The influence of diet on comparative trace metal cadmium,copper and zinc accumulation in Thais clavigera (Gastropoda: Muricidae) preying on intertidal barnacles or mussels     

Blackmore G  Morton B 《Marine pollution bulletin》2002,44(9):870-876

The influence of diet on comparative metal accumulation was investigated using a predatory muricid gastropod Thais clavigera. Individuals were fed for up to 56 days on either barnacles, i.e., Tetraclita squamosa, or mussels, i.e., Perna viridis, collected from metal-contaminated and clean sites. Barnacles and mussels have contrasting metal handling strategies and, therefore, different body concentrations, intracellular distributions and detoxification systems. Field collection of prey items that accumulated body metal concentrations over a lifetime of exposure allowed bioavailability to the predator, T. clavigera, to be assessed naturally, which may not be the case for prey exposed to metals for a short time in the laboratory. T. clavigera that was fed cadmium- and copper-contaminated barnacles or mussels ingested significantly greater amounts compared to those fed conspecifics collected from clean locations. T. clavigera body cadmium and copper concentrations were not, however, significantly different between individuals fed either contaminated or clean prey. Amount of zinc ingested was similar in mussels collected from clean and contaminated environments but much less when compared to the barnacle prey. The body concentrations of zinc in T. clavigera fed mussels collected from both sites fell. In contrast, the amount of zinc ingested from barnacle prey was significantly greater from those collected from the metal-contaminated site as compared to the clean one. This was reflected as significantly greater body zinc concentrations in T. clavigera fed contaminated barnacles compared to those fed clean individuals. Copper and zinc accumulation from prey was, therefore, complex. It varied between metal and between prey type, but appeared to be related to the amount ingested and the metal handling strategy of the prey.  相似文献   

The Influence of Oxalate on Fe-Catalyzed S(IV) Oxidation by Oxygen in Aqueous Solution     

A. Wolf  F. Deutsch  P. Hoffmann  H. M. Ortner 《Journal of Atmospheric Chemistry》2000,37(2):125-135

This study demonstrates that oxalate has a strong inhibiting effect onFe-catalyzed S(IV) oxidation by oxygen in aqueous solution. While thepseudo-first order rate constant of S(IV) oxidation was determined to be1.6 × 10³ M^-1 s^-1 in experimentswithout oxalate, the oxidation of S(IV) was totally inhibited at a molarconcentration ratio of iron:oxalate = 1:5 at an oxalate concentration of 4M. Under these conditions, the Fe(II)/Fe(III) ratio remained nearlyconstant during the observed reaction time. The determined rate constants wereindependent of the initial oxidation state of iron. However, with increasingconcentrations of oxalate, a longer induction period is observed forexperiments with iron initially in the Fe(II) oxidation state.  相似文献   

同仁双朋西金矿浮选尾矿中提铜扩大试验的研究          下载免费PDF全文

龙光明  康永峰 《盐湖研究》2000,8(2):22-28

在小试的工艺基础上 ,对双朋西金矿浮选后的尾矿进行铜、金回收扩大试验。对铜的浸取试验结果表明 ,本工艺对该尾矿具有较高的铜浸取率和回收率  相似文献   

铜矿资源进口区域评价与决策优化研究     

陈甲斌  余良晖 《江苏地质》2006,30(1):70-73

我国铜矿资源的供给能力有限,而其消费需求又在持续扩张,为此导致进口量在逐年递增。根据近几年的统计,我国进口国外铜矿资源产品具有相对稳定的区域分布。对这些区域的进口环境做了初步的评价,筛选出了最为理想的进口靶区。为了以最少的外汇支出换取到我国所需要进口的铜矿资源,并为贸易决策提供支持依据,作者就其进口决策优化方面做了一些分析。  相似文献   

Environmental Assessments of Trace Metals in Sediments from Dongting Lake, Central China   总被引：1，自引：0，他引：1  

姚志刚  鲍征宇高璞 《中国地质大学学报(英文版)》2006,17(4):50-319

INTRODUCTIONFresh water lakes are one of the planet’s mosti mportant freshwater resources.They support life invarious forms,develop tourism and provide uniquerecreational opportunities.It is also a good source ofthe provision of drinking-water for local communi-ties.Studies on trace elements in rivers,lakes,andsedi ments(Zhou et al.,2004;Gray et al.,2000;Grosheva et al.,2000;Klavins et al.,2000;Aucoinet al.,1999;Bortoli et al.,1998;Elbaz-Poulichet etal.,1996;Johansson et al.,1995;F r…  相似文献   

Trace Metal Solid State Speciation in Aerosols of the Northern Levantine Basin,East Mediterranean   总被引：3，自引：0，他引：3  

Mustafa Koçak  Nilgun Kubilay  Barak Herut  Malcolm Nimmo 《Journal of Atmospheric Chemistry》2007,56(3):239-257

An established three stage sequential leach scheme was applied to a series of selected high volume aerosol samples (n = 35) collected from the Turkish Eastern Mediterranean coastline (Erdemli). Samples were selected according to their air mass back trajectory history to reflect the contrasting mixtures of aerosol material present in the Eastern Mediterranean marine aerosol. Two populations were adopted, those samples which were classed as “anthropogenic” and those which were “Saharan” dominated aerosol populations. Applying the three stage leach it was possible to define the proportion for each of the considered metals (Al, Fe, Cu, Pb, Cd, Zn and Mn) present in the (a) “exchangeable” (b) “carbonate / oxide” and (c) “refractory” phases, representing novel solid state aerosol speciation data for this marine system. Clear trends were established, conforming with data from previous studies with mainly crustal derived metals (Al and Fe) being present in the refractory phases (Al > 88%; Fe > 84%) and those influenced by anthropogenic sources being dominating in the exchangeable phase, although for these metals the variability was comparatively high (12–64%; 19–85%; 40–100% for Zn, Pb and Cd, respectively). For the majority, greater exchangeable fractions were present the lower the crustal source contribution to the aerosol population, whereas the “refractory” fraction exhibited contrasting behaviour. This was illustrated by the novel application of the mixing diagram, presenting each of the three speciation stages against the corresponding percent anthropogenic contribution to each collected sample. Zn, Pb and Cd all illustrated progressive decrease in the percent exchangeable with increasing crustal contribution to the aerosol population. The percent exchangeable was discussed in terms of its use to represent the upper limit of the bioavailable fraction of metal associated with the aerosol, post deposition. The mixing diagram approach enabled the prediction of the residual fractions for Cd, Pb and Zn (41 ± 4%; 62 ± 4% and 82 ± 5%, respectively,) in Saharan end-member material.  相似文献   

Speciation and potential remobilization of heavy metals in sediments of the Taihu Lake, China     

YUAN Xuyin DENG Xu SHEN Zhiyong GAO Yun 《中国地球化学学报》2007,26(4):384-393

The species of Cu, Pb, Zn, Cd and Cr in sediments of the Taihu Lake, China, have been analyzed using the sequential chemical extraction method. Variations in the chemical fractions of these metals and their geographic distributions have also been studied. For all five metals, the residual fraction is highest but the exchangeable fraction is lowest among all the fractions. Compared to other metals, Cd has the highest percentage in the exchangeable fraction, and Cr is associated mainly with the residual fraction. Cu in the organic fraction and Pb in the Fe-Mn fraction are the important species, whereas the lowest percentages are found for Cd in the organic fraction, Cu in the Fe-Mn oxide fraction and Pb in the carbonate fraction. With respect to spatial differences, the total contents in the non-residual fractions of the metals in bay sediments are found to be higher than those in other sediments. The fractions of Cd, Cu and Cr showed significant variations in different regions. The fractions of Pb and Zn, however, did not show significant variations in spatial distribution, suggesting different amounts and different paths of anthropogenic input for the metals. Comparisons of the metal speciation indicated that Cd might be the most bioavailable metal, followed by Pb.  相似文献   

高硒环境样品中硒的形态分析方法   总被引：2，自引：0，他引：2  

朱建明  秦海波  李璐  魏中青  雷磊  苏宏灿 《矿物岩石地球化学通报》2007,26(3):209-213

在恩施富硒碳质岩和土壤样品中硒矿物学研究的基础上,提出了硒连续化学提取的改进方案。化学操作上定义为7个连续步骤:水溶态(MQ水提取)、可交换态(0.1 mol/L的K2HPO4 KH2PO4,pH=7.0)、有机结合态(0.1 mol/L NaOH)、元素态(1 mol/L Na2SO3溶液)、酸溶性提取态(15%CH3CO2H溶液)、硫化物/硒化物态(1 mol/L CrCl2 HCl溶液)和残渣态硒(HNO3 HF H2O2混合消化液)。使用HG-AFS法检测了各结合态中的硒形态和总硒,上述流程提取硒加和与总硒间显著一致,平均回收率为99.2%,符合平行样品间变异系数低于10%的精度要求。该方法简单易行,能够准确地揭示富硒地质样品中硒的形态信息。  相似文献   

喇嘛苏铜矿床斑岩体地质地球化学特征及含矿性评价   总被引：5，自引：0，他引：5  

蔡宏渊  郑跃鹏 《矿产与地质》1998,12(6):386-392

矿区内广泛发育以斜长花岗斑岩和花岗闪长斑岩为主的中酸性斑岩体。斑岩的结构特征反映出岩浆浅成侵位成因。研究表明该区斑岩具有相对富硅和富碱高钾的岩石化学特征,属钙碱性系列;具有Ｃｕ、Ａｇ、Ｂｉ等成矿元素高丰度的微量元素地球化学特征和低ΣＲＥＥ与高δＥｕ值的稀土地球化学特征。矿区内铜矿化富集在斑岩体内外接触带,斑岩体深源浅成特点和富碱高钾岩石化学特征于铜矿化富集有利。Ｃｕ、Ａｇ等成矿元素高丰度及其与矿化类型一致性说明成矿与岩浆活动有密切成因关系。  相似文献   

表外矿石利用途径   总被引：1，自引：0，他引：1  

刘维阁 《矿产与地质》1998,12(5):349-352

近年来江西德兴、永平、武山铜矿开展了表外矿石回收利用的研究工作,总结了三种利用表外矿石的途径,（１）调整采矿指标,充分利用表外矿石的范围,（２）合理搭配矿石,综合回收表外矿石的有用组份,（３）结合市场动态,经济合理地改进开采计划和采用有效的采矿方法等实践证明其方法是可行的,既可充分合理利用资源,又可提高经济效益  相似文献