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941.
Fast food restaurants and liquor stores—vice stores—have been shown to be more prevalent in predominantly Black and low income U.S. neighborhoods, and are associated with a number of health risks and social ills. The purpose of this study was to investigate in the City of Chicago vice store density and spatial distribution as a function of racial, socioeconomic, and other population characteristics; to examine spatial clustering among these outlets; and to study how store turnover follows population change over a 13-year period. We used spatial point process analysis to fit linear and non-linear models for the intensity function of stores. Spatial clustering was estimated using the K function. We found heterogeneous associations between stores and population characteristics, with the most consistent finding being a positive association between percent Black and liquor store exposure. A high degree of spatial clustering was evident, and liquor stores were more likely to stay in business over time than fast food restaurants. However, when liquor stores closed, they were more likely to be replaced by non-vice businesses. Results suggest that vice stores are associated with lower positions in racial and socioeconomic hierarchies, and this patterning is often durable over time.  相似文献   
942.
A series of natural omphacites from a wide range of P, T occurrences were investigated by electron microprobe (EMP), infrared (IR)-, Mössbauer (MS)- and optical spectroscopy in the UV/VIS spectral range (UV/VIS), secondary ion mass spectrometry (SIMS) and single crystal structure refinement by X-ray diffraction (XRD) to study the influence of hydrogen loss on valence state and site occupancies of iron. In accordance with literature data we found Fe2+ at M1 as well as at M2, and in a first approach assigned Fe3+ to M1, as indicated by MS and XRD results. Hydrogen content of three of our omphacite samples were measured by SIMS. In combination with IR spectroscopy we determined an absorption coefficient: ε i,tot = 65,000 ± 3,000 lmolH2O ?1 cm?2. Using this new ε i,tot value, we obtained water concentrations ranging from 60 to 700 ppm H2O (by weight). Hydrogen loss was simulated by stepwise heating the most water rich samples in air up to 800°C. After heat treatment the samples were analyzed again by IR, MS, UV/VIS, and XRD. Depending on the type of the OH defect, the grade of dehydration with increasing temperature is significantly different. In samples relatively poor in Fe3+ (<0.1 Fe3+ pfu), hydrogen associated with vacancies at M2 (OH bands around 3,450 cm?1) starts to leave the structure at about 550°C and is completely gone at 780°C. Hydrogen associated with Al3+ at the tetrahedral site (OH bands around 3,525 cm?1, Koch-Müller et al., Am Mineral, 89:921–931, 2004) remains completely unaffected by heat treatment up to 700°C. But all hydrogen vanished at about 775°C. However, this is different for a more Fe3+-rich sample (0.2 Fe3+ pfu). Its IR spectrum is characterized by a very intense OH band at 3,515 cm?1 plus shoulder at 3,450 cm?1. We assign this intense high-energy band to vibrations of an OH dipole associated with Fe3+ at M1 and a vacancy either at M1 or M2. OH release during heating is positively correlated with decrease in Fe2+ and combined with increase in Fe3+. That dehydration is correlated with oxidation of Fe2+ is indirectly confirmed by annealing of one sample in a gas mixing furnace at 700°C under reducing conditions keeping almost constant OH? content and giving no indication of Fe2+-oxidation. Obtained data indicate that in samples with a relatively high concentration of Fe2+ at M2 and low-water concentrations, i.e., at a ratio of Fe2+ M2/H > 10 dehydration occurs by iron oxidation of Fe2+ exclusively at the M2 site following the reaction: \( {\left[ {{\text{Fe}}^{{{\text{2 + [ M2]}}}}{\text{OH}}^{ - } } \right]} = {\left[ {{\text{Fe}}^{{{\text{3 + [ M2]}}}} {\text{O}}^{{{\text{2}} - }} } \right]} + {\text{1/2}}\;{\text{H}}_{{\text{2}}} \uparrow . \) In samples having relatively low concentration of Fe2+ at M2 but high-water concentrations, i.e., ratio of Fe2+ M2/H < 5.0 dehydration occurs through oxidation of Fe2+ at M1.  相似文献   
943.
During the late Maastrichtian to early Danian the Neuquén Basin of Argentina was adjacent to an active volcanic arc to the west and an extensive land area to the northeast. Mineralogical and geochemical studies of the Bajada del Jagüel in the Neuquén Basin indicate a generally warm climate with seasonal changes in humidity and an open seaway to the South Atlantic that maintained marine conditions. Biostratigraphic and quantitative foraminiferal and nannofossil analyses indicate that sediment deposition during the late Maastrichtian (zones CF4-CF2, N. frequens) occurred in relatively shallow middle neritic (100 m) depths with largely dysaerobic bottom waters (abundant low O2 tolerant benthics) and fluctuating sea level. Calcareous nannofossils indicate a high stress marine environment dominated by Micula decussata. Planktic foraminifera mimic the post-K/T high stress environment with alternating blooms of the disaster opportunists Guembelitria and low oxygen tolerant Heterohelix groups, indicating nutrient-rich surface waters and an oxygen depleted water column. The high stress conditions were probably driven by high nutrient influx due to upwelling and terrestrial and volcanic influx. The K/T boundary is marked by an erosional surface that marks a hiatus at the base of a 15-25 cm thick volcaniclastic sandstone, which contains diverse planktic foraminiferal zone P1c assemblages and nannofossils of zone NP1b immediately above it. This indicates deposition of the sandstone occurred 500 ky after the K/T hiatus. No evidence of the Chicxulub impact or related tsunami deposition was detected.  相似文献   
944.
针对城市环境下GNSS车辆导航存在卫星信号易受影响的问题,利用GNSS/INS组合算法提高复杂环境下城市车辆定位性能。基于城市环境下实测GNSS数据评估分析定位结果,使用GNSS/INS组合的常规卡尔曼滤波算法实现卫星失锁区域导航。同时,提出一种基于新息的自适应卡尔曼滤波算法,可有效增强卫星数较少及信号干扰严重区域的车辆导航定位能力。该方法利用量测与预测的关系构造自适应因子,改善定位精度。结果表明,常规卡尔曼滤波可在20 s卫星信号失锁情况下保证亚m级导航精度,自适应卡尔曼滤波算法在卫星信号受到严重干扰时,其定位精度相比于常规卡尔曼滤波算法提高30%,可满足在城市复杂环境下的高精度、高可靠性车辆导航定位服务需求。  相似文献   
945.
The paper reports on preliminary observations from northern Jordan aimed at testing the view that people migrate from areas of relatively high potential for cultivation to the marginal semi-arid/arid frontier because of social differentiation, political factors or environmental constraints. Cultivated areas have been mapped from multi-date remotely sensed imagery, a typology of fields in the area has been constructed, and their dynamics between 1972 and 1992 analysed. In addition, semi-structured interviews with farmers attempted to understand the reasoning behind village growth, changing farming systems and cultivation practices. The findings are discussed in the context of the area's demography and national and regional shifts in economic policy.  相似文献   
946.
Using the new data from Hipparcos and the TD-1 UV data, we fix the positions of three objects, HD 104237, HD 100546 and ε Cha in the HR diagram and discuss their theoretical evolutionary status.  相似文献   
947.
The Leonid meteor storms of 1833 and 1966   总被引:2,自引:0,他引:2  
The greatest Leonid meteor storms since the late eighteenth century are generally regarded as being those of 1833 and 1966. They were evidently due to dense meteoroid concentrations within the Leonid stream. At those times, the orbit of Comet 55P/Tempel–Tuttle was significantly nearer that of the Earth than at most perihelion returns, but still some tens of Earth radii away. Significantly reducing this miss distance can be critical for producing a storm. Evaluation of differential gravitational perturbations, comparing meteoroids with the comet, shows that, in 1833 and 1966 respectively, the Earth passed through meteoroid trails generated at the 1800 and 1899 returns.  相似文献   
948.
根据Hipparcos的资料和TD-1对εCha和HD100546的紫外观测资料讨论了εCha、HD104237和HD100546在赫罗图上的位置以及它们的演化状态.  相似文献   
949.
西安地区旱涝气候的长期变化   总被引:3,自引:2,他引:1  
根据西安丰富的历史旱涝史料,建立了近1500年旱涝序列,并采用滑动滤波、功率谱分析、谐波分析等方法,对西安地区旱涝气候的长期变化进行分析。  相似文献   
950.
周瑶琪 《现代地质》1995,9(1):91-98
摘要:从大规模撞击事件的基本动力学和热力学公式推导出发,讨论了白垩纪-第三纪界线(K/T界线)事件能量随时间的释放过程,并对发生热核聚变反应的条件进行了分析。最后,还对其可能的事件地质学意义进行了讨论.  相似文献   
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