Geochemistry and charge history of oils from the Yuqi area of Tarim Basin,NW China     

《Marine and Petroleum Geology》2017

The geochemistry, origin and charge history of oils from the Yuqi area of Tarim Basin have been investigated, through GC, GC-MS and fluid inclusion microthermometry analysis. The Yuqi oils accumulated mainly in three intervals: (1) in the Lower-Middle Ordovician Yingshan Formation (O_1-2y) carbonate reservoirs; (2) in the overlying Upper Triassic Halahatang Formation (T₃h); and (3) in the Lower Cretaceous Yageliemu Formation (K₁y) sandstones. Oils from different reservoirs have distinct physical properties, varying from extra-heavy (O_1-2y), heavy (T₃h), to light oils (T₃h and K₁y). However, their geochemical compositions show a high degree of similarity, which indicates that they derive from the same source rock. Abundant tricyclic terpanes, gammacerane, dibenzothiophene and C₂₁C₂₂steranes, together with a low level of diasteranes, indicate an anoxic marine source rock for oils in the Yuqi area. Oil-oil correlation shows that Yuqi oils derive from the same source bed as Tahe oils. The co-occurrence of intact n-alkanes and 25-norhopanes in all the samples supports the proposition that there is a mixture of an early filled severely biodegraded oil and a late filled fresh oil.In this study, charge history is examined on the basis of integration of fluid inclusion homogenization temperature data with 1D burial-thermal history models. Two episodes of oil charging are identified in the O_1-2y reservoir (well YQX1-1) at around 436-420 Ma (Middle-Late Silurian) and 10-3 Ma (Miocene to Pliocene), respectively. For the samples from the T₃h and K₁y intervals, only one episode of oil charge is indicated by the homogenization temperatures of coexisting aqueous inclusions with an inferred timing around 10-3 Ma. The T₃h heavy oil reservoir is assumed to be a secondary hydrocarbon pool, which accumulated by re-migration and re-distribution of hydrocarbons from O_1-2y hydrocarbon pools. The few early biodegraded oils in the K₁y light oils were probably picked up along the migration pathway during the late fresh oil charging.  相似文献   

Identification of petroleum hydrocarbons using a reduced number of PAHs selected by Procrustes rotation   总被引：2，自引：0，他引：2  

R. Fernández-Varela  S. Muniategui  F. Ramírez-Villalobos 《Marine pollution bulletin》2010,60(4):526-535

Identifying petroleum-related products released into the environment is a complex and difficult task. To achieve this, polycyclic aromatic hydrocarbons (PAHs) are of outstanding importance nowadays. Despite traditional quantitative fingerprinting uses straightforward univariate statistical analyses to differentiate among oils and to assess their sources, a multivariate strategy based on Procrustes rotation (PR) was applied in this paper. The aim of PR is to select a reduced subset of PAHs still capable of performing a satisfactory identification of petroleum-related hydrocarbons. PR selected two subsets of three (C₂-naphthalene, C₂-dibenzothiophene and C₂-phenanthrene) and five (C₁-decahidronaphthalene, naphthalene, C₂-phenanthrene, C₃-phenanthrene and C₂-fluoranthene) PAHs for each of the two datasets studied here. The classification abilities of each subset of PAHs were tested using principal components analysis, hierarchical cluster analysis and Kohonen neural networks and it was demonstrated that they unraveled the same patterns as the overall set of PAHs.  相似文献   

Soil Washing for Reduction of Aromatic and Aliphatic Contaminants in Soil          下载免费PDF全文

Saeid Gitipour  Mahsa Hedayati  Edris Madadian 《洁净——土壤、空气、水》2015,43(10):1419-1425

  相似文献   

漠河-加格达奇段多年冻土区中俄原油管道运营以来的次生地质灾害研究——以MDX364处的季节性冻胀丘为例   总被引：4，自引：3，他引：1  

王永平  金会军  李国玉  童长江 《冰川冻土》2015,37(3):731-739

通过对中俄原油管道漠河-加格达奇段多年冻土区的现场勘查研究, 统计了管道运营以来出现的冻土次生地质灾害主要有冻胀、融沉、水毁、冻胀丘、冰椎等. 在研究区域特定的气候背景下, 管道的修建和季节性变化的正油温运营, 破坏了管道周围冻土的水热平衡, 使得管道周围土体出现差异性冻胀和融沉, 这种差异性位移量的累积对管道安全稳定长期运营造成了威胁. 以管道里程MDX364处的冻胀丘为例, 利用探地雷达进行了现场探测. 结果表明: 管道周围存在的融区为冻胀丘的发生和发展提供了水源补给通道, 管道的热影响加速了冻胀丘的发展和消融, 2014年3-10月管道周围地表产生的差异性位移超过了1.1 m. 针对该次生开放型季节冻胀丘, 提出了修筑或疏通管道附近的排水通道、钻孔放水和保温排水渗沟等防治措施. 研究成果能为中俄原油管道的安全稳定运营提供技术支撑, 为其他冻土区管道设计施工和运营维护提供参考和依据.  相似文献   

Cold-region environments along the China-Russia Crude Oil Pipeline and their management     

RuiXia He  HuiJun Jin  LanZhi L  ShaoLing Wang 《寒旱区科学》2010,2(2):129-136

The cold-region eco-environments along the China-Russia Crude Oil Pipeline (CRCOP) in northern Northeast China are in disequilibrium due to the combined influences of pronounced climate warming and intensive anthropogenic activities.This is evidenced by the sharp areal reduction and northward shifting of the boreal forests,shrinking of wetlands,enhancing of soil erosion,accelerating degradation of permafrost and deteriorating of cold-region eco-environments.The degradation of permafrost plays an important role as an internal drive in the eco-environmental changes.Many components of the cold-region eco-environments,including frozen ground,forests,wetlands and peatlands,forest fires and "heating island effect" of rapid urbanization,are interdependent,interactive,and integrated in the boreal ecosystems.The construction and long-term operation of the CRCOP system will inevitably disturb the cold-region environments along the pipeline.Therefore,a mandatory and carefully-elaborated environ-mental impact statement is indispensable for the proper mitigation of the ensued adverse impacts.Proper management,effective protection and practical rehabilitation of the damaged cold-region environments are a daunting,costly and long-term commitment.The recommended measures for protection and restoration of permafrost eco-environments along the pipeline route include adequate investigation,assessment and monitoring of permafrost and cold-region environments,compliance of pipeline construction and operation codes for environmental management,proper and timely re-vegetation,returning the cultivated lands to forests and grasslands,and effective mitigation of forest fire hazards.  相似文献   

The Sea Empress oil spill (Wales, UK): effects on Common Scoter Melanitta nigra in Carmarthen Bay and status ten years later     

Banks AN  Sanderson WG  Hughes B  Cranswick PA  Smith LE  Whitehead S  Musgrove AJ  Haycock B  Fairney NP 《Marine pollution bulletin》2008,56(5):895-902

Carmarthen Bay, UK, regularly supports internationally important numbers (>16,000) of non-breeding Common Scoters Melanitta nigra. The spill of 72,000 tonnes of crude oil from the Sea Empress in 1996 affected birds both through direct mortality and likely pollution of key food resources. Numbers were greatly reduced following the spill, whilst changes in the distribution of birds within Carmarthen Bay suggested that potentially sub-optimal foraging zones were used. However, ten years after the incident, numbers of Common Scoter were no different to those recorded immediately before the spill. Compared to some other spills, rapid revival is evident. Numbers increased to pre-spill levels within three winters and distributional changes suggested a concurrent return to previously contaminated feeding areas, implying that the ecosystem had regenerated sufficiently to support its top predator. The importance of prolonged, standardised monitoring of bird numbers and distribution as indicators of ecological recovery from environmental damage is emphasised.  相似文献   

东营凹陷南斜坡孔店组原油地球化学特征及其来源     

王建伟  宋国奇  宋书君  赵密福  高侠 《吉林大学学报(地球科学版)》2008,38(1):56-62

在分析东营凹陷缓坡带孔店组多个原油样品的类异戊二烯烷烃、甾类化合物、萜类化合物和碳同位素构成的基础上,揭示了孔店组原油的典型地球化学特征。孔店组原油甾类化合物主要由规则甾烷构成,异构化程度较低,明显富有C₂₉规则甾烷;三环萜烷相对含量高,三环萜烷/五环萜烷分布范围为0.15～0.53;碳同位素组成偏轻,δ¹³Ｃ值普遍小于－29‰。由于孔店组原油与研究区已认定的Es^x₃亚段、Es^s₄亚段和Ek₂亚段三套生油岩都缺少成因联系,该区可能存在一套尚未落实的生油岩。依据原油的典型生物标志化合物构成特征推断,孔店组原油应来自下第三系深层一套贫粘土矿物且富含化学盐岩的生油岩层。  相似文献   

SHORT COMMUNICATION VARIATIONS IN ESSENTIAL OILS OF MANDARINE RELATED TO PROCESSING AND RIPENING     

ANTONELLACOTRONEO  GIOVANNIDUGO  LUCIANO FAVRETTO  LUCIANA GABRIELLI FAVRETTO 《地理学报(英文版)》1990,11(5)

Mandarine essential oils are extracted from green unripened fruits as well as from red fruits at ripening,both oils having specific uses as natural additives in the food industry.Two processes of production,pressing and peeling,are currently adopted in their production.Capillary gas chromatography with flameionization detection has been suggested as a sensitive method for the fractionation of volatile componentsof the essential oils.Principal component analysis was proposed as an exploratory chemometric methodfor the differentiation of essential oils from fruits at different degrees of ripening,taking into accountthe processes of production.Product-moment correlations between variables(concentrations of 17components)were used as starting matrices and the explained variance was adopted as a criterion foreigenvalue selection.Bi-plots and three-dimensional plots of unrotated principal component scores weresystematically used as well as those of orthogonally rotated factor scores.The 17 variables were reducedto four principal components,which explained 87% of the total variance.Projection on the first threeeigenvectors of all data as unrotated component scores allowed for a tentative differentiation of 59 oilsaccording to their degree of ripening.The two processes of production were also differentiated in asample of 55 oils.  相似文献   

吐哈盆地中下侏罗统源岩和油的生物标志物分布特征——饱和烃馏分   总被引：2，自引：2，他引：0  

房嬛  孟仟祥  孙敏卓  王作栋  李玉梅  徐茵 《沉积学报》2008,26(5):891-895

通过对吐哈盆地煤系地层中下侏罗统煤岩、炭质泥岩、原油饱和烃组分的有机组分分析,获得以下认识:具有共同的特征生物标志化合物:γ 羽扇烷、异降松香烷、C24 四环二萜烷、高丰度C29甾烷,表明它们具有相同的高等植物母质来源。较高Pr/Ph比值、以及γ 蜡烷相对丰度很低等指示环境的参数具有一致性,说明它们的早期沉积环境相同,都是水质偏淡的弱氧化—弱还原环境。甾烷异构化参数C29 ββ／（ββ＋αα）在研究的低演化煤岩及炭质泥岩(Ro:0.47~0.53)中显示明显的高比值（0.294~0.489）,显示岩样在成岩过程中曾遭受过比较强烈的微生物作用,因此,煤岩早期的微生物作用可能是煤系地层早期生烃的动因。  相似文献   

普光气田及邻区碳酸盐储层沥青的分子地球化学研究     

金晓东  潘长春  于双  秦建中 《地球化学》2012,(4):293-302

从普光气田及邻近地区二叠系和下三叠统15个含沥青碳酸盐储集岩样品分步提取了自由态油气组分和油气包裹体组分,并且应用限定体系(金管)热解实验获取了固体沥青热解组分.各组分进一步做色谱和色谱-质谱分析获取了生物标志物组成.分析结果表明,从油气包裹体组分、自由态油气组分至固体沥青热解组分,伽马蜡烷/C31升藿烷比值依次增高.同时油气包裹体组分 C23三环萜烷/(C23三环萜烷+C30藿烷)、C21/(C21+ΣC29)甾烷、C27重排甾烷/(C27重排甾烷+C27规则甾烷)、20S/(20R+20S) C29甾烷和αββ/(ααα+αββ) C29甾烷等成熟度指标与自由态组分相近,而明显高于固体沥青热解组分.根据分子指标,可以推断古油藏的原油来源于不同的烃源岩,早期充注的原油来源于下志留统烃源岩,具有较低的伽马蜡烷含量和较高的成熟度;晚期充注的原油来源于上二叠统烃源岩,具有较高的伽马蜡烷含量和较低的成熟度.固体沥青主要为晚期充注、来源于上二叠统烃源岩的原油裂解生气的产物  相似文献