Oxygen Isotope Exchange Kinetics Between Coexisting Minerals and Water in the Aral Granite Pluton of the Altay Mountains, Northern Xinjiang   总被引：2，自引：0，他引：2  

Liu Wei  Research Center of Mineral Resources Exploration  Chinese Academy of Sciences  Chinese Academy of Sciences  BeijingHe Baichu  Changsha Institute of Geotectonics  Chinese Academy of Sciences  Changsh  Hunanand Chen ZhenshengYichang Institute of Geology  Mineral Resources  Chinese Academy of GeologicalSciences  Yichang  Hubei 《《地质学报》英文版》1996,70(4)

Coexisting quartz, feldspar and biotite vary widely in their δ18O values and display a remarkable 18O/16O disequilibrium relation; especially, a quartz-feldspar reversal (△ 18OQUartz_feldspar< 0) exsists in the Aral granite pluton of the Altay Mountains, northern Xinjiang. The 18O / 16O exchange reaction definitely occurred between granite and water. Initial δ18O values of the granite and exotic fluid are evaluated by the mass balance consideration. The conventional method of discrimination between various magma derivations simply with δ18O values of either whole rock or separate minerals is misleading and unreliable. Experiments carried out by the authors show that the 18O / 16O exchange reaction is not accompanied by what geologists describe as petrological and mineralogical alteration effect. This decoupling relation implies that exchange reaction occurs at a relatively high temperature during subsolidus-postmagmatic cooling of magmas. The exchange mechanism is mainly diffusion-controlled. It is  相似文献   

气相色谱和薄层色谱法在形态分析中的应用   总被引：2，自引：0，他引：2  

方国桢  方梅 《岩矿测试》1996,15(4):299-310

评述了气相色谱和薄层色谱法用于氯、溴、碘、硫、硒、碲、铬、氮、磷、砷、钒、碳、锡、铅、铁和汞１６种元素的不同形态分析的进展。这些形态包括不同价态、有机态、无机态、阳离子和阴离子态等。由于气相色谱和薄层色谱法都具有分离和检测两种功能结合的特点，因此它们是用于元素形态分析的有效和方便的方法。引用１９８０～１９９４年文献９２篇  相似文献   

钛（Ⅳ）的反相萃取柱色层新体系研究及应用     

谭龙华  唐祖光 《矿物岩石》1997,17(3):94-97

本文研究了以ｃＨＣｌ＝８ｍｏｌ·Ｌ－１盐酸为移动相，以聚四氟乙烯负载的钽试剂－ＣＨＣｌ３为固定相反相萃取层析钛（Ⅳ）的新体系，柱上层析的钛用ｃＨＣｌ＝３ｍｏｌ·Ｌ－１盐酸洗脱后经二安替比林甲烷光度法测定，不仅钛回收率可达１００％，并可使钛（Ⅳ）与多种离子分离。能用于矿物岩石类复杂样品及其他物质中钛的分离富集与测定，方法简便快速。  相似文献   

Hypolimnetic density currents traced by sulphur hexafluoride (SF6)     

Jürg W. Schlatter  Alfred Wüest  Dieter M. Imboden 《Aquatic Sciences - Research Across Boundaries》1997,59(3):225-242

The artificial tracer sulphur hexafluoride (SF₆) has been used to study the density-driven deep water exchange between two sill-separated basins of Lake Lucerne, Gersauersee and Urnersee. The sources of the density gradients between the two basins are (1) salinity differences between the major inlets due to the different geology of their drainage areas, and (2) temperature differences due to spatial variation of wind forcing. Wind speeds are generally larger in Urnersee, especially in spring during the so-called Föhn events, when winds blow from the south. In contrast, Gersauersee is protected form these winds. In spring 1989, a total of 630 g of SF₆ was released at 80 to 120 m depth in the small Treib Basin located between Urnersee and Gersauersee. During about 100 days the distribution of SF₆ in the lake was determined by gaschromatography. Two models are used to quantify the exchange flow, (1) a one-box mass balance model for SF₆ in the deep part of Treib Basin, and (2) a one-dimensional diffusion/advection model describing the temporal and vertical temperature variation in Urnersee. According to the first model, the flow into the deep hypolimnion of Urnersee, decreases from 21·10⁶ m³·d^?1 at the end of March to about 8·10⁶ m³·d^?1 in late April. The second model yields similar flow rates. The decrease of the flow rate during spring, confirmed by both approaches, is consistent (1) with the decreasing strength of the density gradient above the sill during spring and early summer, and (2) with hydrographic information collected in Lake Lucerne during other years.  相似文献   

地质速率计—矿物氧扩散的应用     

傅斌  郑永飞 《地球科学进展》1997,12(5):428-433

概述了同位素封闭体系内的矿物氧扩散和同位素交换机制及其在地质速率计上的应用。火成岩从高温冷却或变质岩从高峰主质温度冷却过程中，由于冷却速度不同，扩散作用导致的矿物晶体内部及晶粒间氧同位素再平衡也有所不同。通过实测岩石中各组成矿物氧同位素比值，模式含量和颗粒半径，据矿物氧扩散和同位素交换模型，可以估算出岩石的冷却速率。  相似文献   

Water exchange between Tokyo Bay and the Pacific Ocean during winter     

Tetsuo Yanagi  Hirofumi Hinata 《Ocean Dynamics》2004,54(3-4):452-459

Variability in water-exchange time between Tokyo Bay and the Pacific Ocean during winter is investigated based on the results of intensive field observation from November 2000 to March 2001. Water-exchange time between Tokyo Bay and the Pacific Ocean during winter mainly depends on the strength of northerly monsoon, being about 16 days under the weak monsoon and about 12 days under the strong monsoon. Moreover, it becomes longer by about 1 day in spring tide and shorter in neap tide due to the coupling effect of estuarine circulation and vertical mixing. Water-exchange time also varies depending on the open-ocean condition. When the warm water mass approaches from the Pacific Ocean to the mouth of Tokyo Bay through the eastern channel of Sagami Bay, which connects Tokyo Bay and the Pacific Ocean, water-exchange time becomes longer by about 2 days because the warm water mass is blocked in the surface layer at the bay mouth. On the other hand, when the warm water mass approaches to the mouth of Tokyo Bay through the western channel of Sagami Bay, water-exchange time becomes shorter by about 1 day because the warm water mass intrudes into the middle or lower layers of Tokyo Bay. Such different behavior of warm water mass at the mouth of Tokyo Bay is due to the difference in density of approaching warm water masses, that is, the density of the warm water mass through the eastern channel is smaller than that of the warm water mass through the western channel of Sagami Bay.Responsible Editors: Yens Kappenberg  相似文献   

顶空气相色谱法测定地层水中的苯系物   总被引：10，自引：2，他引：10  

饶竹 李松佟柏龄  吴淑琪李迎春 《岩矿测试》2004,23(2):97-101

利用极性聚乙二醇弹性石英毛细管柱分离苯系物，在线顶空气相色谱法测定地层水中的苯系物。讨论了色谱柱、载气压力、液相体积、顶空压力、顶空加热温度等因素对测定的影响。该方法实现了地层水中苯、甲苯、乙苯、对二甲苯、间二甲苯、邻二甲苯、异丙苯、苯乙烯等各组分的完全分离，方法的检出限在0．07—0．23μg／L，8次测定相对标准偏差在2．98％-4．91％，加标回收率为95．2％-104％。方法可用于地层水等液体样品中苯系物的测定。  相似文献   

夏季红枫湖地区农田土壤-大气界面汞交换通量的初步研究   总被引：11，自引：2，他引：11  

王少锋  冯新斌  仇广乐  付学吾 《矿物岩石地球化学通报》2004,23(1):19-23

采用动力学通量箱法(Dynamic Flux Chamber)与高时间分辨率大气测汞仪联用技术对贵州红枫湖地区土壤-大气界面间汞交换通量进行了初步研究.结果显示,红枫湖地区土壤-大气界面间汞交换通量变化范围为-8.6 ng～215.3 ng@m-2@h-1,平均27.4士40.1 ng/m2@h(n=255);且土壤与大气界面间的汞交换是双向的既有土壤汞的释放,又有大气汞的沉降,主要以土壤汞的释放为主(n释放=253,n沉降=2n).土壤汞的释放通量与土壤温度、气温、光照强度有强相关关系,相关系数分别为0.80、0.83、0.74.  相似文献   

Thermal decomposition of NH4-analcime     

A.Yu. Likhacheva  S. A. Veniaminov  E. A. Paukshtis 《Physics and Chemistry of Minerals》2004,31(5):306-312

The thermal decomposition of ammonium-exchanged natural analcime is characterized by gas chromatography, IR spectroscopy and X-ray diffraction. The de-ammoniation and dehydroxylation proceed in parallel throughout the decomposition, which evidences the instability of the protonated analcime framework. The mechanism of degassing of NH₄-analcime changes throughout its decomposition. At the initial step, the mechanism of de-ammoniation consists in thermal dissociation of NH₄⁺ molecule onto NH₃ and proton (framework OH group) and diffusion of NH₃ out of the structure. Subsequent decomposition and removal of the OH groups lead to a progressive loss of crystallinity. At this step, an apparent activation energy for NH₃ desorption is estimated to be 145(±13) kJ mol^–1. This value is within the upper limit of the activation energy characteristic for the NH₃ desorption from proton centres in large-pore zeolites. At the final step, the adsorption of NH₃ and protons onto the defect centres in the amorphosed aluminosilicate framework results in a significant increase of an apparent activation energy for the de-ammoniation and dehydroxylation up to 270(±20) kJ mol^–1.  相似文献   

Variation of stream temperature among mesoscale habitats within stream reaches: southern Appalachians          下载免费PDF全文

S. Lynsey Long  C. Rhett Jackson 《水文研究》2014,28(7):3041-3052

Stream mesoscale habitats have systematic topographic relationships to hyporheic flow patterns, which may create predictable temperature variation between mesoscale habitat types. We investigated whether systematic differences in temperature metrics occurred between mesoscale habitats within reaches of small streams tributary to the upper Little Tennessee River, southern Appalachians. Surface water temperature was recorded over three or four mid‐summer days in four mesoscale habitat types: riffle, main riffle, pool and alcove in 44 stream segments (sites). Temperature metrics were calculated for each mesoscale habitat relative to the mean value of the metric over the stream: Δ maximum temperature, Δ average maximum temperature and Δ maximum daily variation and also for each site: standard deviation of the maximum temperature and average diurnal variation (ADV). Sites were categorized as fully or partially forested. Pool tailouts had statistically significantly lower Δ maximum temperature and Δ average maximum temperature than riffle tailouts in partially forested sites, although differences were small. This was the opposite of what was expected in the presence of hyporheic exchange, indicating hyporheic exchange is not a dominant driver of mesoscale habitat temperatures at these sites. Temperature differences between mesoscale habitat units were small and unlikely to have ecological significance. We also evaluated relationships between stream temperature and riparian condition, watershed % impervious surfaces, watershed % non‐forested and elevation. ADV and standard deviation of the maximum temperature were significantly higher in partially forested sites, indicating that partially forested sites have greater temperature ranges and spatial variation of maximum temperatures. ADV decreased with elevation and increased with % impervious surfaces. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献