微波消解-火焰原子吸收光谱法测定石英砂中的氧化钙和氧化镁     

鲁青庆 《岩矿测试》2005,24(4):314-316

采用微波消解-硼酸络合-火焰原子吸收光谱法测定石英砂中的氧化钙和氧化镁。样品在MK-Ⅲ型实验室微波炉上消解,消解压力为2.0 MPa、消解时间为5 m in,以硼酸络合消除氢氟酸的影响。方法已用于实际样品的测定,7次测定的相对标准偏差(RSD)小于5%,加标回收率为95.0%~104.2%。  相似文献   

苏皖地区石炭纪海相碳酸盐岩碳和氧同位素演化规律   总被引：5，自引：2，他引：5  

林春明  凌洪飞  王淑君  张顺 《地球化学》2002,31(5):415-423

对江苏南京孔山和安徽巢湖凤凰山石炭系碳酸盐岩C、O稳定同位素进行了测定。结果表明，苏皖地区石炭系δ^13C,δ^18O记录是以4个同位素演化阶段为特征，前3个同位素演化阶段与同时代的北美石炭纪相似，仅仅是内部演化特征略有不同，这反映了区域性的沉积环境的不同变化。在金陵组下部、和州组下部、黄龙组中下部和船山组层段，δ^13C表现出明显的正漂移，这可能是受植物和生物量增长、有机碳储藏量增加所引起的。δ^18O记录总体上与δ^13C值呈相似的变化趋势。δ^18O增加记录了气候变冷和冰川作用的结果。δ^18O负漂移与气候变暖和冰川消融是一致的。在浅水潮坪环境，大气淡水的淋滤作用使δ^13C和δ^18O值明显降低。  相似文献   

碳酸盐岩差异性风化成土特征及其对石漠化形成的影响   总被引：35，自引：0，他引：35  

孙承兴  王世杰  周德全  李瑞玲  李艳丽 《矿物学报》2002,22(4):308-314

碳酸盐岩极低的酸不溶物含量使岩石风化产生的残积土壤物质数量极少，并产生巨大的体积缩小，促使早期形成的残积土在重力作用下不断向下塌陷。显著的差异性风化使基岩面强烈起伏，甚至形成大量的岩溶尘洼地、裂隙、地下管道、洞穴系统等。在重力和水的作用下，土粒沿垂直和水平方向上经微距离或短距离搬运到上述低洼或地下空间中，甚至由地下河带到更远的地方，这是碳酸盐岩地区土壤丢失的重要方式，也是形成石漠化最主要的地质因素。土壤在地表分布高度不均匀，是碳酸盐岩地区的地表少土的重要原因。对于酸不溶物含量相当的石灰岩和白云岩而言，由于白云岩的差异性风化明显弱于石灰岩，以及受各种应力作用后，白云岩形成的节理及裂隙密集而均匀，从而提高了近地表白云岩的含水能力，延长了风化过程中的水－岩反应时间，使风化作用可以相对集中于地表或近地表进行，有利于岩石的整体风化作用的进行，同时使白云岩风化壳基岩面起伏相对较小，风化残积形成的土壤分布也相对均匀。因此，白云岩区地表土层较厚，石漠化程度也稍弱于灰岩区。  相似文献   

Sub-wavebase cross-bedded grainstones on a distally steepened carbonate ramp, Upper Miocene, Menorca, Spain   总被引：1，自引：0，他引：1  

Luis Pomar  Antonio Obrador†  & Hildegard Westphal‡ 《Sedimentology》2002,49(1):139-169

Cross‐bedded grainstones on carbonate ramps and shelves are commonly related to the locus of major wave energy absorption such as shorelines, shoals or shelf breaks. In contrast, on the Early Tortonian carbonate platform of Menorca (Balearic Islands), coarse‐grained, cross‐bedded grainstones are found at a distance from the palaeoshoreline where they were deposited below the wavebase. Excellent exposures along continuous outcrops on the sea cliffs of Menorca reveal the depositional profile and three‐dimensional distribution of the different facies belts of the Tortonian ramp depositional system. Basinward from the palaeoshoreline, fan deltas and beach deposits pass into 5‐km‐wide gently dipping bioturbated dolopackstone (inner and middle ramp), then into 12–20°‐dipping dolograinstone/rudstone clinobeds (ramp slope) and, finally, into subhorizontal fine‐grained basinal dolowackestone to dolopackstone (outer ramp). In this Miocene example, coarse‐grained grainstones exist in five different settings other than beach deposits: (1) on the middle ramp, where cross‐bedded grainstones were deposited by currents roughly parallel to the shoreline at 40–70 m estimated water depth and are interbedded with gently dipping bioturbated dolomitized packstones; (2) on the upper slope, where clinobeds are composed mostly of in situ rhodoliths and red‐algae fragments; (3) on the lower slope, as small‐scale bedforms (small three‐dimensional subaqueous dunes) migrating parallel to the slope; (4) at the transition between the lower slope and the outer ramp, where mollusc‐rich and rhodolithic rudstones and grainstones, interbedded in dolomitized laminated wackestones containing abundant planktonic foraminifera, infill slide/slump scars as upslope‐backstepping bodies (backsets); (5) at the toe of the slope, where coarse skeletal grainstones indicate bedform migration parallel to the platform margin, induced by currents at more than 150 m estimated water depth. This Late Miocene example also illustrates how changes in intrabasinal environmental conditions (nutrients and/or temperature) may produce changes in stratal patterns and facies architecture if they affect the biological system. Two depositional sequences compose the Miocene platform on Menorca, where a reef‐rimmed platform prograded onto an earlier distally steepened ramp. The transition from the ramp to the reef‐rimmed platform was effected by an increase in accommodation space caused by ecological changes, promoting a shift from a grain‐ to a framework‐producing biota.  相似文献   

The nature of calcareous deposits along pan margins in eastern central Namibia     

Florias Mees 《地球表面变化过程与地形》2002,27(7):719-735

In a region along the western margin of the Kalahari in eastern Namibia and western Botswana, many pan basins have mainly calcareous deposits along part of their margins. These are typically lined by low vertical scarps. In Namibia, these pans are mainly located in dry river beds. The petrographical study of these deposits demonstrates that they consist of lacustrine sediments that have to a varying extent been affected by early‐diagenetic processes and by the formation of late‐diagenetic features. The original composition of the deposits ranges from highly calcareous sediments, typically with ostracod, diatom and charophyte remains, to entirely non‐calcareous diatomites. The deposits generally show an upward increase in total carbonate content, which is mainly a synsedimentary feature. The early‐diagenetic processes that affected the deposits include the formation of orthic siliceous nodules. At a later stage, secondary calcite enrichment occurred, leaving only the silica‐impregnated sections unaffected. This enrichment partly accounts for the upward increase in total carbonate content in some profiles and often resulted in the development of a highly calcareous surface horizon. Sepiolite and amorphous silica that are part of the groundmass of the deposits may also partly have formed at this stage. Late‐diagenetic features include various forms of secondary calcite and silica. This study of pan basins in eastern central Namibia indicates that a lacustrine rather than purely pedogenic origin should also be considered for calcareous deposits that commonly occur along pan margins in other parts of southern Africa. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

碳酸盐岩潜山储层垂向分带及油气藏流体分布规律   总被引：8，自引：1，他引：8  

王俊明  肖建玲  周宗良  梁宝琴 《新疆地质》2003,21(2):210-213

从古岩溶形成的基本条件出发，提出可溶性岩石和具溶蚀性的流动水是岩溶发育的基本条件，古岩溶与古风化壳常共生．受储层结构的非均质性、构造圈闭分割性、流体分布不完善性及高地温场等因素影响，流体在古潜山奥陶系储层的分布很复杂，孔、洞、缝发育程度及搭配好坏是决定油气产量的核心，圈闭条件与流体分布也密切相关．  相似文献   

中国油气储层地质研究面临的挑战和发展方向   总被引：36，自引：6，他引：36  

罗平  裘怿楠  贾爱林  王雪松 《沉积学报》2003,21(1):142-147

论述了我国采取“稳定东部 ,发展西部”的油气战略后 ,油气地质所面临的形势 ,以及油气工业的发展对储层地质提出四个领域的挑战 :深部储层、挤压盆地储层、低渗透储层和碳酸盐岩储层 ;这些都是石油勘探开发中久攻不克的难题。根据我国陆上东西部油气区的勘探开发实际和近年的储层研究实践 ,文章系统多视角地分析了这四个难题 ,并提出了相应客观的研究思路和研究方向。  相似文献   

碳酸盐岩与泥质烃源岩生气规律对比研究   总被引：10，自引：1，他引：10  

黄志龙  钟宁宁  张四海 《地球化学》2003,32(1):29-34

配制了两套成熟度相近的碳酸盐岩和泥质岩丰度系列样品。采用半封闭外加温加压式热压模拟装置对碳酸盐岩的生烃情况进行了热模拟实验，研究了碳酸盐岩生气量随成熟度和温度变化的趋势，探讨了碳酸盐岩生气的变化规律。碳酸盐岩与泥质岩的生烃潜力是有机质质量和有机质丰度的函数，与岩性无关；碳酸盐岩的产气规律与泥质岩相似，而且两者产烃的量级也相当，并不存在碳酸盐岩生排烃效率高的现象；碳酸盐岩和泥质岩总有机碳(TOC)含量在热模拟过程中基本上不发生变化；不同岩性的有机质的产烃效率主要受温度和有机质类型决定。  相似文献   

Petrogenesis of the Ulsan carbonate rocks from the south-eastern Kyongsang Basin, South Korea   总被引：1，自引：0，他引：1  

Kyounghee Yang  Jin-Yeon Hwang  Sung-Hyo Yun 《Island Arc》2003,12(4):411-422

Abstract The petrogenesis of the Ulsan carbonate rocks in the Mesozoic Kyongsang Basin of South Korea, which have previously been interpreted as limestone of Paleozoic age, is reconsidered in the present study. Within the Kyongsang Basin, a small volume of carbonate rocks, containing a magnetite deposit and spatially associated ultramafic rocks, is surrounded by sedimentary, volcanic and granitic rocks of the Mesozoic age. The simple cross‐cutting relationships and other outcrop features of the area indicate that the carbonate rocks are an intrusive phase and younger than the other surrounding Mesozoic rocks. The Ulsan carbonates have low concentrations of rare earth elements (REE) and trace elements with the carbon and oxygen isotope values in the range of δ¹³C_PDB = 2.4 to 4.0‰ and δ¹⁸O_SMOW = 17.0 to 19.5‰. Outcrop evidence and geochemical signatures indicate that the Ulsan carbonates were formed from crustal carbonate melts, which were generated by the melting/fluxing of crustal carbonate materials, caused by the emplacement‐related processes of alkaline A‐type granitic rocks. Compared to typical mantle‐derived carbonatites associated with silica‐undersaturated, strongly peralkaline systems, the relatively small size and geochemical characteristics of the Ulsan carbonates reflect carbonatite genesis in a silica‐saturated, weakly alkali intrusive system. Major deep‐seated tectonic fractures formed by the collapse of the cauldron or the rift system associated with the opening of the East Sea (Japan Sea) might have facilitated the ascent of the crustal carbonate melts.  相似文献   

龙门山地区泥盆纪碳酸盐与硅质碎屑的混积相与混积机理   总被引：7，自引：0，他引：7       下载免费PDF全文

李祥辉  刘文均  郑荣才 《沉积与特提斯地质》1997,17(3):1-10

碳酸盐与陆源碎屑的混合沉积研究至今尚未引起足够重视。文献屈指可数。扬子西经缘龙门山地区盆纪发育了了这类良好的混合沉积。作者根据实际材料，首次从这一思路出发，识别该区泥盆纪Ｅｍｓｉａｎ期到Ｇｉｖｅｔｉａｎ早期的混积相四种，混积亚相约１４种，阐明了其优势混积作用；根据混积作用特征、沉积背景关系，划分出两大混积类型，即泥质背景下的混积１型和砂灰质背景下的混积Ⅱ型；对混积作用机理进行了探讨；并指出不同级次  相似文献