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131.
Bed sediment-associated trace metals in an urban stream, Oahu, Hawaii   总被引:78,自引:0,他引:78  
 Of the 117 stream and lake systems sampled nationwide, fish from Manoa Stream on Oahu, Hawaii, have consistently shown the highest Pb concentrations. Therefore a detailed study was conducted to examine total metal contents in bed sediments from a 5.8-km stretch of Manoa Stream. A total of 123 samples (<63 μm) were examined for 18 elements and 14 samples for 21 elements. Selected samples were also examined using different leach solutions to examine metal phase associations. All trace metal data, computations of enrichment ratios and the modified index of geoaccumulation point to mineralogical control for Cr and Ni; minor anthropogenic contamination for Ba, Cd, Cu, Hg and Zn; and a very strong contamination signal for Pb. Maximum Pb contents (up to 1080 mg kg−1) were associated with anthropogenic material dumping in minor tributaries, storm sewer sediments and sediments in the “lower” section of the basin. Proportionally Pb had the highest non-residual component of elements examined; dominantly in the reducible phase associated with Mn and amorphous Fe oxyhydroxides. The contamination signal was typically lowest in the “undisturbed” headwater reach of the basin (above 5.1 km) with significant increases throughout the “residential” and “commercial-institutional” zones of the mid-basin. The spatial pattern of bed sediment contamination and evidence from storm sewer-outlet sediments strongly indicates that Pb, and to a lesser degree some other metals, is still being transported to the stream and the primary agent is soil erosion and transport of metals sorbed to sediments. The primary source of sediment-associated metals is considered to be the automobile, though other minor sources can not be ruled out. Received: 3 November 1998 · Accepted: 26 January 1999  相似文献   
132.
Land degradation due to soil erosion is a global problem, especially on cultivated hill slopes. Economically important aromatic grasses can protect degraded hill slopes more effectively than field crops, but little information is available on their performance. This study quantifies runoff, sediment yield,enrichment ratios of soil and nutrients, and sediment-associated organic carbon and nutrients losses under three aromatic grass species: citronella(Cymbopogon nardus), lemon(Cymbopogon flexuosus), and palmarosa(Cymbopogon martini), compared with a traditional field crop, finger millet(Eleusine coracana)grown at three land slopes(4%, 8%, and 12%). It was observed that the degree of slope and type of grass both significantly influenced runoff generation. Runoff and sediment yield(SY) were significantly higher at 12% slope than at 8% and 4% slopes. Relation between rainfall and runoff were significant for all the grass species(p 0.05). Palmarosa, lemon, and citronella grass reduced the SY by 10, 54, and 60%,respectively, over finger millet. SY was also significantly related to rainfall for all the treatments(p 0.05). The threshold runoff values to produce SY were higher for aromatic grasses compared to finger millet. Enrichment of clay, silt, sand, soil organic carbon(SOC), available nitrogen(N), phosphorus(P) and potassium(K) in the sediment were not significantly different between slopes but differed significantly between aromatic grasses and finger millet. Sediment associated nutrient load varied inversely with SY mainly because of the nutrient dissolution effect of high runoff volume. Annual loss of SOC and nutrients varied from 84.7-156.8 kg ha~(-1) y~(-1) for SOC, 4.38-9.18 kg ha~(-1) y~(-1) for available N, 0.35-0.75 kg ha~(-1) y~(-1) for available P, and 2.22-5.22 kg ha~(-1) y~(-1) for available K, with the lowest values for citronella and highest for finger millet. The study found that the aromatic grasses have greater environmental conservation values than finger millet on steep degraded land.  相似文献   
133.
Sediment from twelve stations was sampled from the Tupilipalem Coast, southeast coast of India, and the presence of a set of heavy metals was established including iron (Fe), manganese (Mn), chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), zinc (Zn) and cadmium (Cd). The heavy metals were assessed by factor analysis, the results of which showed positive and/or negative correlations among Fe, Mn, Cr, Cu, Ni, Pb, Zn, and Cd. Factor analysis also indicated that heavy metals in the sediments of the study area have different natural and anthropogenic sources. Similarly, a sediment pollution assessment was done using the Geoaccumulation Index (Igeo), Enrichment Factor (EF), and Pollution Load Index (PLI). The Geoaccumulation Index indicated that the surface sediment of the Tupilipalem Coast was extremely contaminated with Fe, Mn, Cr, Cu, Ni, Pb, and Zn. The calculation of enrichment factors showed a significant enrichment with respect to Pb, Zn, and Cd and a moderate enrichment with Cr, Cu, and Ni. The falling trend of average contents’ enrichment factors is Cd> Pb> Zn> Cu> Cr> Ni> Mn> Fe. The PLI values of the Cd show higher (>1) values due to the influence of distinct external sources like agricultural runoff, industrial activities, and other anthropogenic inputs. Ninety two percent of heavy metals under study showed the highest concentrations at station TP-5 where the Buckingham Canal and other agricultural and aquacultural effluents connect with the Bay of Bengal. This location is the second inlet which is periodically closed and it seemed that these parts of the study area are heavily affected by anthropogenic pollution.  相似文献   
134.
This study aimed to evaluate the spatial and temporal distribution of heavy metals (Cd, Cr, Cu, Co, Fe, Pb, Ni, V, and Zn) in the sediments of Bayan Lepas Free Industrial Zone of Penang, Malaysia. Ten sampling stations were selected and sediment samples were collected during low tide (2012 ? 2013). Metals were analyzed and the spatial distribution of metals were evaluated based on GIS mapping. According to interim sediment quality guidelines (ISQG), metal contents ranged from below low level to above high level at different stations. Based on the geoaccumulation index (Igeo) of sediment, sampling stations were categorized from unpolluted to strongly polluted. The enrichment factor (EF) of metals in the sediment varied between no enrichment to extremely high enrichment. The potential ecological risk index (RI) indicated Bayan Lepas FIZ was at low risk.  相似文献   
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