Dynamic recrystallization near the brittle-plastic transition in naturally and experimentally deformed quartz aggregates   总被引：1，自引：0，他引：1  

Michael Stipp  Karsten Kunze   《Tectonophysics》2008,448(1-4):77-97

The electron backscattering diffraction technique (EBSD) was used to analyze bulging recrystallization microstructures from naturally and experimentally deformed quartz aggregates, both of which are characterized by porphyroclasts with finely serrated grain boundaries and grain boundary bulges set in a matrix of very fine recrystallized grains. For the Tonale mylonites we investigated, a temperature range of 300–380 °C, 0.25 GPa confining pressure, a flow stress range of ~ 0.1–0.2 GPa, and a strain rate of ~ 10^− 13 s^− 1 were estimated. Experimental samples of Black Hills quartzite were analyzed, which had been deformed in axial compression at 700 °C, 1.2–1.5 GPa confining pressure, a flow stress of ~ 0.3–0.4 GPa, a strain rate of ~ 10^− 6 s^− 1, and to 44% to 73% axial shortening. Using orientation imaging we investigated the dynamic recrystallization microstructures and discuss which processes may contribute to their development. Our results suggest that several deformation processes are important for the dismantling of the porphyroclasts and the formation of recrystallized grains. Grain boundary bulges are not only formed by local grain boundary migration, but they also display a lattice misorientation indicative of subgrain rotation. Dynamic recrystallization affects especially the rims of host porphyroclasts with a hard orientation, i.e. with an orientation unsuitable for easy basal slip. In addition, Dauphiné twins within porphyroclasts are preferred sites for recrystallization. We interpret large misorientation angles in the experimental samples, which increase with increasing strain, as formed by the activity of fluid-assisted grain boundary sliding.  相似文献   

实验条件对X射线衍射物相定量分析结果的影响   总被引：8，自引：6，他引：2  

房俊卓  张霞  徐崇福 《岩矿测试》2008,27(1):60-62

通过实验验证了多物相试样X射线衍射定量分析的基体效应,着重研究了参比强度K值、衍射强度、混合物各物相粒度、X射线管功率等实验条件对物相定量分析结果的影响。结果表明,物相定性分析是定量分析的前提,采用积分强度、使各物相颗粒尽可能细而且均匀、采用较高的X射线管功率以及适合的扫描速率均有利于提高物相X射线衍射定量分析的准确度。  相似文献   

X射线衍射数据分析系统评价   总被引：4，自引：1，他引：3  

李建欣  宋党育  张军营  郑楚光 《岩矿测试》2008,27(3):189-193

以贵州省高灰、高污染组分煤中矿物质的分析为例,应用Bruker AXS D8 Advance衍射仪测得煤中矿物相的X射线衍射图谱,分别应用数据分析系统EVA 12.0、X’Pert HighScore 2.0和MDI Jade 5.0对矿物物相组成的原始测试数据进行定性分析,通过对比分析过程和结果的差异比较了三款软件系统之间的异同和优劣。  相似文献   

Room-temperature equation of state of Li<Subscript>2</Subscript>VOSiO<Subscript>4</Subscript> up to 8.5 GPa     

Serena C. Tarantino  Michele Zema  Tiziana Boffa Ballaran  Paolo Ghigna 《Physics and Chemistry of Minerals》2008,35(2):71-76

High-pressure single-crystal X-ray diffraction measurements of lattice parameters of the compound Li₂VOSiO₄, which crystallises with a natisite-type structure, has been carried out to a pressure of 8.54(5) GPa at room temperature. Unit-cell volume data were fitted with a second-order Birch-Murnaghan EoS (BM-EoS), simultaneously refining V ₀ and K ₀ using the data weighted by the uncertainties in V. The bulk modulus is K ₀ = 99(1) GPa, with K′ fixed to 4. Refinements of third order equations-of-state yielded values of K′ that did not differ significantly from 4. The compressibility of the unit-cell is strongly anisotropic with the c axis (K ₀(c) = 49.7 ± 0.5 GPa) approximately four times more compressible than the a axis (K ₀(a) = 195 ± 3 GPa).  相似文献   

In situ strength measurements on natural upper-mantle minerals   总被引：1，自引：0，他引：1  

Junji Yamamoto  Jun-ichi Ando  Hiroyuki Kagi  Toru Inoue  Akihiro Yamada  Daisuke Yamazaki  Tetsuo Irifune 《Physics and Chemistry of Minerals》2008,35(5):249-257

Using in situ strength measurements at pressures up to 10 GPa and at room temperature, 400, 600, and 700°C, we examined rheological properties of olivine, orthopyroxene, and chromian-spinel contained in a mantle-derived xenolith. Mineral strengths were estimated using widths of X-ray diffraction peaks as a function of pressure, temperature, and time. Differential stresses of all minerals increase with increasing pressure, but they decrease with increasing temperature because of elastic strain on compression and stress relaxation during heating. During compression at room temperature, all minerals deform plastically at differential stress of 4–6 GPa. During subsequent heating, thermally induced yielding is observed in olivine at 600°C. Neither orthopyroxene nor spinel shows complete stress relaxation, but both retain some stress even at 700°C. The strength of the minerals decreases in the order of chromian-spinel ≈ orthopyroxene > olivine for these conditions. This order of strength is consistent with the residual pressure of fluid inclusions in mantle xenoliths.  相似文献   

A neutron diffraction study of alkali cation migration in montmorillonites     

D. Gournis  A. Lappas  M. A. Karakassides  D. Többens  A. Moukarika 《Physics and Chemistry of Minerals》2008,35(1):49-58

Neutron powder diffraction measurements on lithium and cesium saturated montmorillonite samples before and after heat treatment at 300°C are studied, in order to undertake a complete refinement of crystal structure and unravel the migration mechanism for the interlayer cations of Li or Cs. Rietveld analysis of the corresponding diffraction patterns finds that montmorillonite crystallizes in the C2/m space group with unit cell dimensions consistent with the size of the specific interlayer cation. We show that thermal treatment affects the two types of samples in a different way. This is with respect to their unit cell dimensions and the migration of Li from the 2b to the 2c clay lattice site, in constrast to the Cs positioning which remains effectively unchanged.  相似文献   

实验研究不同盐离子对水分子拉曼效应的影响   总被引：3，自引：0，他引：3  

陈勇  周瑶琪  查明  王爱国 《地球化学》2008,37(1):22-26

对流体包裹体中常见的几种盐水溶液进行了拉曼光谱分析.采用了频移参数描述水分子拉曼峰的形变强度,并讨论了频移参数与盐度之间的关系.实验分析结果表明,盐度越大,频移参数越大,水分子拉曼峰形变越大.对频移参数曲线斜率分析显示,盐类对水分子拉曼峰偏移程度影响的强弱顺序为NaCl＞Na2SO4＞NaHCO3＞Na2CO3.讨论了不同阳离子和阴离子对水伸缩振动拉曼峰的影响,结果表明,高价阳离子的影响明显高于低价阳离子;而阴离子对水拉曼峰影响的强弱顺序初步确定为Cl-≈SO2-4-＞HCO-3＞CO2-3≈NO-3.  相似文献   

A Forced System of Two Cylinders with Various Spacings   总被引：3，自引：0，他引：3  

邹建锋  任安禄邓见 《中国海洋工程》2004,18(3):391-402

The spectrum characteristics and wake structures for a circular cylinder oscillating in a wake are investigated by use of the currently modified virtual boundary method. A forced system of two cylinders with a small spacing ( the downstream one is made to oscillate in the transverse direction) is studied and interesting flow characteristics are observed. A vortex switch and the change of vortex modes (between 2S mode and 2P mode) are observed in the “lock-in“ region. Vortex bands are formed and lost with the increasing excitation frequency. Information concerning saddle points in the flow field is obtained for different excitation frequencies. For a forced system of two cylinders with a large spacing, the upstream cylinder sheds vortexes because there is no downstream cylinder oscillating in the wake. No distinct “lock-in“ response is found for the downstream cylinder.  相似文献   

Variations in wave direction estimated using first and second order Fourier coefficients     

V. Sanil Kumar  N. M. Anand 《Ocean Engineering》2004,31(17-18):2105-2119

In most design applications such as alignment of the berthing structure and breakwater alignment, it becomes necessary to determine the direction of design wave. There are two different approaches to determine wave direction. One involves the use of first order Fourier coefficients (mean wave direction) while the other uses second order Fourier coefficients (principal wave direction). Both the average wave direction over the entire frequency range (0.03–0.58 Hz) and the direction corresponding to the peak frequency are used in practice. In the present study, comparison is made on wave directions estimated based on first and second order Fourier coefficients using data collected at four locations in the west and east coasts of India. Study shows that at all locations, the mean and principal wave directions for frequencies ranging from 0.07 to 0.25 Hz (±0.5 times peak frequency) co-vary with a correlation coefficient of 0.99 but at lower and higher frequencies, difference between the parameters is large. Average difference between the mean wave direction at peak frequency and the average over the frequency related to spectral energy more than 20% of maximum value is less, around 13°. Study shows that average difference in the sea and swell directions is around 39°.  相似文献   

黄河三角洲沿岸及邻近海区细粒沉积物中的碳酸盐   总被引：4，自引：0，他引：4  

何良彪 《海洋科学》1991,15(3):41-45

本文用X-射线衍射法直接计算了来自黄河三角洲沿岸及邻近海区80个沉积样的细粒组分(<2μm)中的碳酸盐含量。计算结果与全样的容量法分析结果基本一致。研究结果表明,本区细粒沉积物中碳酸盐含量变化受沉积物来源、海区水动力作用、海底地貌特征和碳酸盐的地球化学行为等因素所影响。  相似文献