钾长石分解反应热力学与过程评价   总被引：2，自引：2，他引：2  

马鸿文  苏双青  王芳  徐锦明  谭丹君  刘浩 《现代地质》2007,21(2):426-434

综述了添加各种助剂分解钾长石的研究进展。对不同体系中钾长石分解反应的G ibbs自由能和能耗计算,综合考虑一次性资源、能源消耗量和烧结过程的环境相容性、产品方案等因素,结果表明:只有以石灰石、碳酸钠为配料的工艺路线具有实际工业应用价值;而唯有以碳酸钠为配料时,钾长石原料烧结过程才具有一次性资源消耗量最少、能耗最低、温室气体CO2排放量最小、且可生产高附加值产品、实现完全清洁生产等优点。因此,选择以碳酸钠为配料分解钾长石的技术路线,具有良好的工业化应用前景。  相似文献   

湿斜压大气中暴雨中尺度系统发展的一种可能机制   总被引：1，自引：0，他引：1  

陈忠明 《高原气象》2007,26(2):233-239

根据暴雨中尺度系统发生时的大气运动特征,在绝热、无摩擦条件下,从湿斜压原始方程出发,考虑大气运动的涡度及散度演化不仅受动力场的制约,而且还受到热力场的约束,采用不同于传统研究涡度及散度方程的分析方法,导出了新形式的涡度及散度方程。在此基础上,分析了湿斜压大气中对流层中低层气流旋转与辐合持续增长的动力特征,初步揭示了湿斜压大气中暴雨中尺度系统发展的动力机制。  相似文献   

基于TOUGHREACT的成矿过程化学反应数值模拟——以虎头崖铅锌多金属矿床为例          下载免费PDF全文

张婉秋  邹艳红 《地质找矿论丛》2020,35(3):354-362

虎头崖铅锌多金属矿床是青海省祁漫塔格成矿带中典型的矽卡岩型矿床。本文基于前人对该矿区地质特征、矿物学和地球化学特征等方面的研究成果，利用TOUGHREACT数值模拟软件，针对石英-晚期硫化物成矿阶段进行成矿过程化学反应数值模拟研究。通过建立地质概念模型和网格化物化参数的设置，在设置的时间步长内对多相流体流动和热对流传导、溶质运移以及地球化学反应过程进行模拟计算，研究了矿区内不同温压条件下成矿元素化学平衡浓度变化的总体趋势以及对方铅矿和闪锌矿矿物溶解沉淀情况的影响。结果表明：当温度从250℃降至155℃时，Pb²⁺的化学平衡浓度出现骤减；当温度从300℃降至100℃时，Zn²⁺的化学平衡浓度出现骤减；由于矿物的沉淀需要消耗大量相关的成矿元素，方铅矿和闪锌矿最佳成矿温度范围分别为155℃~250℃和100℃~300℃；不同温度和压力对成矿元素化学平衡浓度影响不同，温度是控制方铅矿和闪锌矿沉淀化学反应的核心因素，压力的影响较小。模拟结果与传统地质解译结果相对符合，证明了模拟的有效性。  相似文献   

昆明机场红土地层地下结构抗震模拟研究     

周全通  周志国  许少清  龚仙贵 《地质灾害与环境保护》2020,(1):35-43

昆明机场残积红土既是区域内重要的土地资源,更是各类工程建设的建筑地基,由于机场及临近区域内小江地震活动断裂带和普渡河断裂带地震活动频繁,使研究区处于较不稳定状态。本文采用MIDAS GTS有限元数值分析软件,利用动三轴试验所得出的结果,分别对昆明长水国际机场玄武岩残积红土、砂页岩残积红土地层下典型的地下结构进行了抗震模拟研究。所获得的研究成果,对红土分布区城市及村镇房屋建筑地基和地下空间结构抗震安全稳定性评价具有一定的指导意义和实用价值。  相似文献   

Genetic relationship of metamorphic reaction and dehydration-melting     

Fulai Liu  Qihan Shen  Yuansheng Eng  Xuechun Xu  Rui Ma 《中国科学D辑(英文版)》1998,41(1):49-56

The high-temperature and pressure experimental data of garnet, sillimantite and biotite-bearing potash feldspar gneiss (SGBG, natural block rock) has shown that metamorphic reactions between garnet and melt, and mineral assemblage evolutional features are not only controlled byP-T condition, but also genetically correlate with dehydration-melting of biotite and partial melting of felsic minerals. Combining experimental data with theoretical analyses, the genetic mechanism of metamorphic reaction and its dynamic significance have been demonstrated in the process of metamorphic evolution of khondalite series on the border of Jin (Shanxi Province)-Inner Mongolia. Project supported by the Youth Geologist Foundation of Ministry of Geology and Mineral Resources of China, the Post-docter Foundation and the National Natural Science Foundation of China (Grant No. 49572138).  相似文献   

蔓箐沟一带石榴基性麻粒岩变质反应与矿物演化     

刘福来 《吉林大学学报(地球科学版)》1998,(1)

蔓箐沟地区石榴基性麻粒岩发育多期变质反应结构。矿物组合演化可划分三个阶段：①峰期阶段（Ｍ１）,以包裹于石榴石中的Ｏｐｘ＋Ｃｐｘ±Ｈｂ＋Ｐｌ±Ｑｚ和由Ｇｔ＋Ｏｐｘ＋Ｃｐｘ±Ｈｂ＋Ｐｌ±Ｑｚ组成基质矿物组合为代表;②退变早期近等温减压阶段（Ｍ２）,形成蠕虫状后成合晶Ｏｐｘ＋Ｈｂ＋Ｐｌ±Ｍｔ;③退变晚期阶段（Ｍ３）,则形成细粒、黄绿色Ｈｂ＋中酸性Ｐｌ的较低温组合。并揭示该区石榴基性麻粒岩从中下部地壳的麻粒岩相变质,到快速抬升至中浅部地壳发生的近等温减压及晚期降温退变的复杂ｐＴ演化历史。  相似文献   

Measurements of Reaction Coefficients of NO2 and HONO on Aerosol Particles     

Roy M. Harrison  Gareth M. Collins 《Journal of Atmospheric Chemistry》1998,30(3):397-406

The reaction coefficients of nitrogen dioxide and nitrous acid with monodisperse sodium chloride and ammonium sulphate aerosols have been measured in a flow reactor at atmospheric pressure. These experiments were performed at relative humidities above and below the deliquescence points of both aerosols (r.h. 50 and 85%) at 279 K. The results for NO₂ afford a reaction coefficient in the range (2.8–10) × 10^-4 and for HONO, (2.8–4.6) × 10^-3. For both species, there appears to be an enhancement of the reaction coefficient on sodium chloride aerosol at 50% r.h. The results are compared with reaction coefficients determined by other experimental methods. A good agreement is found for both gases between this method and the coated denuder method previously developed in our research laboratories (Msibi et al., 1993) and with the majority of other published data for NO₂. In the case of HONO, our estimate of reaction coefficient is smaller than, or at the lower limits of the ranges reported by other published studies.  相似文献   

THE INFLUENCE OF PHOTOCHEMICAL PROCESS ON THE ATMOSPHERIC WAVE^*          下载免费PDF全文

Xu Jiyao  Wang Yingjian 《Acta Meteorologica Sinica》1998,12(4):459-462

The time damping rate of gravity wave in the range of 30-70 km is calaclated in three circumstances:(1) adiabatic process,(2) diabatic process caused by atmospheric cooling,and(3) diabatic process resulting from atmospheric photochemical heating and cooling.The results indicate that the photochemical heating is as important as Newtonian cooling and its contribution to the time damping rate of gravity wave can not he negligible.  相似文献   

THE INFLUENCE OF PHOTOCHEMICAL PROCESS ON THE ATMOSPHERIC WAVE     

徐寄遥  王英鉴 《Acta Meteorologica Sinica》1998,(4)

The time damping rate of gravity wave in the range of 30-70 km is calaclated in threecircumstances:(1)adiabatic process,(2)diabatic process caused by atmospheric cooling,and(3)diabatic process resulting from atmospheric photochemical heating and cooling.The resultsindicate that the photochemical heating is as important as Newtonian cooling and its contribution tothe time damping rate of gravity wave can not he negligible.  相似文献   

Ultrasonic-assisted condensation of chitosan with salicylaldehyde     

段丽红  郭祀远  杨晋青  叶盛权  王兆梅  肖凯军  郑必胜 《中国海洋湖沼学报》2009,27(4):882-886

In order to synthesize an improved adsorbent for heavy metal ions, we studied the condensation reaction of chitosan with salicylaldehyde in ethanol to form a Schiff base. The effect irradiating the reaction using an ultrasonic liquid processor was contrasted with conventional methods. The IR spectra of condensed chitosan prepared by the two methods showed that their molecular structures were identical. The reaction conditions, including solvents, ultrasonic power density and irradiation time, pH, and reactant ratio, were optimized by orthogonal design. A shorter reaction time and a higher product yield were obtained using ultrasonic-assisted synthesis compared with the traditional method. A condensation degree of 89.63% was achieved using the optimized conditions: i.e. ultrasonic irradiation at 180 W for 60 min; 95% ethanol as the solvent, pH 4.0, and salicylaldehyde:chitosan ratio of 6:1.  相似文献