The Interface Configuration of the Fresh‐/Dead Sea Water – Theory and Measurements     

E. Salameh  H. E.‐Naser 《洁净——土壤、空气、水》2000,28(6):323-328

The high‐density Dead Sea water (1.235 g/cm³) forms a special interface configuration with the fresh groundwater resources of its surrounding aquifers. The fresh groundwater column beneath its surroundings is around one tenth of its length compared to oceanic water. This fact alone indicates the vulnerability of the fresh groundwater resources to the impacts of changes in the Dead Sea level and to saltwater migration. Ghyben‐Herzberg and Glover equations were used to calculate the volumes of water in coastal aquifers which were replaced by freshwater due to the interface seaward migration as a result of the drop in the level of the Dead Sea. For that purpose, the dynamic equation of Glover approach has been integrated to accommodate that type of interface readjustment. The calculated amounts of freshwater which substituted salt Dead Sea water due to the migration of interface are 3.21 · 10¹¹ m³, from a Dead Sea level of –392 m to τ411 m below sea level. The average porosity of coastal aquifers was calculated to range from 2.8 to 2.94%. Geoelectric sounding measurements showed that areas underlying the coastal aquifers formerly occupied by the Dead Sea water are gradually becoming flushed and occupied by freshwater. The latter is becoming salinized due to the residuals of Dead Sea water in the aquifer matrix, the present salinity of which is lower than that of the Dead Sea water. At the same time salt dissolution from the Lisan Marl formation is causing collapses along the shorelines in the form of sinkholes, tens of meters in diameter and depth.  相似文献   

Effect of Preozonation on the Formation of Chlorinated Disinfection By‐products for River Ruhr     

Y.‐W. Ko  G. Abbt‐Braun  F. H. Frimmel 《洁净——土壤、空气、水》2000,28(5):256-261

The purpose of the study is to gain a better understanding about the formation of THM (trihalomethanes), HAA (haloacetic acids), and AOX (adsorbable organic halogen) in river water (river Ruhr, Essen) through a chlorination kinetics approach. The effect of chlorination time and preozonation on the formation of THM, HAA, and AOX substances was studied. Preozonation can reduce the chlorine demand and the precursors for AOX and THM. THM generation was reduced further, when the ozone dosage consumed increased from 3.5 to 12.5 mg in the 1.4 L reaction vessel. AOX and TCAA (trichloroacetic acid) concentrations also decreased dramatically when 3.5 mg of ozone had reacted with the river water, but a higher dose of ozone did not further reduce AOX and TCAA formations. Besides, the characteristics of organic matter in raw water, ozonated water, and preozonated/chlorinated water was investigated. The results suggest the formation of low‐molecular‐weight acids with low UV absorbance when high‐molecular refractive matter is oxidized.  相似文献   

Abschätzung der Eignung einer molekularbiologischen Methode zur Charakterisierung der Grundwasserbiozönose     

B. Kuhlmann  B. Kilb  G. Preuß 《洁净——土壤、空气、水》2000,28(5):250-255

Assessing the Suitability of a Molecularbiological Method To Characterise the Microbial Populations in Groundwater A molecularbiological technique was used to characterise the bacterial community structure of groundwater habitats. This method consists of the isolation of bacterial DNA from the samples, amplification of 16S rDNA by PCR (polymerase chain reaction), and separation of the amplified DNA by DGGE (denaturing gradient gel electrophoresis). By using more specific primer combinations in the PCR instead of universal eubacterial primers, also groups of microorganisms (Proteobacteria, sulfate reducer, Archaea) were determined. The resulting DGGE patterns that reflect the microbial diversity are compared and differences or similarities evaluated. In the present studies, groundwater from different sites (bank filtrate, artificially recharged groundwater, and natural groundwater) and with changing redox milieus (aerobic, anaerobic) were investigated as well as the solid aquifer material. Besides, samples were taken from the different stages of artificial groundwater recharge, i.e., from surface water to the drain tile. Samples from groundwater derived from sites with different hydrogeochemical or hydrological conditions like bank filtrate and recharged groundwater revealed great differences in DGGE patterns indicating a characteristic species composition in these habitats, while samples taken at different times from the same groundwater showed only small seasonal variations. Clearly different patterns were also found for groundwater and the adjacent solid material as well as for anaerobic and aerobic groundwaters. Looking at artificial groundwater recharge, almost identical patterns were found in raw water and samples from gravel and sand filtration. DGGE patterns from the resulting groundwater indicated a total change in community structure during underground passage. By using group specific primers, Desulfovibrionaceae, Desulfobacteriaceae, and Archaea could be detected in anaerobic groundwaters.The molecularbiological approach described here gives an increasingly comprehensive and more precise picture of the microbial population of different environments. It is especially suitable to compare the community structure from different habitats or to analyse changes for example due to environmental stress at the same site.  相似文献   

298.15K下LiCl-Li2B4O7-H2O体系热力学性质的等压研究          下载免费PDF全文

杨吉民  姚燕  张爱云  宋彭生 《盐湖研究》2004,12(3):31-38

用等压法研究了LiCl-Li2 B4O7-H2 O体系离子强度范围为 0 1 5 3 0～ 3 0 75 8mol kg-1不同质量摩尔浓度分数的等压平衡浓度 ,水活度 ;计算了LiCl和Li2 B4O7,混合盐溶液的饱和蒸汽压 ,渗透系数等热力学性质。以总硼浓度 0 0 8mol·kg-1为界 ,把所有混合盐的实验数据分为高浓度和低浓度两部分 ,按照不同的物种生成转化反应 ,考虑溶液中H3 BO3 和硼氧配阴离子B(OH) 4 -,B3 O3 (OH) 4 -和B4O5(OH) 4 2 -的存在形式。由实验数据用最小二乘法和迭代法求取了LiB(OH) 4 离子对的缔合平衡常数Km1,B3 O3 ,(OH) 4 离子的生成转化反应的化学计量平衡常数Km2 ,以及Pitzer模型的离子相互作用参数。用该模型计算的渗透系数值与实验结果取得合理的一致。对完善含锂、硼盐湖卤水体系的热力学模型和盐湖资源的综合开发具有重要意义  相似文献   

Biochemical Characterization of Refractory Organic Substances     

S. Hesse  F. H. Frimmel 《洁净——土壤、空气、水》1999,27(2):94-97

The characterization of refractory organic substances (ROS) is very complicated because of their heterogeneous structure. Size-exclusion chromatography with continuous detection of dissolved nitrogen (LC-DN), dissolved organic carbon (LC-DOC), and UV-absorbance (LC-UV) is a very useful analytical tool for the characterization of changes of ROS in natural aquatic systems and in technological treatment. The effect of natural, oxidative, and biochemical processes on formation and removal of ROS is described. Additionally the role of hydrolysable carbohydrates in the composition of ROS is presented.  相似文献   

Einflußfaktoren auf die Freisetzung von DOC und AOX unter ehemaligen Abwasserversickerungsflächen     

I. Savric  T. Reemtsma  M. Jekel 《洁净——土壤、空气、水》1999,27(3):157-163

Factors Influencing the Release of DOC and AOX out of Former Wastewater Infiltration Soils The influence of soil and of infiltration water quality on the release of dissolved organic carbon (DOC) and adsorbable organic halogens (AOX) from two former wastewater infiltration sites was investigated in laboratory column studies. Desorption was the most important factor influencing release processes. It depends on the amount of sorbent and sorbate and the strength of binding. Therefore, for constant irrigation rates a higher soil organic carbon content coincided with higher DOC-contents of the column effluent, while the irrigation water quality was of minor importance. Within one system the dependencies of AOX release and DOC mobilization were found to be similar. Transferring these dependencies on other systems has its limitations because of a different binding quality between sorbent and sorbate.  相似文献   

The River Odra Estuary as a Gateway for Alien Species Immigration to the Baltic Sea Basin     

P. Gruszka 《洁净——土壤、空气、水》1999,27(5):374-382

The river Odra estuary belongs to those water bodies in the Baltic Sea area which are most exposed to immigration of alien species. Non-indigenous species that have appeared in the Szczecin Lagoon (i.a. Dreissena polymorpha, Potamopyrgus antipodarum, Corophium curvispinum) and in the Pomeranian Bay (Cordylophora caspia, Mya arenaria, Balanus improvisus, Acartia tonsa) in historical time and which now are dominant components of animal communities there as well as other and less abundant (or less common) alien species in the estuary (e.g. Branchiura sowerbyi, Eriocheir sinensis, Orconectes limosus) are presented. In addition, other newcomers – Marenzelleria viridis, Gammarus tigrinus, and Pontogammarus robustoides – found in the estuary in the recent ten years are described. The significance of the sea and inland water transport in the region for introduction of non-indigenous species is discussed against the background of the distribution pattern of these recently introduced polychaete and gammarid species.  相似文献   

Polycyclic Aromatic Hydrocarbons and Polysaccharides in River Sediments from the Odra Basin after the 1997 Flood     

B. Bierawska  D. G&#x;d  J. B&#x;aejowski  B. Lammek  J. Szafranek  E. Niemirycz 《洁净——土壤、空气、水》1999,27(5):350-356

Fourteen polycyclic aromatic hydrocarbons (PAH), six monosaccharides (SA) formed following the hydrolysis of polysaccharides, as well as water and organic matter contents were determined in river sediments sampled in thirteen points in the Odra basin after the catastrophic flood of 1997. The water content is related to the water absorbing capacity of the soil in the Odra catchment area. The PAH content increases together with the increase in the organic matter (OM) content which suggests that these species are mainly of anthropogenic origin. On the other hand, SA and OM contents decrease with increasing water content, which implies that both enhance biological life. The PAH content tends to decrease when the SA content increases. This relation goes hand in hand with the quality of water resources, which is greater when the quantity of polysaccharides is higher.  相似文献   

Description of Ecosystem of the Lower Odra and the Odra Estuary     

J. C. Chojnacki 《洁净——土壤、空气、水》1999,27(5):257-267

Environmental conditions of the lower river Odra and its estuary show a high variability of chemical and biological parameters, related to the dynamics of the river, its mouth area, the Lake Dabie-Szczecin Lagoon system, and the Pomeranian Bay. Water chemistry, affected by the total sum of industrial, urban, and agricultural pollution discharged from the direct drainage area is discussed. This pollution load influences the composition and ecological structures of terrestrial, frequently unique, phytal communities associated with aquatic areas, phyto- and zooplankton, benthos, fish fauna, and avifauna. The current status of the terrestrial and aquatic ecosystems is described; elements of cultural infrastructure existing within the Lower Odra Valley in Western Pomerania are mentioned as well.  相似文献   

Distribution and Fate of Polycyclic Aromatic Hydrocarbons (PAHs) in Sediments and Fluffy Layer Material from the Odra River Estuary     

G. Witt  E. Trost 《洁净——土壤、空气、水》1999,27(5):308-315

The distribution and fate of polycyclic aromatic hydrocarbons (PAHs) were investigated in surface sediments (0...2 cm) and fluffy layer material of the internal and external coastal waters of the Odra river estuary (north-eastern Germany). The area includes the Odra Lagoon (Oderhaff), the Greifswalder Bodden, the Pomeranian Bight, and the Arkona Basin. Elevated concentrations were observed in the surface sediments of the internal coastal waters with highest concentrations in the Odra Lagoon. This indicates a significant contribution of river discharge to the contamination of sediments with PAHs. During the exceptional Odra flood in the summer of 1997 significantly higher concentrations of PAHs were found in the fluffy layer material of the Odra Estuary. The distribution of the individual PAH compounds varies widely depending on their structure and molecular weight. A concentration gradient of the lower molecular weight PAHs was found from the Odra Lagoon to the open sea areas. The concentrations decreased rapidly from the Oder Haff to the Arkona Basin. These results were found in both sediments and fluffy layer material. This is attributed to the degradation of the lower molecular weight PAHs during transport from the urban regions to the sedimentation basins. A decrease of this magnitude was not found for the higher molecular weight PAHs (i.e. benzo(a)pyrene) due to their higher persistence. An enrichment of these compounds was measured in the Arkona Basin.  相似文献