含金黄铁矿的拉曼光谱特征及其找矿意义初探   总被引：1，自引：0，他引：1       下载免费PDF全文

贾建业  潘兆橹 《地球科学》1997,22(6):575-578

黄铁矿的拉曼光谱特征长期被人们所忽视，经研究发现含金性不同的黄铁矿，其拉曼光谱特征存在诸多显著差异，其中尤以拉曼散射强度和相干度反应最敏感，反之，利用这些差异就可以对金矿床的含金性作出评价，此外，还对含金黄铁矿拉曼光谱产生的差异进行了理论剖析。  相似文献   

阜平群的退变质作用：石榴石的生长和分解   总被引：2，自引：0，他引：2  

肖龙 《矿物岩石》1992,12(1):108-114

本文通过阜平群下部基性麻粒岩中石榴石变斑晶的矿物化学、成分环带,包含变晶结构和冠状体结构的研究,结合石榴石生长前后温压条件估算,确定石榴石生长于区域麻粒岩高峰变质作用之后的近等压降温的热背景中,并由于后期阜平群的快速抬升而发生降压分解,最后利用石榴石的生长成分环带和降压分解现象揭示阜平群在麻粒岩相变质作用之后的退变质PTt轨迹。  相似文献   

河南毛堂金矿黄铁矿的标型特征     

邓宗立 《矿物学报》1992,12(4):344-352

本文通过对黄铁矿的化学成分、形态及微形貌、晶胞参数、热电系数等标型特征的研究结果表明,矿床中黄铁矿普遍含金,最高含金量达4200g/t,是国内外已知黄铁矿含金量最高的。矿石中黄铁矿常量元素S/Fe<2,显示亏硫的特点,微量元素Co/Ni=3.25,S/Se=1.98×10~4,表明为热液成因属性。δ~(34)S平均值为1.10‰,靠近标准值(δ~(34)S=0‰),反映出硫源以深源为主。晶胞参数α值小于理论值,与硫空位等因素有关。热电系数以正值为主,P型黄铁矿比率占84.3％,据此,推断矿体剥蚀程度较浅,深部找矿远景较大。  相似文献   

不可见金的赋存状态研究   总被引：10，自引：0，他引：10  

毛永和 《矿物学报》1990,10(1):66-74,T007,T008

电子探针、扫描电镜和溶矿试验研究证明，在某地“卡林型”金矿中，黄铁矿是最主要的载金矿物。黄铁矿由先期形成的含Au和As很低的自形晶核心和后期形成的含Au和As很高的环边组成，其中Au和As呈正消长关系。因此，根据As的分布情况即可研究和认识Au的分布规律。研究结果为改善矿石的氧化焙烧、氯化处理和氰化浸出工艺设计提供了科学依据。  相似文献   

辽东裂谷白云金矿载金黄铁矿Re-Os定年及其地质意义   总被引：2，自引：0，他引：2  

张朋  李斌  李杰  柴鹏  王希今  沙德铭  时建民 《大地构造与成矿学》2016,(4):731-738

白云金矿是辽东裂谷区内重要的大型金矿之一,长期以来缺少直接的年代学数据。本次对白云金矿不同矿石类型中的8件载金黄铁矿进行了Re-Os同位素定年,获得其等时线年龄为225.3±7.0 Ma(MSWD=5.8),187Os/188Os初始值为2.1±2.8。结合前人的研究成果及本次年代学研究得出:白云金矿形成于印支期,其成矿物质主要为壳源,白云金矿是与印支期岩浆活动有关的热液矿床;其形成构造背景可能为受蒙古–鄂霍次克大洋向南北两侧俯冲之后的陆内后碰撞造山环境。本次研究也为今后在辽东裂谷区寻找与印支期岩浆活动有关的矿床提供了依据。  相似文献   

Pyrite-hydrocarbon Interaction under Hydrothermal Conditions: an Alternative Origin of H2S and Organic Sulfur Compounds in Sedimentary Environments     

DING Kangle  MEI Ping  LUO Yue 《《地质学报》英文版》2016,90(6):2133-2148

Sulfate rocks and organic sulfur from sedimentary organic matter are conventionally assumed as the original sulfur sources for hydrogen sulfide(H_2S) in oil and gas reservoirs. However,a few recent experiments preliminarily indicate that the association of pyrite and hydrocarbons may also have implications for H_2S generation,in which water effects and natural controls on the evolution of pyrite sulfur into OSCs and H_2S have not been evaluated. In this study,laboratory experiments were conducted from 200 to 450° C to investigate chemical interactions between pyrite and hydrocarbons under hydrothermal conditions. Based on the experimental results,preliminary mechanism and geochemical implications were tentatively discussed. Results of the experiments showed that decomposition of pyrite produced H_2S and thiophenes at as low as 330°C in the presence of water and n-pentane. High concentrations of H_2S were generated above 450°C under closed pyrolysis conditions no matter whether there is water in the designed experiments. However,much more organic sulfur compounds(OSCs) were formed in the hydrous pyrolysis than in anhydrous pyrolysis. Generally,most of sulfur liberated from pyrite at elevated temperatures was converted to H_2S. Water was beneficial to breakdown of pyrite and to decomposition of alkanes into olefins but not essential to formation of large amounts of H_2S,given the main hydrogen source derived from hydrocarbons. In addition,cracking of pyrite in the presence of 1-octene under hydrous conditions was found to proceed at 200°C,producing thiols and alkyl sulfides. Unsaturated hydrocarbons would be more reactive intermediates involved in the breakdown of pyrite than alkanes. The geochemistry of OSCs is actually controlled by various geochemical factors such as thermal maturity and the carbon chain length of the alkanes. This study indicates that the scale of H_2S gas generated in deep buried carbonate reservoirs via interactions between pyrite and natural gas should be much smaller than that of thermochemical sulfate reduction(TSR) due to the scarcity of pyrite in carbonate reservoirs and the limited amount of long-chained hydrocarbons in natural gas. Nevertheless,in some cases,OSCs and/or low contents of H_2S found in deep buried reservoirs may be associated with the deposited pyrite-bearing rock and organic matters(hydrocarbons),which still needs further investigation.  相似文献   

山东胶东地区盘子涧金矿成矿流体He-Ar同位素地球化学特征     

毛光周  何铁良  许庆林  杨锋杰  曹明平  安鹏瑞  窦义鑫  于晓卫  刘晓通  孟令强  宋立国 《地球科学与环境学报》2020,(2):188-198

盘子涧金矿地处山东胶东地区蓬莱—栖霞金成矿带南部,是典型的石英脉型金矿,Au品位高,目前对该矿床成矿流体来源的研究尚不深入。在详细的矿相学观察及黄铁矿显微结构研究基础上,对盘子涧金矿主成矿阶段(石英-黄铁矿(绢云母)阶段和金-石英-多金属硫化物阶段)的载金黄铁矿进行了流体包裹体He-Ar同位素组成分析。结果表明:盘子涧金矿载金黄铁矿中流体包裹体的3He丰度为(3.49~8.50)×10^-14 cm^3 STP·g^-1,4He丰度为(2.46~5.06)×10^-8 cm^3 STP·g^-1,3He/4He值为0.8 Ra^1.2 Ra(Ra为大气3He/4He值,Ra=1.39×10^-6),成矿流体表现出以富集地幔为主导的壳幔混合特征;40Ar丰度为(1.02~2.65)×10^-7 cm^3 STP·g^-1,40Ar/36Ar值为896.3~1724.1,是大气饱和水40Ar/36Ar值的2~3倍,与中国东北部幔源岩样品40Ar/36Ar值相近,推测成矿流体主要来源于富集地幔,成矿流体中存在着一定量的地壳放射性成因40Ar,表明地壳流体参与了成矿作用。综上所述,推断山东胶东地区盘子涧金矿成矿流体为以富集地幔流体为主导的壳幔混合流体。  相似文献   

U – Pb zircon ages from leucogneiss in the Etheridge Group and their significance for the early history of the Georgetown region,north Queensland     

LP Black  IW Withnall  P Gregory    JHC Bain 《Australian Journal of Earth Sciences》2013,60(3):385-401

The Timbarra Tablelands pluton is an extensive (～550 km²) complexly zoned intrusion forming one of many predominantly monzogranite I‐type plutons, which constitute the Moonbi Supersuite in northern New South Wales, Australia. It comprises an outer rim of Rocky River monzogranite (Zones 1–3), an intermediate zone of Sandy Creek syenogranite (Zones 4A–4C), surrounding a core of Surface Hill syenogranite (Zones 5–7). The suite is calc‐alkaline, high‐K, and varies from mildly metaluminous to weakly peraluminous with increasing fractionation. Average Rb/Sr ratios range from 0.4 in the least evolved very coarse‐grained monzogranite (Zone 3) to 46 in the most evolved very fine‐grained biotite microgranite (Zone 6). Trace‐element modelling indicates that the observed compositional variation could have been produced by crystal fractionation. New bulk rock major‐ and trace‐element data for 71 samples are presented, and indicate that a compositional continuum exists that varies between 63 and 78 wt% SiO₂. Importantly, there is no systematic chemical variation with spatial distribution of samples from the core of the pluton to its margin, requiring multiple separate pulses of an evolving magma to explain compositional discontinuities. The pluton is interpreted to have been emplaced at mesozonal levels (～180 ± 60 MPa, 5–10 km depth) and crystallised at temperatures between 620 and 820°C under moderately oxidising conditions (log fO₂ = ‐11.5 to ‐19). The association of gold‐molybdenite mineralisation at Timbarra with moderately oxidised I‐type magmas is consistent with fractionation‐redox controls on ore‐element behaviour in magmatic systems in other studies.  相似文献   

胶东焦家金成矿带2420~3206 m垂深金矿物和黄铁矿微量元素特征     

刘鹏瑞  杨德平  宋英昕  舒磊  刘继梅 《矿床地质》2023,42(5):955-977

在胶东莱州吴一村地区完成的3266.06 m深钻,是目前焦家金成矿带最深见矿钻孔,研究钻孔揭露的深部矿石中金矿物及黄铁矿微量元素特征,对探讨深部成矿作用演化具有重要意义。笔者采取深钻中2420~3206 m垂深的岩（矿）芯样品进行了详细的岩相学和矿相学研究,结合扫描电镜和电子探针微区分析,研究了矿石中金矿物的赋存状态和成分。对不同成矿阶段形成的黄铁矿进行了LA-ICPMS微量元素分析。研究结果表明,深部矿石中载金矿物主要为黄铁矿,其次为石英、黄铜矿、方铅矿,可见金主要以自然金和银金矿的形式存在,以晶隙金和裂隙金为主,其次为包体金。与浅部金矿床比较,深部金的成色较高。黄铁矿分为6种类型,第Ⅰ成矿阶段形成富Co型黄铁矿Py1,第Ⅱ成矿阶段形成富Ni型黄铁矿Py2a和Py2b,第Ⅲ成矿阶段形成富Au、As型黄铁矿Py3a和富Au、Ag、Pb、Bi型黄铁矿Py3b,第Ⅳ成矿阶段形成贫微量元素黄铁矿Py4。其中,Py1和Py2a发生强烈破碎,裂隙表面对热液中的Au络合物产生吸附作用,对金沉淀富集起重要作用。黄铁矿中Co、Ni、As等微量元素主要以类质同象形式赋存,而Au、Ag、Cu、Pb、Zn、Bi等主要以纳米级、微米级矿物包体形式赋存。Pb+Bi、Cu+Pb+Zn、Te+Bi与Au+Ag呈明显正相关,而Au与As相关性较差。黄铁矿中Co、Ni含量较低,而Au+Ag+As或Au+Ag+Pb+Bi+Cu含量较高指示成矿有利。另外,黄铁矿中Co、Ni含量较高,并且破碎强烈,成矿相关元素含量较高也指示成矿有利。  相似文献   

悦洋银多金属矿床黄铁矿化学成分标型特征及其矿床学意义          下载免费PDF全文

贾伟晨  王翠芝  陈鹏 《地质找矿论丛》2023,38(2):146-154

悦洋银多金属矿目前的保有储量已不能满足矿山持续生产的需求,需要进行深-边部找矿工作。本文基于成因矿物学理论,通过矿物地球化学方法对矿区内的黄铁矿化学成分标型特征进行了研究。结果表明：(1)黄铁矿中w(Co)/w(Ni)值、As-Co-Ni三角图解、w(Au)/w(Ag)值、w(S)/w(Se)值等特征,联合显示该黄铁矿的成因为岩浆热液(火山热液成因)型;(2)悦洋银多金属矿中稀散元素Se、Ga、Ge可以作为伴生资源开发利用;(3)由黄铁矿微量元素中简化的前缘晕元素组合(As-Sb-Ag)、近矿晕元素组合(Au-Cu-Pb-Zn)、尾晕元素组合(Co-Ni)的三元相图显示,采区矿脉主要处于矿体的中下部,说明在深-边部还有一定的找矿前景;(4)基于该矿床硫化物的研究,结合区域地质、矿区地质特征,岩相学特征等,认为蚀变分带是悦洋银多金属硫化物矿体的找矿标志,即浅部碳酸盐化带、中部硅化+冰长石化带、深部绢英岩化带、硅化+冰长石化带是寻找矿体的直接标志。  相似文献