理以及进展。传统的流体包裹体低温分析技术是以显微冷冻测温测定无机盐体系为主,目前已发展到应用低温原位拉曼光谱技术对包裹体中的阳离子和阴离子进行定量-半定量分析。油气包裹体原位低温分析技术也取得了较大的突破,对不同成分油气包裹体低温下的相变过程取得了一定的认识,据此对油气包裹体进行分类,推测其主要成分,为油气包裹体计算提供基础参数。  相似文献   

气相色谱法测定地下水中六六六结果的不确定度评定   总被引：7，自引：4，他引：3  

李松  饶竹 《岩矿测试》2008,27(4):295-298

依照《测量不确定度评定与表示》,对气相色谱法测定地下水中六六六(HCH)四种单体结果进行了不确定度评定。分析了测量过程中引入的不确定度来源,包括提取液体积的量取、样品提取溶液的定容体积、分析仪器的进样量、标准系列溶液的测量以及仪器重复测定等分量引入不确定度及其各参数的采集和计算方法,最后合成标准不确定度,通过乘以95%概率下的扩展因子2,获得测量结果的扩展不确定度。  相似文献   

Response of groundwater chemistry to water deliveries in the lower reaches of Tarim River,Northwest China   总被引：2，自引：0，他引：2  

Yongjin Chen  Kefa Zhou  Yaning Chen  Weihong Li  Jiazhen Liu  Tao Wang 《Environmental Geology》2008,53(6):1365-1373

In this paper, we analysed the monitored data from nine groundwater-monitoring transects in the lower reaches of Tarim River during the five times of stream water deliveries to the river transect where the stream flow ceased. The results showed that the groundwater depth in the lower reaches of Tarim River rose from −9.30 m before the conveyances to −8.17 and −6.50 m after the first and second conveyances, −5.81 and −6.00 m after the third and fourth the conveyance, and −4.73 m after the fifth. The horizontal extent of groundwater recharge was gradually enlarged along both sides of the channel of conveyance, i.e., from 250 m in width after the first conveyance to 1,050 m away from the channel after the fourth delivery. With the rising groundwater level, the concentrations of major anions Cl⁻, SO₄²⁻ and cations Ca²⁺, Mg²⁺, Na⁺, as well as total dissolved solids (TDS) in groundwater underwent a significant change. The spatial variations in groundwater chemistry indicated that the groundwater chemistry at the transect near Daxihaizi Reservoir changed earlier than that farther from it. In the same transect, the chemical variations were earlier in the monitoring well close to watercourse than that farther away from the stream. In general, the concentration of the major ions and TDS at each monitoring well increased remarkably when the water delivery started, and decreased with the continued water delivery, and then increased once again at the end of the study period. Hence, the whole study period may be divided into three stages: the initial stage, the intermediate stage and the later stage. According to the three stages of groundwater chemistry reaction to water delivery and the relationships between groundwater chemical properties and groundwater depths, we educe that under the situation of water delivery, the optimum groundwater depth in the lower reaches of the Tarim River should be −5 m.  相似文献   

A modified DRASTIC model for Siting Confined Animal Feeding Operations in Williams County,Ohio, USA   总被引：1，自引：0，他引：1  

Enrique Gomezdelcampo  J. Ryan Dickerson 《Environmental Geology》2008,55(8):1821-1832

Three of DRASTIC’s parameters (Depth to Water, Soil Media, and Topography) were modified and another parameter was added (land use/land cover) to the model to determine the potential impact on groundwater from Confined Animal Feeding Operations (CAFO) manure lagoon settings and manure application as fertilizer. Williams County is a mostly agricultural county located in northwest Ohio, USA. It currently has three CAFOs, all dairy, with the possibility of the construction of a multi-million chicken egg CAFO in the near future. A Geographic Information System (GIS) was utilized to modify the Ohio Department of Natural Resources (ODNR) DRASTIC map for the county to fully assess the county-wide pollution potential of CAFOs. The CAFO DRASTIC map indicates that almost half of Williams County has elevated groundwater pollution potential. The rest of the county, primarily the southeast corner, has lower CAFO groundwater pollution potential. Future CAFO development within the county should focus on the southeastern portion of the county where the groundwater table is deeper, and the aquifer is composed of shale substrate with low hydraulic conductivity. The CAFO DRASTIC results are intended to be used as a screening tool and are not to replace site-specific hydrogeologic investigations.  相似文献   

Potential for localized groundwater contamination in a porous pavement parking lot setting in Rhode Island     

Thomas B. Boving  Mark H. Stolt  Janelle Augenstern  Brian Brosnan 《Environmental Geology》2008,55(3):571-582

The control of polluted surface runoff and the assessment of possible impacts on groundwater is a concern at the local and regional scale. On this background, a study investigates possible impacts of organic and inorganic pollutants (including bacteria) originating from a permeable asphalt parking lot on the water quality immediately beneath it. The functioning of the permeable pavement, including clogging and restricted vertical percolation, was also evaluated. Four nested sample ports (shallow and deep) were installed below low- and high-traffic areas, including one port outside the parking lot. At least initially there was a good hydraulic connection between the parking surface and the shallow sample ports. The presence of a geotextile layer at the base of the parking lot structure, however, was identified in lab tests as one factor restricting vertical percolation to the deeper ports. Clogging of the permeable surface was most pronounced in heavy traffic areas and below snow pile storage areas. Corroborated by high electric conductivity and chloride measurements, sand brought in by cars during winter was the principal cause for clogging. No bacteria or BOD were found in percolating water. Polycyclic aromatic hydrocarbons (PAH) were present at concentrations near minimum detection limit. Nutrients (nitrate and phosphate) were being leached into the ground via the permeable parking lot surface at annual flux rates of 0.45–0.84 g/m²/year. A multi-species tracer test demonstrated a retention capacity of the permeable parking lot structure of >90% for metals and 27% for nutrients, respectively.  相似文献   

Dissolved trace elements and heavy metals in the Danjiangkou Reservoir,China   总被引：9，自引：0，他引：9  

Siyue Li  Zhifang Xu  Xiaoli Cheng  Quanfa Zhang 《Environmental Geology》2008,55(5):977-983

Concentrations of trace elements and heavy metals (Al, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Sr, V and Zn) in the Danjiangkou Reservoir, the water source area of the Middle Route of China’s interbasin South to North Water Transfer Project, were analyzed using an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) and compared with the national and international standards for drinking water. The results indicated that concentrations of As, Pb, Sb and Se in the Reservoir exceeded the standards and they would pose health risk for residents in the region and the water receiving areas of the interbasin water transfer project. Spatial and temporal variability of the trace elements and heavy metals in the Reservoir implies their mixed sources of natural processing and anthropogenic activities in the upper drainage of the Reservoir. The research results would help develop water resource management and conservation strategy for the interbasin water transfer project.  相似文献   

Low-pressure,water-assisted anatexis of basic dykes in a contact metamorphic aureole,Fuerteventura (Canary Islands): oxygen isotope evidence for a meteoric fluid origin     

M. I. Holloway  F. Bussy  T. W. Vennemann 《Contributions to Mineralogy and Petrology》2008,155(1):111-121

Migmatites produced by low-pressure anatexis of basic dykes are found in a contact metamorphic aureole around a pyroxenite–gabbro intrusion (PX2), on Fuerteventura. Dykes outside and inside the aureole record interaction with meteoric water, with low or negative δ¹⁸O whole-rock values (+0.2 to −3.4‰), decreasing towards the contact. Recrystallised plagioclase, diopside, biotite and oxides, from within the aureole, show a similar evolution with lowest δ¹⁸O values (−2.8, −4.2, −4.4 and −7.6‰, respectively) in the migmatite zone, close to the intrusion. Relict clinopyroxene phenocrysts preserved in all dykes, retain typically magmatic δ¹⁸O values up to the anatectic zone, where the values are lower and more heterogeneous. Low δ¹⁸O values, decreasing towards the intrusion, can be ascribed to the advection of meteoric water during magma emplacement, with increasing fluid/rock ratios (higher dyke intensities towards the intrusion acting as fluid-pathways) and higher temperatures promoting increasing exchange during recrystallisation. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Depths of Partial Crystallization of H2O-bearing MORB: Phase Equilibria Simulations of Basalts at the MAR near Ascension Island (7 11{degrees}S)     

Almeev  Renat; Holtz  Francois; Koepke  Jurgen; Haase  Karsten; Devey  Colin 《Journal of Petrology》2008,49(1):25-45

Phase equilibria simulations were performed on naturally quenchedbasaltic glasses to determine crystallization conditions priorto eruption of magmas at the Mid-Atlantic Ridge (MAR) east ofAscension Island (7–11°S). The results indicate thatmid-ocean ridge basalt (MORB) magmas beneath different segmentsof the MAR have crystallized over a wide range of pressures(100–900 MPa). However, each segment seems to have a specificcrystallization history. Nearly isobaric crystallization conditions(100–300 MPa) were obtained for the geochemically enrichedMORB magmas of the central segments, whereas normal (N)-MORBmagmas of the bounding segments are characterized by polybariccrystallization conditions (200–900 MPa). In addition,our results demonstrate close to anhydrous crystallization conditionsof N-MORBs, whereas geochemically enriched MORBs were successfullymodeled in the presence of 0·4–1 wt% H₂O in theparental melts. These estimates are in agreement with direct(Fourier transform IR) measurements of H₂O abundances in basalticglasses and melt inclusions for selected samples. Water contentsdetermined in the parental melts are in the range 0·04–0·09and 0·30–0·55 wt% H₂O for depleted and enrichedMORBs, respectively. Our results are in general agreement (within±200 MPa) with previous approaches used to evaluate pressureestimates in MORB. However, the determination of pre-eruptiveconditions of MORBs, including temperature and water contentin addition to pressure, requires the improvement of magma crystallizationmodels to simulate liquid lines of descent in the presence ofsmall amounts of water. KEY WORDS: MORB; Mid-Atlantic Ridge; depth of crystallization; water abundances; phase equilibria calculations; cotectic crystallization; pressure estimates; polybaric fractionation  相似文献   

实验研究不同盐离子对水分子拉曼效应的影响   总被引：3，自引：0，他引：3  

陈勇  周瑶琪  查明  王爱国 《地球化学》2008,37(1):22-26

对流体包裹体中常见的几种盐水溶液进行了拉曼光谱分析.采用了频移参数描述水分子拉曼峰的形变强度,并讨论了频移参数与盐度之间的关系.实验分析结果表明,盐度越大,频移参数越大,水分子拉曼峰形变越大.对频移参数曲线斜率分析显示,盐类对水分子拉曼峰偏移程度影响的强弱顺序为NaCl＞Na2SO4＞NaHCO3＞Na2CO3.讨论了不同阳离子和阴离子对水伸缩振动拉曼峰的影响,结果表明,高价阳离子的影响明显高于低价阳离子;而阴离子对水拉曼峰影响的强弱顺序初步确定为Cl-≈SO2-4-＞HCO-3＞CO2-3≈NO-3.  相似文献