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排序方式: 共有110条查询结果,搜索用时 46 毫秒
1.
本文介绍了海水中砷标准物质的研制过程,其中包括溶液的配制、均匀性和稳定性检验,标样的分析方法。并对标准物质的定值数据进行统计处理,两种浓度的定值结果分别为:1.00μg/cm3±0.04μg/cm3和51.0μg/dm3±2.6μg/dm3。两种浓度砷标准物质的稳定期均为一年 相似文献
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The distribution of dissolved and participate concentrations of As, Cr and V was investigated in the mixing area of the Po river in five surveys over the period March 1992-March 1995. The data obtained indicate noticeable contamination of coastal waters of the northern Adriatic with Cr but not As or V. Total dissolved concentrations for As and V were comparable with oceanic levels but were higher by a factor of 4 for Cr. These results suggest either low anthropogenic inputs of As and V, from terrigenous and atmospheric sources, or efficient removal mechanisms. The investigated metals had low reactivity during freshwater-seawater mixing and the distribution of concentrations in the dissolved and solid phases suggests that the dilution process is the main factor controlling the transport of these metals to the sea in low-to-medium solid transport conditions. Further investigations are required to elucidate the behavior of these metals during high solid transport conditions. Significant changes in the speciation of As occurred during the transition between the two end-member matrices. In the coastal waters of the northern Adriatic, the arsenite fraction in winter, and the arsenite and dimethylarsinate fractions in summer increased with respect to riverine waters. Changes in the speciation of chromium were minor, but also showed a small increase in reduced species in marine waters. 相似文献
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原子荧光光谱法测定化探样品时有机质对As,Sb,Bi的干扰 总被引:1,自引:0,他引:1
通过研究黑龙江省森林沼泽景观区有机水系沉积物(泥炭)、土壤中As,Sb,Bi的测定结果,发现样品中的有机质对王水消解氢化物原子荧光法测定上述元素存在极大的干扰,提出采用低温(<450℃)灰化处理可完全消除干扰。对比研究还发现,过去森林沼泽景观区的区域化探扫面资料中的As,Sb,Bi数据存在问题,应专门对其进行评价研究。 相似文献
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YU Yunmei ZHU Yongxuan & GAO Zhenmin Key Laboratory of Ore Deposit Geochemistry Chinese Academy of Sciences Guiyang China 《中国科学D辑(英文版)》2004,47(5)
Arsenopyrite is one of the most important pri-mary arsenic mineral. In the Eh-pH diagram of the As-O2-S-H2O system, if the total arsenic concentration (TAs) is taken to be 0.75 mg/L, the total sulfur con-centration, 32 mg/L, the temperature, 25℃and the pressure, one atmosphere pressure for the discrimina-tion of arsenic species, it may be found that under hy-pergene conditions, arsenopyrite is a moderately stable mineral. Only in the strongly alkaline and reducing environment can arsenopy… 相似文献
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北京市不同土地利用类型的土壤砷含量特征 总被引:42,自引:4,他引:42
通过对北京市菜地、稻田、果园、绿化地、麦地以及自然土壤6种土地利用类型共500 个土壤样品的调查分析,探讨了不同土地利用方式对土壤砷积累的影响。与北京市土壤背景值相比,砷在土壤中均有不同程度的增加,累积现象比较普遍。在6种土地利用类型中,自然土壤的砷含量最低,最接近背景值;菜地和稻田的土壤砷含量的增加最为显著。以基线值为标准,北京市涉及土地利用的土壤砷含量总体超标率为1.8%;6种土地利用类型中,菜地、果园、麦地三种土壤砷含量的超标率分别为2.6%、2.7%、0.7%。土壤砷含量的平均值由高到低分别为:稻田>绿化地>菜地>果园>麦地>自然土壤。 相似文献
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Recent evaluations of acute and chronical toxicity of arsenic resulted in a reduction of the standard value for total arsenic from 40 μg/L to 10 μg/L in drinking water which will be valid in Germany after a transition period as from January 1996. Arsenic is well known as substance of deep groundwaters, mainly of geogenic origin and normally found as As(III) or As(V). As(V) is well removable by flocculation and filtration after adding iron salts. As(III), however, has to be oxidized first to As(V). Therefore, it is important for treatment techniques to be able to distinguish between As(III) and As(V). A modified determination of As(III) using flow injection analysis was installed and optimized in order to investigate whether As(III) may be oxidized to As(V) by bacteria in natural waters. The results showed that at 4°C, no As(III)-oxidation was observed within 14 days. At room temperature, however, in the bacteria-containing samples, an As(III)-oxidation was found starting after 3 to 7 days. After 14 days, no As(III) was left over. In contrast, in the sterile samples, no As(III)-oxidation could be observed within 14 days. These results demonstrated that microbial processes influence the oxidation of As(III) to As(V) in natural waters. 相似文献
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Cearreta A Irabien MJ Leorri E Yusta I Quintanilla A Zabaleta A 《Marine pollution bulletin》2002,44(6):487-503
The distribution and abundance of benthic foraminifera and a range of elements have been analysed in six long cores (up to 10 m long) from the Bilbao estuary, N. Spain, to document environmental transformation of this estuarine ecosystem and to determine sediment contamination levels. Three different environmental zones could be distinguished in the recent sedimentary record based on its microfaunal and geochemical contents. Initially, a pre-industrial zone containing very abundant and diverse foraminiferal assemblages together with baseline metal levels. Secondly, an older industrial zone exhibiting co-existence of abundant and diverse foraminiferal assemblages with high concentrations of metals. Finally, a younger industrial zone with extreme concentrations of metals and barren of indigenous foraminifera. This environmental transformation has been caused by the discharge of untreated domestic and industrial effluents during the last 150 years. The occurrence of foraminifera in the two industrial zones and along the estuary is not related to defined levels of metals, and this seems to confirm oxygen limitation as the key factor to explain complete estuarine defaunation during deposition of the younger industrial zone (period 1950-2000). Effectiveness of current regeneration schemes could be assessed using microfaunal and geochemical proxies as environmental quality indicators. 相似文献