UV-Vis spectrophotometric and XAFS studies of ferric chloride complexes in hyper-saline LiCl solutions at 25-90 °C     

Weihua Liu  Barbara Etschmann  Leone Spiccia  Brent McInnes 《Chemical Geology》2006,231(4):326-349

The speciation and thermodynamic properties of ferric chloride complexes in hydrothermal solutions and hypersaline brines are still poorly understood, despite the importance of this element as a micronutrient and ore-component. Available experimental data are limited to room temperature and relatively low chloride concentrations. This paper reports results of UV-Vis spectrophotometric and synchrotron XAFS experiments of ferric chloride complexes in chloride concentrations up to 15 m and at temperatures of 25-90 °C. Qualitative interpretation of the UV-Vis spectra shows that FeCl²⁺, FeCl₂⁺, FeCl_3(aq) and FeCl₄⁻ were present in the experimental solutions. As chloride concentrations increase, higher ligand number complexes become important with FeCl₄⁻ predominating in solutions containing more than 10 m at 25 °C. The predominance fields of FeCl_3(aq) and FeCl₄⁻ expand to lower Cl concentrations with increasing T. Both XANES and UV-Vis spectra reveal a major change in the geometry of the complex between FeCl₂⁺ and FeCl_3(aq). EXAFS data confirm that the number of chloride ligands increases with increasing chloride concentration and show that Fe³⁺, FeCl²⁺ and FeCl₂⁺ share an octahedral geometry. FeCl_3(aq) could be either tetrahedral or trigonal dipyramidal, while FeCl₄⁻ is expected to be tetrahedral. EXAFS data support a tetrahedral geometry for FeCl₄⁻, especially at 90 °C, but do not allow to distinguish between a tetrahedral or trigonal dipyramidal geometry for FeCl_3(aq) because of similar Fe-Cl distances. At room temperature, EXAFS data suggest that FeCl_3(aq) may be a mixture of octahedral and tetrahedral or trigonal dipyramidal forms.The room temperature formation constants for three ferric chloride complexes (FeCl₂⁺, FeCl_3(aq) and FeCl₄⁻) determined from the UV data are generally in good agreement with previous studies. Calculations based on the properties extrapolated to 300 °C show that hematite solubility is much higher than previously estimated, and that the high orders complexes FeCl_3(aq) and FeCl₄⁻ are important at high temperatures even in solutions with low chloride concentrations. The accuracy of these properties is limited by a poor understanding of activity-composition relationships in concentrated electrolytes, and by limitations in the available experimental techniques and extrapolation algorithms; however, the inclusion of higher order complexes in numerical models of ore transport and deposition allows for a more accurate qualitative prediction of Fe behaviour in hydrothermal and hypersaline systems.  相似文献   

藏北羌塘泛非和印支事件的记录:来自俄久卖变质杂岩地球化学与锆石U-Pb年代学的证据   总被引：3，自引：2，他引：1  

郑艺龙  王根厚  郭志文  梁晓  袁国礼  王寒冻  黄波  何亚东 《岩石学报》2015,31(4):1137-1152

藏北羌塘盆地大地构造属性是长期争议的议题,深入研究有助于对该问题的探讨。俄久卖杂岩体产出于羌塘盆地中央隆起带北缘,包括夕线石片麻岩和片麻状花岗岩,以及侵位于其中的淡色花岗岩脉。在中央隆起北侧,高级变质岩仅发现于俄久卖杂岩体内。因此,该杂岩为研究羌塘盆地构造演化的重要窗口。在区域地质调查的基础上,本文重点对片麻状花岗岩和淡色花岗岩开展了岩石学、锆石U-Pb年代学与地球化学研究。其中,片麻状花岗岩加权平均年龄为476.6±4.8Ma,且岩石中大离子亲石元素Rb、Ba、Th和Pb相对富集,高场强元素Nb、Ta、Ti和P较亏损,显示弧火山岩的地球化学特征。淡色花岗岩中的锆石呈明显的核-幔-边环带结构,其核部测得年龄介于2052±25Ma~541±8Ma之间,幔部加权平均年龄为463.7±7.5Ma,边部内侧为214.6±2Ma,边部外侧为189.4±1.1Ma。地球化学特征表明该淡色花岗岩形成于典型的同碰撞构造环境。综合研究表明,俄久卖杂岩体包括早古生代泛非晚期岩浆事件产物(~470Ma),且在印支运动期遭受深埋作用并发生部分熔融,分别形成了~214Ma和~189Ma的淡色花岗岩。因此,羌塘盆地内泛非时期的地质记录可延伸至中央隆起带北缘。  相似文献   

三氯乙烯在模拟有机质-矿质复合体中的吸附行为研究   总被引：1，自引：0，他引：1  

张坤峰  李巨峰  何江涛  刘菲 《岩石矿物学杂志》2011,30(6):1099-1104

土壤中有机质与无机矿物长期共存,其存在形式发生着变化。本文利用批实验的方法对三氯乙烯的吸附行为进行模拟研究,结果表明,土壤中有机质与无机矿物是以有机质-矿质复合体形式存在的,有机质与无机矿物的相互作用影响复合体的吸附性能,与有机质、无机矿物单体相比,复合体Kd、Koc明显发生变化;并提出了有机质-矿质复合体模型。  相似文献   

The geometry of the Archean, Paleo- and Neoproterozoic tectonics in the Southwest Cameroon     

Sbastien Owona  Joseph Mvondo Ondoa  Lothar Ratschbacher  Simon Pierre Mbola Ndzana  Flix M. Tchoua  Georges Emmanuel Ekodeck 《Comptes Rendus Geoscience》2011,343(4):312-322

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东秦岭陡岭杂岩花岗岩的Sr-Nd-Pb同位素特征及其地质意义     

杨斌虎  张成立  李雷 《地质通报》2011,30(203):439-447

东秦岭陡岭杂岩中甘沟、三坪沟和封子山等花岗岩体SiO2含量变化大,低碱、高钠,富集LREE和LILE,贫HFSE,亏损Nb、Sr、P和Ti,具准铝质钙碱性I型花岗岩的特征。吐雾山岩体富Si、碱,高Al,贫Ca、Mg,稀土元素总量高,Eu负异常强,富集Rb、Th、U和Pb,明显亏损Sr、P和Ti,显示了A2型花岗岩的地球化学特征。2类花岗岩体Nd-Pb同位素组成基本一致,指示源自相同的物质源区,地球化学特征的差异主要为岩浆分异演化途径不同所致。它们的Pb同位素组成明显不同于北秦岭基底岩系及同时代花岗岩的高放射性成因Pb,与南秦岭和扬子地块基底岩系低放射成因Pb同位素组成类似,表明这次花岗岩浆活动是新元古代中期扬子地块统一陆块形成过程中岩浆活动在秦岭地区的反映,与北秦岭构造带无任何成因联系。  相似文献   

Borehole electrical imaging and structural analysis in a granitic environment     

A. Straub  U. Krückel  Y. Gros 《Geophysical Journal International》1991,106(3):635-646

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CLUSTERS AND COMPLEXES OF MEDIUM-SIZED URBAN MANUFACTURING SYSTEMS: TWO CASE STUDIES IN BRAZIL *     

Baruch A. Kipnis 《The Professional geographer》1983,35(1):32-39

Industrial linkages of two medium-sized Brazilian urban manufacturing systems are analyzed. Clusters are similar to those of the national economy while complexes are uneven for the two cities which implies that neither the size nor the diversity of the local industry influences the evolution of complexes. Development depends on time and on the volume (threshold) of manufacturing activity. If manufacturing complexes are carefully implemented and maintained, medium-sized centers might become viable manufacturing growth center communities.  相似文献   

Devonian rodingite from the northern margin of the North China Craton: mantle wedge metasomatism during ocean–continent convergence     

Chao-Nan Hu 《International Geology Review》2018,60(9):1073-1097

The northern margin of the North China Craton (NCC) was an active convergent margin during Palaeozoic and preserves important imprints of magmatic and metasomatic processes associated with oceanic plate subduction. Here, we investigate the mafic–ultramafic rocks in the Xiahabaqin–Sandaogou complexes from the northern NCC including pyroxenite, hornblendites, hornblende gabbro, and their rodingitized counterparts within a serpentinite domain. We present petrological, zircon U–Pb geochronological, and geochemical data to constrain the nature and timing of the magmatic and metasomatic processes in the subduction zone mantle wedge. The rock suites investigated in this study are characterized by low contents of SiO₂, Na₂O, and K₂O, with high CaO, FeO, Fe₂O₃, and MgO. The rodingitized rocks show markedly high CaO and lower MgO compared to their ultramafic protolith, suggesting extensive post-magmatic infiltration of Ca-rich, Si-poor fluids derived by serpentinization of mantle peridotite. The enrichment of large ion lithophile and light rare earth elements such as Ba, Sr, K, La, and Ce with relative depletion of high field strength elements like Nb, Ta, Zr, and Hf in the ultramafic rocks collectively suggest metasomatism of a fore-arc mantle wedge by fluids released through dehydration of subducted oceanic slab and subduction-derived sediments. Dehydration and decarbonation leading to metasomatic fluid influx and serpentinization of mantle wedge peridotite account for the enriched geochemical signatures for the rodingitized rocks. The zircon grains in these rocks show textures indicating magmatic crystallization followed by fluid-controlled dissolution–precipitation. Magmatic zircons from altered pyroxenite, hornblendite, and rodingitized pyroxenite in Xiahabaqin yield protolith crystallization ages peaks at 396 Ma and 392 Ma and metasomatic grains show ages of 386 Ma, 378 Ma, and 348 Ma. The zircons from hornblendite and basaltic trachyandesite indicate protolith emplacement during 402–388 Ma. Metasomatic zircon grains from rodingitized hornblende gabbro in Sandaogou complex show a wide range of ages as 412 Ma, 398 Ma, 383 Ma, and 380 Ma. The common magmatic zircon ages peaks at 398–388 Ma in most of the rocks suggest a similar time for magma crystallization in the Xiahabaqin and Baiqi during Middle Devonian. Subsequently, repeated pulses fluids and melts resulted in metasomatic reactions in mantle wedge until early Permian. The Lu–Hf analysis of the zircon grains from these rocks display markedly negative εHf(t) values ranging from ?22.4 to ?7.7, suggesting magma derivation from an enriched, hydrated lithospheric mantle through fluid–rock interaction and mantle wedge metasomatism. Rodingitization processes are associated with exhumation of ultramafic mantle wedge rocks within a serpentinized subduction channel close to the subducted slab in response to slab roll back in a long-lasting subduction regime. This study offers insights into magmatic and metasomatic processes of ultramafic rocks in the fore-arc mantle wedge which were exhumed and accreted to an active continental margin during the southward subduction of the Palaeo-Asian oceanic lithosphere beneath the NCC.  相似文献   

南盘江盆地中部西林断隆南翼中-下三叠统沉积学特征及其大地构造意义     

夏文静  闫全人  向忠金  夏磊  江文  卫巍  李晓剑  周斌 《岩石学报》2018,34(7):2119-2139

印支造山带对华南地质演化具有重要影响,南盘江盆地作为华南与印支造山带相关的最大的盆地,其构造演化过程备受关注,然而对于盆地由伸展到挤压的构造转换时限还存在争议。西林县位于南盘江盆地的中部,古生界和中-下三叠统出露良好,是进行沉积大地构造学研究的理想地区。为进一步明确南盘江盆地的构造演化过程,本文选取南盘江盆地中部西林县一带中-下三叠统进行了详细的沉积相分布和演化、古水流以及碎屑组成分析。结果表明,空间上,下三叠统自下而上自北向南依次出露:(1)泥岩、泥灰岩、砂屑灰岩和凝灰岩构成的潮坪-泻湖相沉积;(2)砾岩、含砾砂岩、细砂岩和粉砂岩构成的块体搬运沉积(MTD,Mass-transport deposit)与浊积扇相沉积互层;(3)中粗砂岩、粉砂岩、泥岩组成的浊积扇相沉积,构成向上水体急剧加深的沉积序列。中三叠统为一套浊积扇相沉积,由粗砂岩、细砂岩、粉砂岩和泥岩组成。古水流和碎屑组成分析结果显示,西林县一带下三叠统碎屑物主要来自北侧西林-隆林一带的碳酸盐岩台地,而中三叠统碎屑除来自北侧相邻碳酸盐岩台地外,还可能来自江南造山带、康滇古陆、云开地块和峨眉山玄武岩。沉积相的垂向变化记录了西林一带由古生代孤立碳酸盐岩台地向三叠纪半深海浊积岩盆地的演化过程,而早三叠世MTD是盆地张开过程中的直接沉积记录,以上地质事实暗示了南盘江盆地在早三叠世受控于区域伸展体制,西林一带的古生代孤立碳酸盐岩台地则是伸展过程中形成的断隆。盆地内的基性岩墙侵位(258~248Ma)以及西林一带早三叠世晶屑沉凝灰岩的锆石U-Pb年代学分析结果(249.4±1.2Ma)表明南盘江盆地在晚二叠世至早三叠世处于伸展构造背景之下,中三叠统为半深海浊积岩沉积则表明这一伸展过程至少持续至中三叠世。由于在时间上和空间上,南盘江盆地的张开都与古特提斯分支洋盆的俯冲消减有关,因而我们认为南盘江盆地也是晚二叠世到中三叠世古特提斯洋岩石圈俯冲体系的一部分。由于南盘江盆地及其邻近区缺失上三叠统沉积,这可能说明古特提斯洋俯冲结束于中三叠世。  相似文献   

西藏班公湖-怒江缝合带北缘多龙矿集区晚三叠世—侏罗纪增生杂岩结构及其对成矿地质背景的约束   总被引：10，自引：4，他引：6  

段志明  李光明  张晖  段瑶瑶 《地质通报》2013,32(5):742-750

西藏班公湖-怒江缝合带北缘多龙斑岩铜金矿集区出露的晚三叠世—体罗纪增生杂岩属总体无序、局部有序的非史密斯地层,由基质和块体2个部分组成.基质为晚三叠世—侏罗纪砂泥质复理石建造,块体由大小不等的玄武岩、安山玄武岩、灰岩、砂岩、硅质岩、辉长岩、超基性岩等组成.增生杂岩系变形强烈,发育强烈的构造置换作用,块体与基质之间由透入性挤压面理、剪切面理或韧性剪切断层分隔,为典型造山带大陆增生边缘的增生杂岩.多龙斑岩铜矿的含矿斑岩体侵位于侏罗纪增生杂岩系或以侏罗纪增生杂岩系为基底的岛弧型火山岩系中,属增生楔基础上发育的具有超大型潜力的岛弧型斑岩铜金矿床,其外围的拿若、色拉、拿顿、地保那木岗、鹫山、铁格龙和尕尔勤等系列铜金铅锌矿床点,在空间上均赋存于早白垩世花岗闪长斑岩体内部及其与侏罗纪增生杂岩系的内外接触带中,受矿集区北东向走滑断裂的控制,呈北东向成群展布,二者具有相似的成矿环境与成矿条件,其深部可能存在统一的斑岩型铜金铅锌矿床,属于统一的斑岩浅成低温热液成矿系统.班公湖-怒江缝合带北缘多龙矿集区晚三叠世—侏罗纪增生杂岩的识别,为正确认识多龙超大型斑岩铜金矿床的成矿地质背景和缝合带的演化提供了新的线索.  相似文献