Changes in the Chemical Components of Light Crude Off During Simulated Short Term Weathering     

MA Qimin LUO Xia YU Zhigang 《中国海洋大学学报(英文版)》2007,6(3):231-236

To unambiguously identify spilled oils and to link them to the known sources are extremely important in settling questions of environmental impact and legal liability. The fate and behavior of spilled oils in the environment depend on a number of physicochemical and biological factors. This paper presents the results regarding changes in chemical composition of light crude oil during simulated short-term weathering based on natural environmental conditions. The results show that the saturated hydrocarbons of the light crude oil mainly distribute between n-C8 and n-C23 and the most abundant n-alkanes are found in the n-C10 to n-C16. The main chemical components of the light crude oil are n-alkanes and isoprenoids. The aromatic compounds are subordinate chemical components. Under the conditions of the weathering simulation experiment,n-alkanes less than n-C12,toluene and 1,3-dimethyl benzene are lost after 1 d weathering,the n-C13,n-C14,naphthalene and 2-methyl-naphthalene are lost on the fifth day of weathering,and n-C15 alkane components show certain weatherproof capability. The ratios n-C17/pristane and n-C18/phytane are unaltered and can be used to identify the source of the light crude oil during the first 8 d of weathering. After 21 d,the ratio pristine/phytane can not provide much information on the source of the spilled light crude oil. Triterpanes（m/z 191） as biomarker compounds of light crude oil are more valuable.  相似文献   

中亚造山带中的燃烧变质事件及其年代学研究   总被引：2，自引：1，他引：1  

Igor S. Novikov Ellina V. Sokol 《岩石学报》2007,23(7):1561-1572

Combustion metamorphic(pyrometamorphic)complexes produced by prehistoric natural coal fires are widespread inCentral Asia,namely at the interfaces between mountain systems and the flanking sedimentary basins.Large-scale and prolonged firesaccompanied the initial orogenic stages as unweathered coal-bearing formations became exposed into the aeration zone.Pyrometamorphic rocks are comparable to sanidinite facies rocks in formation conditions and in alteration of sedimentary material but,unlike these,their protolith underwent different melting degrees to produce either ferrous basic paralavas or glazed clinkers.The phasecomposition of the newly-formed melted rocks are favorable for~(40)Ar/~(39)Ar dating of combustion metamorphic events which are coeval tothe onset of the main stage of recent orogenic events.We suggest a new algorithm providing correct ~(40)Ar/~(39)Ar dating ofpyrometamorphic rocks followed by well-grounded geological interpretation.We studied pyrometamorphic rocks in the western Salairzone of the Kuznetsk coal basin where combustion metamorphism under temperatures above 1000℃acted upon large volumes of coal-bearing sediments.Samples of paralavas were dated by the step heating ~(40)Ar/~(39)Ar method checked against internal(plateau andisochrone ages)and external("criterions of couple")mineralogical criterions,and against preliminary dating from geological andstratigraphic evidence.As a result,we distinguished two groups of dates for combustion metamorphic events.The first one(1.2±0.4Ma)is drawn towards the west boundary of Prokopyevsk-Kiselevsk block of Salair zone,while the second one(0.2±0.3Ma)isconfined to its east boundary.The former ages represent rocks in the western edge of the Prokopievsk-Kiselevsk block of the Salair zoneand the latter ages correspond to those in its eastern edge.The dates record the time when the fault boundaries of the blocks wererejuvenated during recent activity and the block accreted to the Salair orogenic area as a piedmont step.These are the first absolute agesobtained for the onset of uplift of the northern edge of the Ahai-Sayan area,the key event of its neotectonic history.The suggestedapproach to the choice of objects,classification of rocks,and interpretation of~(40)Ar/~(39)Ar data is universal and can be practiced in anyarea subjected to combustion metamorphism.  相似文献   

Towards a climate event stratigraphy for New Zealand over the past 30 000 years (NZ‐INTIMATE project)     

Brent V. Alloway  David J. Lowe  David J. A. Barrell  Rewi M. Newnham  Peter C. Almond  Paul C. Augustinus  Nancy A. N. Bertler  Lionel Carter  Nicola J. Litchfield  Matt S. McGlone  Jamie Shulmeister  Marcus J. Vandergoes  Paul W. Williams  NZ‐INTIMATE members 《第四纪科学杂志》2007,22(1):9-35

It is widely recognised that the acquisition of high‐resolution palaeoclimate records from southern mid‐latitude sites is essential for establishing a coherent picture of inter‐hemispheric climate change and for better understanding of the role of Antarctic climate dynamics in the global climate system. New Zealand is considered to be a sensitive monitor of climate change because it is one of a few sizeable landmasses in the Southern Hemisphere westerly circulation zone, a critical transition zone between subtropical and Antarctic influences. New Zealand has mountainous axial ranges that amplify the climate signals and, consequently, the environmental gradients are highly sensitive to subtle changes in atmospheric and oceanic conditions. Since 1995, INTIMATE has, through a series of international workshops, sought ways to improve procedures for establishing the precise ages of climate events, and to correlate them with high precision, for the last 30 000 calendar years. The NZ‐INTIMATE project commenced in late 2003, and has involved virtually the entire New Zealand palaeoclimate community. Its aim is to develop an event stratigraphy for the New Zealand region over the past 30 000 years, and to reconcile these events against the established climatostratigraphy of the last glacial cycle which has largely been developed from Northern Hemisphere records (e.g. Last Glacial Maximum (LGM), Termination I, Younger Dryas). An initial outcome of NZ‐INTIMATE has been the identification of a series of well‐dated, high‐resolution onshore and offshore proxy records from a variety of latitudes and elevations on a common calendar timescale from 30 000 cal. yr BP to the present day. High‐resolution records for the last glacial coldest period (LGCP) (including the LGM sensu stricto) and last glacial–interglacial transition (LGIT) from Auckland maars, Kaipo and Otamangakau wetlands on eastern and central North Island, marine core MD97‐2121 east of southern North Island, speleothems on northwest South Island, Okarito wetland on southwestern South Island, are presented. Discontinuous (fragmentary) records comprising compilations of glacial sequences, fluvial sequences, loess accumulation, and aeolian quartz accumulation in an andesitic terrain are described. Comparisons with ice‐core records from Antarctica (EPICA Dome C) and Greenland (GISP2) are discussed. A major advantage immediately evident from these records apart from the speleothem record, is that they are linked precisely by one or more tephra layers. Based on these New Zealand terrestrial and marine records, a reasonably coherent, regionally applicable, sequence of climatically linked stratigraphic events over the past 30 000 cal. yr is emerging. Three major climate events are recognised: (1) LGCP beginning at ca. 28 000 cal. yr BP, ending at Termination I, ca. 18 000 cal. yr BP, and including a warmer and more variable phase between ca. 27 000 and 21 000 cal. yr BP, (2) LGIT between ca. 18 000 and 11 600 cal. yr BP, including a Lateglacial warm period from ca. 14 800 to 13 500 cal. yr BP and a Lateglacial climate reversal between ca. 13 500 and 11 600 cal. yr BP, and (3) Holocene interglacial conditions, with two phases of greatest warmth between ca. 11 600 and 10 800 cal. yr BP and from ca. 6 800 to 6 500 cal. yr BP. Some key boundaries coincide with volcanic tephras. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

扬子陆块西缘中元古代晚期元谋花岗岩的时代、成因及构造意义          下载免费PDF全文

宋冬虎  王燕  刘兵  熊波  关奇  路永严  刘晓玮  刘军平  田素梅  米云川  张硕 《沉积与特提斯地质》2023,43(3):661-673

扬子陆块西缘晚中元古代地质演化史一直存在较大争议,本文选择以扬子西缘元谋杂岩中一套二长花岗岩为研究对象,开展岩相学、锆石U-Pb年代学、全岩地球化学等综合研究,为认识和理解扬子西缘晚中元古代地质演化提供支撑。两件元谋二长花岗岩样品的LA-ICP-MS锆石U-Pb年龄分别为1086±10 Ma（MSWD=1.4,n=50）和1099±10 Ma（MSWD=1.8,n=58）。所有样品具有高硅（SiO₂为69.44%~73.98%）、富碱（Na₂O+K₂O为6.11%~7.72%）、贫钙（CaO为0.39%~1.46%）、贫镁（MgO为0.52%~0.76%）、低钛（TiO₂为0.30%~0.59%）的特点,同时表现出强过铝质（A/CNK=1.19~1.35）及中钾钙碱性–钾玄岩系列特征。它们具有高的稀土元素总量（∑REE=211.60×10^-6~349.01×10^-6）,呈现轻稀土元素富集和重稀土元素亏损（（La/Yb）_N=4.32~7.36）;富集Rb、U、Th等大离子亲石元素和Zr、Th、Hf等,亏损Nb、Ta、Ba等元素,并具有明显的负Eu异常（δEu=0.46~0.59）,锆石饱和温度介于827~912℃之间,展示了A型花岗岩的属性。这些二长花岗岩可能是通过中上地壳的中酸性火成岩的部分熔融形成,结合前人的研究成果,它们最可能形成于弧后的伸展环境,综合扬子陆块周缘晚中元古代的岩浆记录,元谋杂岩中1.09 Ga二长花岗岩的形成应与扬子陆块开始参与Rodinia超大陆聚合有关。  相似文献   

Laser Ablation (U-Th-Sm)/He Dating of Zircons: Analytical Age Bias and its Consequence for Studying Detrital Zircon Populations     

Julien Léger  Raphaël Pik  Bouchaïb Tibari  Sébastien Ternois  Mary Ford  Chantal Peiffert  Julien Mercadier 《Geostandards and Geoanalytical Research》2023,47(2):219-242

The in situ (U-Th-Sm)/He and U/Pb laser-ablation double-dating procedure is a valuable method that can provide a large dataset relatively efficiently in contrast with conventional bulk helium thermochronometry. In this study, we evaluate the potential age error associated with the double ablation procedure and report the in situ (U-Th-Sm)/He double-ablation dating of 249 zircons from the Fish Canyon Tuff locality. With LA-ICP-MS pseudo-depth profiling and 3D numerical modelling, we show that the concentric double-ablation procedure in minerals with U-Th-Sm zoning can generate a significant (U-Th-Sm)/He age error (positive or negative), resulting in over-scattering and/or an offset of the mean age. Pseudo-depth profiling is insufficient to predict the individual age error, partly because of the superimposed ablations. To evaluate the consequence of this inherent bias, we confront a synthetic age distribution to the error expected for U-Th-Sm zoned zircons analysed with double-ablation (U-Th-Sm)/He thermochronometry. As expected, a strong age bias causes the spreading of peak ages, downgrading the original signal. Yet, the throughput of the ablation-based method can allow intra- and inter-sample peak age identification and comparison, and the coupling of (U-Th-Sm)/He and U/Pb ages extends our ability to deconvolute a multimodal age spectrum.  相似文献   

Initial Characterisation of SK01 Sanidine: A Candidate 40Ar/39Ar Reference Material     

Youjuan Li  Brian R. Jicha  Wanfeng Zhang  Wen Chen  Brad S. Singer  Dewen Zheng  Huaiyu He 《Geostandards and Geoanalytical Research》2023,47(3):657-668

The precision and accuracy of ⁴⁰Ar/³⁹Ar dates are ultimately linked to co-irradiated reference materials of known age. Here we provide new data from the SK01 sanidine, which was analysed in three different laboratories to evaluate it as a ⁴⁰Ar/³⁹Ar reference material. Aliquots of 5 mg, incrementally heated in two laboratories, yielded indistinguishable results with a weighted mean age of 27.58 ± 0.06 Ma (95% confidence level). Single-crystal step heating and single-crystal total fusion analyses of SK01 sanidine were undertaken in the third laboratory to further test the intracrystalline homogeneity. For the seven step-heating analyses, six crystals yielded nearly concordant age spectra with ⁴⁰Ar/³⁹Ar ages ranging from 26.853 ± 0.094 Ma to 26.963 ± 0.067 Ma, whereas one crystal gave an older age of 27.774 ± 0.071 Ma with a slightly discordant age spectrum. Twenty-three single-crystal total fusion analyses yielded ⁴⁰Ar/³⁹Ar ages ranging from 27.070 ± 0.108 Ma to 27.736 ± 0.062 Ma with a dispersion of ~ 3.8%. The older ages from single-crystal total fusion dates are interpreted to reflect an inherited or excess argon component in some crystals. This is an initial characterisation of the SK01 sanidine, and additional work needs to be conducted to further evaluate the age dispersion so that it can be utilised as a ⁴⁰Ar/³⁹Ar reference material.  相似文献   

内蒙古沙麦钨矿花岗岩岩石地球化学、锆石U-Pb年代学及其地质意义     

李怀彬  籍进柱  廉永  李腊梅  吴皓然 《岩石矿物学杂志》2023,42(6):809-825

沙麦钨矿床位于内蒙古东乌旗地区,是该区目前已探明的中型岩浆热液型钨矿床。矿体主要赋存在黑云母二长花岗岩和黑云母二长花岗斑岩中,对这两种花岗质岩石的岩相学、岩石地球化学和LA-ICP-MS锆石U-Pb年代学进行了研究。结果表明,黑云母二长花岗岩锆石U-Pb年龄为135.6±1.6 Ma和136.3±1.8 Ma,黑云母二长花岗斑岩锆石U-Pb年龄为138.6±1.1 Ma,二者侵位时间均为早白垩世。两种花岗质岩体具有富SiO₂(73.73%～78.23%)、高钾钠(Na₂O+K₂O)(7.56%～8.89%)、贫MgO(0.09%～0.20%)、贫CaO(0.51%～0.89%)、贫TiO₂(0.03%～0.12%)的特征,属于过铝质-高钾钙碱性系列;微量元素富集Rb、K、Th和U,相对亏损Sr、Ba、Nb、P和Ti元素,具有强烈的Eu负异常,具有较高的FeO^T含量,较高的FeO^T/MgO和FeO^T/(FeO^T+M...  相似文献   

大兴安岭北段喀喇其花岗斑岩体地球化学特征、锆石U-Pb年龄及构造背景          下载免费PDF全文

洪文武 《地质找矿论丛》2023,38(2):209-214

本文对大兴安岭北部喀喇其花岗斑岩体进行了岩石学、地球化学及锆石U-Pb年代学的研究,探讨了其形成的构造背景。结果表明:喀喇其花岗斑岩体锆石U-Pb年龄为132 Ma±1 Ma,表明其形成时代应为早白垩世晚期;岩石具有高钾钙碱性系列,过铝质特征;稀土元素属于轻稀土富集型,分布模式为右倾、左陡右平型式,具有较明显的Eu负异常特征。认为该花岗岩为铝质A型花岗岩,属于地壳岩石部分熔融的产物;该期岩浆侵位活动受蒙古—鄂霍茨克构造体系影响,形成于后造山大陆弧或后碰撞弧环境。  相似文献   

碧口地块东-北缘中、新生代构造隆升及演化：来自磷灰石和锆石裂变径迹的证据     

金文正  白万奎  叶治续 《江苏地质》2023,47(3):231-241

青藏高原具有复杂的构造演化特征,该地区自中、新生代以来的构造隆升和构造演化机制一直是地质研究的热点。为精细刻画青藏高原板块、华北板块和华南板块之间的拼合关系及差异性隆升特征,对位于青藏高原东北端的碧口地块进行了磷灰石和锆石裂变径迹测试,以及热史模拟和岩石冷却速率计算。结果锆石和磷灰石裂变径迹年龄分别在（118±5～265±29）Ma和（29.0±2.7～54.0±7.0）Ma之间;碧口地块东北缘及北缘冷却速率接近,在3.125～3.448 ℃/Ma之间,东缘冷却速率相对较低,为2.041～2.273 ℃/Ma。结果表明,中、新生代以来,碧口地块及其周缘总体上经历了持续隆升过程,但不同地区隆升特征具有差异性：碧口地块北侧在早、中侏罗世（151±7）Ma经历了构造挤压和隆升过程;东部相对较晚,在晚侏罗世（143±11）Ma经历了构造隆升阶段;东北端在早白垩世才与华北板块拼接并进入持续构造隆升阶段。进入古近纪（54.0±7.0）Ma隆升阶段,即始新世早期后,碧口地块东缘在始新世中后期（44 Ma）开始发生构造隆升,北缘自渐新世中晚期（29～32 Ma）开始发生显著的构造隆升。上述区域在10 Ma（中新世晚期）共同进入快速隆升阶段。  相似文献   

西拉木伦构造带克德河砂砾岩的时代及构造意义     

郑月娟  张德军  张海华  张健  陈树旺  甄甄 《地质学报》2023,97(8):2459-2475

西拉木伦构造带北部双井地区发育一套巨厚的、成熟度低的快速堆积的粗碎屑沉积建造,为同造山磨拉石沉积,前人称其为克德河砂砾岩带并将其时代分别划为中二叠世(哲斯组)、晚二叠世(林西组)。本次工作对该套地层进行了大比例尺剖面测量,对取自剖面第下、中、上(1、25、86层)三个部分的砂岩样品进行LA-ICP-MS U-Pb年代学研究,结果显示：3个样品具有相似的主要年龄区间,依次为405-485Ma、401-463Ma、363-520Ma,其峰值年龄分别为427Ma、445Ma、440Ma,锆石数量分别占总量的48％、52.5％和38.75％;其次为大于1000Ma的年龄,锆石数量分别占30.7%、22.5%、45%,且均具有1800Ma和2500Ma左右的峰值年龄,明显具有华北板块基底年龄信息;自下而上3个测年样品最年轻峰值年龄分别为312Ma、376Ma,282Ma,最年轻的锆石年龄分别为304Ma、244Ma和245Ma。在第85层杂色复成分砾岩的灰岩砾石中发现晚石炭－早二叠世阿木山组的蜓和珊瑚化石,在41及43层发现中生代孢粉化石。综合碎屑锆石测年及生物化石研究结果,克德河砂砾岩带的时代应为中三叠世。推测西拉木伦构造带经历了一个较长的演化过程,中二叠世开始华北板块和西伯利亚板块进入碰撞造山阶段, 同造山磨拉石建造(克德河砂砾岩带)标志着中亚造山带演化的终止,华北板块和西伯利亚板块的碰撞拼合造山一直延续到中三叠世才结束。  相似文献