Presence of LaO, ScO and VO Molecular Lines in Sunspot Umbral Spectra     

P. Sriramachandran  S. P. Bagare  N. Rajamanickam  K. Balachandrakumar 《Solar physics》2008,252(2):267-281

High-resolution Fourier Transform Spectrometer sunspot umbral spectra of the National Solar Observatory/National Optical Astronomy Observatory at Kitt Peak were used to detect rotational lines from 19 electronic transition bands of the molecules LaO, ScO and VO, in the wavenumber range of 11 775 to 20 600 cm⁻¹. The presence of lines from the following transitions is confirmed: A ² Π _r1/2 – X ² Σ ⁺(0, 0; 0, 1), A ² Π _r3/2 – X ² Σ ⁺(1, 0), B ² Σ ⁺ – X ² Σ ⁺(0, 0; 0, 1; 1, 0) and C ² Π _r1/2 – A′²Δ _r3/2(0, 0; 1, 1) of LaO; A ² Π _r3/2 – X ² Σ ⁺(0, 0), A ² Π _r1/2 – X ² Σ ⁺(0, 0) and B ² Σ ⁺ – X ² Σ ⁺(0, 0) of ScO; and C ⁴ Σ ⁻ – X ⁴ Σ ⁻(0, 1; 1, 0; 0, 2) and (2, 0) of VO. However, the presence of A ² Π _r3/2 – X ² Σ ⁺(0, 0) and C ² Π _r3/2 – A′²Δ _r5/2(0, 0; 1, 1) of LaO and C ⁴ Σ ⁻ – X ⁴ Σ ⁻(0, 0) of VO are found to be doubtful because the lines are very weak, and detections are difficult owing to heavy blending by strong rotational lines of other molecules. Equivalent widths are measured for well-resolved lines and, thereby, the effective rotational temperatures are estimated for the systems for which the presence is confirmed.  相似文献   

清镇式铁矿矿石特征及加工技术性能探讨 ——以猫场铝土矿红花寨、白浪坝矿段铁矿床为例          下载免费PDF全文

杨明坤  张周位  杨国彬  李宏志  杨毕  苏亮广 《贵州地质》2019,36(1):95-100

贵州中部清镇、修文等地石炭系铝土矿底部的铁矿俗称为"清镇式铁矿",与黔中铝土矿共同赋存于下石炭统九架炉组之中。本文在实际勘探工作及通过勘探阶段在钻孔副样中采集的铁矿进行可选性试验基础上,以同类型的清镇市猫场铝土矿红花寨、白浪坝矿段铝土矿共生的铁矿为研究对象,指出该类型铁矿矿石自然类型为赤铁矿和褐铁矿;工业类型为需选铁矿石;矿石矿物主要为赤铁矿,部分赤铁矿水化为针柱状褐铁矿;脉石矿物则以白云石和方解石为主。矿石中可供利用的主要元素是铁,造渣组分主要是硅、铝,其次为钙、镁等。试验结果表明,该矿采用一粗一精一扫的强磁选试验可获得铁精矿TFe含量55. 58%,回收率80. 11%的良好指标,精矿中各元素含量达到H55-Ⅰ类赤铁精矿质量要求,在当前市场条件下采用推荐工艺处理该矿可获利。结论对黔中铝土矿资源的综合勘查开发具有借鉴意义。  相似文献   

Heating duration of igneous rim formation on a chondrule in the Northwest Africa 3118 CV3oxA carbonaceous chondrite inferred from micro-scale migration of the oxygen isotopes     

《Chemie der Erde / Geochemistry》2019,79(4):125524

Due to their common occurrence in various types of chondrites, igneous rims formed on pre-existing chondrules throughout chondrule-forming regions of the solar nebula. Although the peak temperatures are thought to reach similar values to those achieved during chondrule formation events, the heating duration in chondrule rim formation has not been well defined. We determined the two-dimensional chemical and oxygen isotopic distributions in an igneous rim of a chondrule within the Northwest Africa 3118 CV3_oxA chondrite with sub-micrometer resolution using secondary ion mass spectrometry and scanning electron microscopy. The igneous rim experienced aqueous alteration on the CV parent body. The aqueous alteration resulted in precipitation of the secondary FeO-rich olivine (Fa_40–49) and slightly disturbed the Fe-Mg distribution in the MgO-rich olivine phenocrysts (Fa_11–22) at about a 1 μm scale. However, no oxygen isotopic disturbances were observed at a scale greater than 100 nm. The MgO-rich olivine, a primary phase of igneous rim formation, has δ¹⁷O = −6 ± 3‰ and δ¹⁸O = −1 ± 4‰, and some grains contain extreme ¹⁶O-rich areas (δ¹⁷O, δ¹⁸O = ∼−30‰) nearly 10 μm across. We detected oxygen isotopic migration of approximately 1 μm at the boundaries of the extreme ¹⁶O-rich areas. Using oxygen self-diffusivity in olivine, the heating time of the igneous rim formation could have continued from several hours to several days at near liquidus temperatures (∼2000 K) in the solar nebula suggesting that the rim formed by a similar flash heating event that formed the chondrules.  相似文献   

Phosphate removal from water by naturally occurring shale,sandstone, and laterite: The role of iron oxides and of soluble species     

Dan Eude Kpannieu  Martine Mallet  Lacina Coulibaly  Mustapha Abdelmoula  Christian Ruby 《Comptes Rendus Geoscience》2019,351(1):37-47

Aqueous phosphate removal by three geomaterials from Ivory Coast was evaluated to determine their potential application as low-cost phosphate adsorbents in wastewater treatment. Batch experiments showed that phosphate uptake strongly depended on pH. Laterite and sandstone dissolution was less pronounced compared to shale. A correlation between concentrations of aqueous cation species released from shale and phosphate uptake was observed. The kinetics were well described using the pseudo-second-order model. Isotherms displayed a saturation level on shale, while phosphate uptake continuously increased for laterite and sandstone. The removal efficiency decreased in the following ranking order: laterite > sandstone > shale. Laterite was also the most efficient adsorbent in column experiments. The high phosphate removal efficiency of laterite (8.3 mg PO₄ g^?1) was attributed to the presence of superparamagnetic low grain sizes of goethite. Laterite is a particularly promising material for further investigation in wastewater treatment technology such as constructed wetlands.  相似文献   

论中国古代地缘战略制定中的“权衡”——以《盐铁论》为例   总被引：3，自引：1，他引：2  

王丰龙  刘云刚 《地理科学》2019,39(9):1407-1415

《盐铁论》是记录汉朝时期关于盐铁酒榷均输及对匈奴关系的辩论的一部重要著作,能够较典型地反映中国古代地缘战略制定中的“权衡”过程。构建中国古代地缘战略制定中的“权衡”理论分析框架,继而基于该分析框架对《盐铁论》中的地缘战略辩论进行详细解读。《盐铁论》中辩论双方“权衡”的要点包含匈奴对汉朝产生的威胁程度、领土扩张所带来的收益大小和相应地缘战略的合法性3个方面。从思想、方法、目的等比较中西方地缘政治研究差异,指出“权衡”思想为西方主导的地缘政治理论提供新视角。  相似文献   

马里亚纳海沟挑战者深渊初期多金属氧化物的 矿物学、地球化学特征及其成因环境研究          下载免费PDF全文

王海峰  赖佩欣  邓希光  王汾连  杨永  邓义楠  何高文 《海洋学研究》2019,37(1):21-29

对大洋27航次在西太平洋马里亚纳海沟挑战者深渊获取的3个多金属氧化物样品进行了X射线矿物衍射分析、穆斯堡尔谱分析及地球化学元素分析,研究其矿物、地球化学特征差异。结果表明,所取样品处于多金属氧化物发育的初始阶段,具有独特的矿物地球化学特征:(1)相较于太平洋CC区及中太平洋海盆获取的多金属结核样品,本研究样品的矿物组成中含有异常高的石英、斜长石以及黏土矿物,而水羟锰矿和钙锰矿含量较低。(2)样品中铁相矿物主要为正方针铁矿(91.6%),另含少量纤铁矿(8.4%),推测是纤铁矿向更加稳定的正方针铁矿衍变的结果。(3)由于样品中深海黏土组分以及氧化物核心物质的混入,加上吸附金属氧化物时间较短,导致SiO₂和Al₂O₃含量均高于正常结核,而Fe、Mn、Cu、Co、Ni等其余金属元素含量较低。(4)由于形成时间较短,样品中稀土元素含量相对较低,ΣREE仅约为0.4×10^-3(一般太平洋CC区及中太平洋结核中稀土含量均大于1.0×10^-3);加之海水氧化还原作用的降低以及研究区海底热液活动的影响,Ce元素未表现出多金属结核中常见的正异常。  相似文献   

Evaluation of riverbed magnetic susceptibility for mapping biogeochemical hot spots in groundwater-impacted rivers     

Chen Wang  Martin A. Briggs  Frederick D. Day-Lewis  Lee D. Slater 《水文研究》2021,35(5):e14184

Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.  相似文献   

东平-汶上铁成矿带西侧低缓磁异常区找矿前景分析          下载免费PDF全文

程龙  杨勇 《山东国土资源》2020,36(9)

梁山东丁庄铁矿位于东平-汶上铁成矿带西侧的低缓磁异常区,为区内新发现的沉积变质型铁矿床。通过1∶1万高精度磁法面积测量工作,在区内圈定3个磁异常,并进行钻探验证,证实其中2个为隐伏磁铁矿体引起,矿体赋存于泰山岩群山草峪组中。通过研究矿体的地质特征、磁异常特征,并与区域铁矿成矿条件对比分析,认为区内矿致磁异常特征一般表现为在数十纳特的平缓背景场基础上,突然升高至数百纳特的相对高值异常,具突变特征。该类异常一般呈NW走向,与东平-汶上铁成矿带走向基本一致,其形态一般呈规则的长条带状、椭圆状或串珠状。区域上存在较多与研究区具有相似特征的低缓磁异常,且具备有利的成矿地层条件,因此认为区域上低缓磁异常区具有较大的找矿潜力,找矿前景良好。  相似文献   

Geochemistry of Flooded Underground Mine Workings Influenced by Bacterial Sulfate Reduction     

Amber J. Roesler  Christopher H. Gammons  Gregory K. Druschel  Harry Oduro  Simon R. Poulson 《Aquatic Geochemistry》2007,13(3):211-235

Unlike the majority of the water in the flooded mine complex of Butte Montana, which includes the highly acidic Berkeley pit lake, groundwater in the flooded West Camp underground mine workings has a circum-neutral pH and contains at least 8 μM aqueous sulfide. This article examines the geochemistry and stable isotope composition of this unusual H₂S-rich mine water, and also discusses problems related to the colorimetric analysis of sulfide in waters that contain FeS_(aq) cluster compounds. The West Camp mine pool is maintained at a constant elevation by continuous pumping, with discharge water that contains elevated Mn (90 μM), Fe (16 μM), and As (1.3 μM) but otherwise low metal concentrations. Dissolved inorganic carbon in the mine water is in chemical and isotopic equilibrium with rhodochrosite in the mineralized veins. The mine water is under-saturated with mackinawite and amorphous FeS, but is supersaturated with Cu- and Zn-sulfides. However, voltammetry studies show that much of the dissolved sulfide and ferrous iron are present as FeS_(aq) cluster molecules: as a result, the free concentration of the West Camp water is poorly constrained. Concentrations of dissolved sulfide determined by colorimetry were lower than gravimetric assays obtained by AgNO₃ addition, implying that the FeS_(aq) clusters are not completely extracted by the Methylene Blue reagent. In contrast, the clusters are quantitatively extracted as Ag₂S after addition of AgNO₃. Isotopic analysis of co-existing aqueous sulfide and sulfate confirms that the sulfide was produced by sulfate-reducing bacteria (SRB). The H₂S-rich mine water is not confined to the immediate vicinity of the extraction well, but is also present in flooded mine shafts up to 3 km away, and in samples bailed from mine shafts at depths up to 300 m below static water level. This illustrates that SRB are well established throughout the southwestern portion of the extensive (>15 km³) Butte flooded mine complex.  相似文献   

海洋中铁的来源、形态和对初级生产力的限制作用   总被引：6，自引：0，他引：6  

秦延文  张曼平  周革非 《海洋科学进展》1998,(3)

在海洋中,铁和Ｎ、Ｐ等主营养盐一样,也是一种限制浮游植物初级生产力的重要因素。由于铁是一种化学活性较高的元素,所以海水中铁的存在形态、来源及沉降会直接影响其生物可利用性。目前人们一般采用预富集／原子吸收法（ＡＡＳ）或是借助于电分析技术（如催化极谱）来测定海水中的铁。  相似文献