海水中磷酸盐在固体粒子上阴离子交换作用　海水中磷酸盐-固体粒子相互作用的台阶型等温线     

赵宏宾  刘莲生  张正斌 《海洋与湖沼》1997,28(2):172-178

通过研究氯化钠溶液中磷酸盐在4种固体粒子（针铁矿、δ－氧化锰、伊利石和高岭石）上的交换等温线及钙对上述交换等温线的影响，发现磷酸盐液－固界面作用的台阶型等温线（2个台阶），可用分级离子／配位子交换等温式定量描述。钙能够促进磷酸盐在针铁矿和δ－氧化锰上的交换作用，其机理是交换在固体粒子上的钙再结合溶液中的磷酸盐，形成表面无机三元络合物。  相似文献   

Estuary/ocean exchange and tidal mixing in a Gulf of Maine Estuary: A Lagrangian modeling study   总被引：2，自引：0，他引：2  

Ata Bilgili  Jeffrey A. Proehl  Daniel R. Lynch  Keston W. Smith  M. Robinson Swift 《Estuarine, Coastal and Shelf Science》2005,65(4):607-624

A Lagrangian particle method embedded within a 2-D finite element code, is used to study the transport and ocean–estuary exchange processes in the well-mixed Great Bay Estuarine System in New Hampshire, USA. The 2-D finite element model, driven by residual, semi-diurnal and diurnal tidal constituents, includes the effects of wetting and drying of estuarine mud flats through the use of a porous medium transport module. The particle method includes tidal advection, plus a random walk model in the horizontal that simulates sub-grid scale turbulent transport processes. Our approach involves instantaneous, massive [O(500,000)] particle releases that enable the quantification of ocean–estuary and inter-bay exchanges in a Markovian framework. The effects of the release time, spring–neap cycle, riverine discharge and diffusion strength on the intra-estuary and estuary–ocean exchange are also investigated.The results show a rather dynamic interaction between the ocean and the estuary with a fraction of the exiting particles being caught up in the Gulf of Maine Coastal Current and swept away. Three somewhat different estimates of estuarine residence time are calculated to provide complementary views of estuary flushing. Maps of residence time versus release location uncover a strong spatial dependency of residence time within the estuary that has very important ramifications for local water quality. Simulations with and without the turbulent random walk show that the combined effect of advective shear and turbulent diffusion is very effective at spreading particles throughout the estuary relatively quickly, even at low (1 m²/s) diffusivity. The results presented here show that a first-order Markov Chain approach has applicability and a high potential for improving our understanding of the mixing processes in estuaries.  相似文献   

珠江口水体中铜与悬浮颗粒物相互作用的研究     

丘耀文  王肇鼎  张正斌  刘莲生 《热带海洋学报》1995,(4)

使用无机离子交换法研究珠江口水体中铜与悬浮颗粒物的相互作用，测出钢与悬浮颗粒物相互作用的ｐＨ曲线呈Ｓ形，其分级离子交换等温线是一种新的“台阶”型；从分级离子交换理论求得分级平衡常数Ｋ１为５．０，Ｋ２为７８．１，珠江口水体中铜的表观络合容量为０．９２μｍ及其条件稳定常数为３．５×１０７。  相似文献   

几丁糖酯原料药稳定性研究     

吕志华  赵峡  徐家敏 《中国海洋大学学报(自然科学版)》2001,31(6):842-848

该文建立高效凝胶渗透色谱法 (HPGPC) ,明胶比浊法 ,氧瓶燃烧法三种分析方法考察海洋硫酸多糖药物几丁糖酯的稳定性 ,采用这三种方法分别考察几丁糖酯原料药在高温、高湿、强光照射及加速条件下分子量及分布宽度、样品中硫酸根含量及样品含量的变化情况。结果表明 :三种方法均适用于几丁糖酯的稳定性考察 ,几丁糖酯在上述影响因素条件下稳定性良好  相似文献   

热带西太平洋海-气热量交换特征分析     

吴迪生 《热带海洋学报》1993,(1)

本文采用1985年12月12日至1986年2月8日“向阳红14”号调查船在太平洋调查所获海洋水文气象资料,计算了四种热交换量。结果表明:海-气热输送与天气系统和海洋水文条件关系密切。冬季,在各种天气系统条件下西太平洋及中太平洋的大气主要是从海洋得到热量,其中以黑潮流经的海域最为明显,而热交换的方式主要是海洋以潜热的形式把热量输送给大气。  相似文献   

Three-Dimensional Velocity Field and Cross-Frontal Water Exchange in the Kuroshio Extension     

Susana Sainz-Trápaga  Takashige Sugimoto 《Journal of Oceanography》2000,56(1):79-92

A spread of warm water from the first crest of the Kuroshio Extension is periodically enhanced by northward warm water intrusions from the main current. The water type in the spread area was previously found to be the same as that in the Kuroshio front at depth. In looking for the possible mechanism responsible for the northward warm water intrusions, a dynamic analysis in the Kuroshio front was carried out by using CTD, ADCP, AVHRR and ARGOS buoy data, obtained in 1996 by the R.V. Hakuho Maru. Downstream, cross-stream and vertical velocities in the Kuroshio Extension were found by using a "stream coordinate system". The velocity field in the Kuroshio front at the first crest showed a double structure with two surface velocity maxima. In the inner part of the front, relatively high cross-stream (northward) and vertical (upward) velocities were found. Thus, this study suggests that while water particles flow downstream along the first stationary meander of the Kuroshio Extension, they also experience lateral and vertical movements which allow the deeper water from an upstream location to rise to the surface layer, and in certain locations to deflect northward. By assuming isopycnal movement and conservation of potential vorticity, it was found that in those locations where anticyclonic curvature of the meander increases, warm water is more likely to deflect northward. High ageostrophic components observed in the first 300 m of the water column are probably related to the relatively high cross-stream and vertical velocities in the inner part of the front.  相似文献   

A preliminary study of carbon system in the East China Sea   总被引：1，自引：0，他引：1  

Shizuo Tsunogai  Shuichi Watanabe  Junya Nakamura  Tsuneo Ono  Tetsuro Sato 《Journal of Oceanography》1997,53(1):9-17

In the central part of the East China Sea, the activity of CO₂ in the surface water and total carbonate, pH and alkalinity in the water column were determined in winter and autumn of 1993. The activity of CO₂ in the continental shelf water was about 50 ppm lower than that of surface air. This decrease corresponds to the absorption of about 40 gC/m²/yr of atmospheric CO₂ in the coastal zone or 1 GtC/yr in the global continental shelf, if this rate is applicable to entire coastal seas. The normalized total carbonate contents were higher in the water near the coast and near the bottom. This increase toward the bottom may be due to the organic matter deposited on the bottom. This conclusion is supported by the distribution of pH. The normalized alkalinity distribution also showed higher values in the near-coast water, but in the surface water, indicating the supply of bicarbonate from river water. The residence time of the East China Sea water, including the Yellow Sea water, has been calculated to be about 0.8 yr from the excess alkalinity and the alkalinity input. Using this residence time and the excess carbonate, we can estimate that the amount of dissolved carbonate transported from the coastal zone to the oceanic basin is about 70 gC/m²/yr or 2 GtC/yr/area-of-global-continental-shelf. This also means that the rivers transport carbon to the oceans at a rate of 30 gC/m²/yr of the coastal sea or 0.8 GtC/yr/ area-of-global shelf, the carbon consisting of dissolved inorganic carbonate and terrestrial organic carbon decomposed on the continental shelf.  相似文献   

离子色谱分析在黄土和粉尘研究中的应用   总被引：1，自引：0，他引：1  

王丹  屈文军  张小曳  严立文  曹国良 《海洋地质与第四纪地质》2005,25(1):113-118

黄土中存在着大量的碱金属及碱土金属，以往的测试方法多为原子吸收和ICP—MS，离子色谱法在测试黄土样品的碱金属和碱土金属元素含量中应用不多。将黄土地质标准样品进行消解后用离子色谱进行测试，测试效果良好，重复测试的相对标准偏差小于5％，与推荐值的相对误差小于5％，准确度和精密度符舍相关的质量控制要求。本实验方法测试的离子含量都在仪器响应呈线性的最佳测试范围之内，标准曲线经回归后相关系数均达到0．9999。黄土样品的分析结果与粉尘气溶胶样品的离子分析结果对比表明，此方法对于探讨粉尘起源以及沙尘暴天气的研究具有重要意义。  相似文献   

砷酸根的液—固界面交换吸附研究——pH和Ca(Ⅱ)的影响     

赵卫红  张正斌 《中国海洋大学学报(自然科学版)》1997,(2)

研究ｐＨ和Ｃａ（Ⅱ）对砷酸根在海水与ＮａＣｌ介质中对水合氧化物和粘土矿物上交换吸附的影响：（１）在酸性条件下和海水及ＮａＣｌ介质中，砷酸根在针铁矿上的交换率Ｅ（％）—ｐＨ曲线呈平顶峰型、在δ－ＭｎＯ呈峰型、在粘土上分别呈双峰型和肩峰型。这是砷酸根存在多种形式与固体表面发生离子／配位子交换以及介质中阴离子竞争交换吸附共同作用的结果。（２）在碱性条件下的海水介质中，砷酸根与水合氧化物和粘土矿物的Ｅ（％）—ｐＨ曲线都呈Ｖ型，这是因为生成了具有一定结构的液—固界面三元络合物之故。（３）在ＮａＣｌ介质中，Ｃａ加入起促进作用，再次证明液—固界面三元络合物生成机理与Ｖ型曲线的内在关系  相似文献   

Dynamics and Variability of Terra Nova Bay Polynya   总被引：1，自引：0，他引：1  

Giannetta Fusco  Daniela Flocco  Giorgio Budillon  Giancarlo Spezie  Enrico Zambianchi 《Marine Ecology》2002,23(S1):201-209

Abstract. We present a process study on the dynamics and variability of the Terra Nova Bay polynya in the western sector of the Ross Sea. The air-sea heat exchange is known to be particularly large in polynya during the winter, when differences between air and sea temperatures are large. We apply a 1-D model (Pease, 1987; Van Woert, 1999a, 1999b), which is modified in the latent heat parameterisation in order to account for time-dependent relative humidity and cloud coverage. Furthermore, the Ice Collection Depth is correlated linearly with a variable wind speed. The model is forced with two different meteorological data sets: the operational analysis of the European Center for Medium Range Weather Forecasts atmospheric data set and the meteorological parameters measured by an Automatic Weather Station located on the coast of Terra Nova Bay. The results are compared in terms of polynya extension, ice, and High Salinity Shelf Water production. According to the two different wind velocities, the results obtained from the different data sets clearly differ. Qualitatively, however, the results are in good agreement.  相似文献