The relationship of precipitation seasonality to the flora and stable isotope chemistry of soils in the Vizcaíno desert, Baja California, México     

Ronald Amundson  Ernesto Franco-Vizcaíno  R.C. Graham  Michael DeNiro 《Journal of Arid Environments》1994,28(4)

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Multifacetted study of a cretaceous coal with algal affinities—II. Composition of liquefaction products     

Z. Mudamburi  P.H. Given 《Organic Geochemistry》1985,8(3):221-231

Two hydrogen-rich lithobodies of highly alipathic character from a coal occurring in southwest Utah, have been studied. Bituminite (>50%), vitrinite (25–30%) and liptodetrinite (7–12%) are the principal macerals. The hexane-soluble products of hydrogenating the lithotypes at 400° with tetralin and hydrogen have been analyzed by GC-MS. Products identified include homologous series of alkylated naphthalenes, phenols, furans, cyclohexenones and hydroxy-pyridines. In the case of furans, the alkyl groups extend beyond C₃₀. Materials released by Soxhlet extraction with pyridine consist chiefly of homologous series of fatty acids and their methyl esters and of methyl alkyl ketones, which were not found in the hydrogenation products. The long alkyl chains in these substances can account for about 75% of the alkanes found in the hydrogenation products but not in the extracts. Most of the compounds mentioned in the foregoing are thought to be physically held or trapped in the coal, rather than chemically combined in its macromolecular network. Except for the fatty acids, the origins of these substances are difficult to identify.  相似文献   

Pyrolysis of immature Torbanite and of the resistant biopolymer (PRB A) isolated from extant alga Botryococcus braunii. Mechanism of formation and structure of torbanite     

C. Largeau  S. Derenne  E. Casadevall  A. Kadouri  N. Sellier 《Organic Geochemistry》1986,10(4-6)

Immature Torbanite and the resistant biopolymer (PRB A) isolated from extant B. braunii were previously compared using bulk spectroscopic methods. In the present work, analysis of 400°C pyrolysis products and pyrolysis residues provided further information on their structure and possible relationships. It appears that such polymers are based upon unbranched, saturated, cross-linked hydrocarbon chains up to C₃₁. In addition to these bridging structures, a substantial part of the alkyl chains is singly bound, as esters of unbranched, saturated or cis unsaturated, even fatty acids. These esters are sterically protected, against chemical degradations, by the network of the bioand geopolymer.Quantitative and qualitative observations derived from 400°C pyrolysis confirm that the chemical structure of PRB A and immature Torbanite are closely related. The pyrolysis residues show a similar evolution and numerous common features are noted, with respect to the nature and the distribution of the major constituents of the pyrolysates (hydrocarbons and fatty acids). Accordingly, Botryococcus provides what seems to be the first example of a close structural relationship between a biopolymer produced in large amounts by an extant alga and the geopolymer of an immature kerogen. The essential role of PRB A in Torbanite formation is ascertained. Moreover, it is found that the resistant biopolymer does not undergo important structural changes during the first stages of diagenesis. Thus, owing to steric protection, the esters of immature Torbanite show a distribution quite close to the one of PRB A esters, with exclusively even constituents and a large contribution of unsaturated acids.Recent observations pointed to the possible genesis of some algal kerogens principally by selective preservation of resistant macromolecules. Such a type of formation is clearly predominant in Torbanite, where the bulk of the fossil organic matter corresponds to a selectively preserved and weakly altered, resistant biopolymer, while incorporation of lipids into the kerogen structure during diagenesis seems to play a minor role.  相似文献   

中国西北C-3植物的碳同位素组成与年降雨量关系初探   总被引：2，自引：0，他引：2  

王国安  韩家懋 《地质科学》2001,(4):494

 本文对不同年降雨量环境下生长的藜、独行菜、魁蓟和平车前这4种常见C-3植物的δ¹³C进行了分析,发现这4种C-3植物的δ¹³C组成都表现出随年降雨量减少而变重的趋势,其中藜和独行菜的碳同位素组成对降水变化的响应相对要较其它2种植物强烈得多。藜、独行菜和魁蓟的δ¹³C组成与年降雨量有显著的线性关系,平车前碳同位素组成与年降雨量没有显著的相关性,表明藜、独行菜和魁蓟的δ¹³C组成可作为年降雨量的替代性指标,平车前的δ¹³C组成不能作为年降水的替代性指标。  相似文献   

环境中Al13的研究进展     

刘璟  赵峰华  刘建权 《地球科学进展》2007,22(3):305-312

铝的水解反应及其水解聚合铝形态的研究，特别是具有Keggin结构的Al13聚合形态一直是地球化学、环境科学、形态分析以及生物毒理学等众多领域的研究热点之一。综述了近20年来Al13的分析方法、形成和转化机制、影响因素以及动力学方面研究的进展。  相似文献   

Characteristics of seasonal and spatial variations of primary production over the southeastern Bering Sea shelf   总被引：3，自引：1，他引：3  

TaeKeun Rho  Terry E. Whitledge 《Continental Shelf Research》2007,27(20):2556-2569

In situ primary production data collected during 1978–1981 period and 1997–2000 period were combined to improve understanding of seasonal and spatial distribution of primary production in the southeastern Bering Sea. Mean daily primary production rates showed an apparent seasonal cycle with high rates in May and low rates in summer over the entire shelf of the southeastern Bering Sea except for oceanic region due to lack of data. There was also an increasing trend of primary production rates in the fall over the inner shelf and the middle shelf. There was a decreasing trend of primary production rates between late April and mid-May over the inner shelf while there was an abrupt increase between late April and mid-May over the middle shelf and the outer shelf. In the shelf break region, there was an increasing pattern in late May. These suggest that there was a gradual progression of the development of the spring phytoplankton bloom from the inner shelf toward the shelf break region. There was also a latitudinal variability of primary production rate over the middle shelf, probably due to either spatial variations of the seasonal advance and retreat of sea ice or horizontal advection of saline water in the bottom layer. Annual rates of primary production across the southeastern Bering Sea shelf were 121, 150, 145, 110, and 84 g C m⁻² yr⁻¹ in the inner shelf, the middle shelf, the outer shelf, the shelf break, and oceanic region, respectively. High annual rates of primary production over the inner shelf can be attributed to continuous summer production based on regenerated nitrogen and/or a continuous supply of nitrogen at the inner front region, and to fall production. There were some possibilities of underestimation of annual primary production over the entire shelf due to lack of measurement in early spring and fall, which may be more apparent over the shelf break and oceanic region than the inner shelf, the middle, and the outer shelf. This study suggests that the response of primary production by climate change in the southeastern Bering Sea shelf can be misunderstood without proper temporal and seasonal measurement.  相似文献   

对流层氮氧化物光化学转化特征研究   总被引：10，自引：0，他引：10       下载免费PDF全文

朱彬  孙照渤  安俊岭 《大气科学》2002,26(4):487-495

应用大气光化学模式研究了日间影响NOx光化学转化率的主要物理化学因子.探讨了在不同NMHC/NOx比值时,NOx光化学特征及其转化产物的变化规律.结果表明,影响NOx转化率的主要因子是阳光辐射强度和NMHC/NOx比值.但在NMHC/NOx比值很低时,光强的增加并不能显著提高NOx转化率.温度和初始臭氧浓度对NOx转化率的影响次之.相对湿度对NOx转化率的影响较小.在不同NMHC/NOx比值下,NOx转化特征和产物有很大区别.NMHC/NOx比值高时,产物中PAN＞HNO3.NMHC/NOx比值中(低)时,产物主要是HNO3,PAN等有机氮不到10%(1%).最后初步比较了模拟和观测的NOy组成.  相似文献   

Effects of fire, grazing, and the presence of shrubs on Chihuahuan desert grasslands     

Paul B. Drewa  Kris M. Havstad 《Journal of Arid Environments》2001,48(4):429

Responses of herbaceous and suffrutescent species to fire, grazing, and presence of Prosopis glandulosa were examined in a Chihuahuan desert grassland in south-central New Mexico. Treatments were assigned randomly to eight 12×8 m plots within each of two blocks. Following fires in June 1995, unfenced plots were exposed to livestock grazing over 4 years. Plots were established that either included or excluded P. glandulosa. Perennial grass cover, primarilyBouteloua eriopoda , decreased by 13% in burned plots but increased 5% in unburned areas. Conversely, perennial forb cover was 4% greater after fire. Perennial grass frequency decreased 30% more and perennial forb frequency increased 10% more following burning. Further, increases in evenness after fire resulted in a 225% increase in species diversity. Grazing also resulted in a decrease in perennial grass cover while frequency decreased 22% more in grazed than ungrazed plots. Only frequency and not cover of perennial forbs and annual grasses increased more following grazing. Presence of P. glandulosa had no differential effect on responses of non-shrub species. Fires were conducted during near drought conditions while grazing occurred during years of precipitation equivalent to the long-term average. Precipitation immediately following fire may be critical for recovery of B. eriopoda -dominated desert grasslands; relationships between fire and post-fire precipitation patterns require future investigation.  相似文献   

植物响应气候变化模型模拟研究进展   总被引：9，自引：0，他引：9  

李双成 《地理科学进展》2001,20(3):217-226

尽管温室气体的增温效应及幅度大小具有很大的不确定性 ,存在许多分歧 ,然而植物对于气候变化的响应研究仍然成为众多学者关注的热点。近十年来 ,国内外学者从模型模拟的角度进行了多层面定量研究。归纳起来 ,已有的模型可以归并为生物地理相关模型、生态响应面模型、立地模型、植物生理模型以及统计模型等五类。本文逐一进行了评述 ,分析了它们的优势与不足 ,最后对模型模拟的发展趋势进行了展望。  相似文献   

藻类勃发—湖相油源岩形成的一种重要机制   总被引：38，自引：0，他引：38       下载免费PDF全文

刘传联  徐金鲤等 《地质论评》2001,47(2):207-210

浮游藻类是重要的湖相生油母质，本文以渤海湾盆地济阳坳陷早第三纪湖相生油岩为例，研究了其中藻类（主要是颗石藻和沟鞭藻＿化石的分布特征，并通过与现代水体中藻类生产和沉积作用的比较，探讨了生油湖泊中藻类生产和沉积方式及其对油源岩形成所起的控制作用，结果显示，藻类勃发现象在早第三纪生油湖泊中相当普遍，而且贯穿于各类油源岩的形成过程，这类快速事件性沉积是湖相油源岩形成的一种重要机制。  相似文献