Upper Maastrichtian deposits formed in a nearshore subtidal environment within the Valdenoceda Formation (Castilian Ramp, North Iberian margin) are described together with two recently found selachian assemblages. Rare earth element concentrations (REE) have been used to assess the degree of taphonomic mixing and reworking, observing that it is minor or non-existent, and differences in degree of preservation and ecologic mixing can be explained by biostratinomic processes. The patterns of REE also helped to obtain a better understanding of the depositional environment, including the diagenetic history from burial to final degree of bone preservation.The fossil assemblages here described are close to that of the late Maastrichtian of Albaina (in the enclave of Condado de Treviño, Burgos), both in the Basque-Cantabrian Region, but their age may be slightly older (early late Maastrichtian). In total, the new assemblages consist of 17 taxa, assigned to 11 genera of shallow-water dwellers combined with individuals from the outer shelf. They represent cosmopolitan taxa (Squalicorax pristodontus, Serratolamna serrata and Rhombodus binkhorsti) together with local species (Rhinobatos echavei, Rhinobatos ibericus). Although there are not significant differences between Albaina and Quintanilla la Ojada faunas, the new assemblages add interesting taphonomic and geochemical information to the few existing uppermost Cretaceous deposits with fossil sharks in southwestern Europe. 相似文献
The Amazonian Craton hosts world-class metallogenic provinces with a wide range of styles of primary precious, rare, base metal, and placer deposits. This paper provides a synthesis of the geological database with regard to granitoid magmatic suites, spatio temporal distribution, tectonic settings, and the nature of selected mineral deposits. The Archean Carajás Mineral Province comprises greenstone belts (3.04–2.97 Ga), metavolcanic-sedimentary units (2.76–2.74 Ga), granitoids (3.07–2.84 Ga) formed in a magmatic arc and syn-collisional setting, post-orogenic A2-type granites as well as gabbros (ca. 2.74 Ga), and anorogenic granites (1.88 Ga). Archean iron oxide-Cu-Au (IOCG) deposits were synchronous or later than bimodal magmatism (2.74–2.70 Ga). Paleoproterozoic IOCG deposits, emplaced at shallow-crustal levels, are enriched with Nb–Y–Sn–Be–U. The latter, as well as Sn–W and Au-EGP deposits are coeval with ca. 1.88 Ga A2-type granites. The Tapajós Mineral Province includes a low-grade meta-volcano-sedimentary sequence (2.01 Ga), tonalites to granites (2.0–1.87 Ga), two calc-alkaline volcanic sequences (2.0–1.95 Ga to 1.89–1.87 Ga) and A-type rhyolites and granites (1.88 Ga). The calc-alkaline volcanic rocks host epithermal Au and base metal mineralization, whereas Cu–Au and Cu–Mo ± Au porphyry-type mineralization is associated with sub-volcanic felsic rocks, formed in two continental magmatic arcs related to an accretionary event, resulting from an Andean-type northwards subduction. The Alta Floresta Gold Province consists of Paleoproterozoic plutono-volcanic sequences (1.98–1.75 Ga), generated in ocean–ocean orogenies. Disseminated and vein-type Au ± Cu and Au + base metal deposits are hosted by calc-alkaline I-type granitic intrusions (1.98 Ga, 1.90 Ga, and 1.87 Ga) and quartz-feldspar porphyries (ca. 1.77 Ga). Timing of the gold deposits has been constrained between 1.78 Ga and 1.77 Ga and linked to post-collisional Juruena arc felsic magmatism (e.g., Colíder and Teles Pires suites). The Transamazonas Province corresponds to a N–S-trending orogenic belt, consolidated during the Transamazonian cycle (2.26–1.95 Ga), comprising the Lourenço, Amapá, Carecuru, Bacajá, and Santana do Araguaia tectonic domains. They show a protracted tectonic evolution, and are host to the pre-, syn-, and post-orogenic to anorogenic granitic magmatism. Gold mineralization associated with magmatic events is still unclear. Greisen and pegmatite Sn–Nb–Ta deposits are related to 1.84 to 1.75 Ga late-orogenic to anorogenic A-type granites. The Pitinga Tin Province includes the Madeira Sn–Nb–Ta–F deposit, Sn-greisens and Sn-episyenites. These are associated with A-type granites of the Madeira Suite (1.84–1.82 Ga), which occur within a cauldron complex (Iricoumé Group). The A-type magmatism evolved from a post-collisional extension, towards a within-plate setting. The hydrothermal processes (400 °C–100 °C) resulted in albitization and formation of disseminated cryolite, pyrochlore columbitization, and formation of a massive cryolite deposit in the core of the Madeira deposit. The Rondônia Tin Province hosts rare-metal (Ta, Nb, Be) and Sn–W mineralization, which is associated with the São Lourenço-Caripunas (1.31–1.30 Ga), related to the post-collisional stage of the Rondônia San Ignácio Province (1.56–1.30 Ga), and to the Santa Clara (1.08–1.07 Ga) and Younger Granites of Rondônia (0.99–0.97 Ga) A-type granites. The latter are linked to the evolution of the Sunsás-Aguapeí Province (1.20–0.95 Ga). Rare-metal polymetallic deposits are associated with late stage peraluminous granites, mainly as greisen, quartz vein, and pegmatite types. 相似文献
The Esino Limestone of the western Southern Alps represents a differentiated Ladinian-Lower Carnian (?) carbonate platform comprised of margin, slope and peritidal inner platform facies up to 1000 m thick. A major regional subaerial exposure event lead to coverage by another peritidal Lower Carnian carbonate platform (Breno Formation). Multiphase dolomitization affected the carbonate sediments. Petrographic examinations identified at least three main generations of dolomites (D1, D2, and D3) that occur as both replacement and fracture-filling cements. These phases have crystal-size ranges of 3–35 μm (dolomicrite D1), 40–600 μm (eu-to subhedral crystals D2), and 200 μm to 5 mm (cavity- and fracture-filling anhedral to subhedral saddle dolomite D3), respectively.The fabric retentive near-micritic grain size coupled with low mean Sr concentration (76 ± 37 ppm) and estimated δ18O of the parent dolomitizing fluids of D1 suggest formation in shallow burial setting at temperature ∼ 45–50 °C with possible contributions from volcanic-related fluids (basinal fluids circulated in volcaniclastics or related to volcanic activity), which is consistent with its abnormally high Fe (4438 ± 4393 ppm) and Mn (1219 ± 1418 ppm) contents. The larger crystal sizes, homogenization temperatures (D2, 108 ± 9 °C; D3, 111 ± 14 °C) of primary two-phase fluid inclusions, and calculated salinity estimates (D2, 23 ± 2 eq wt% NaCl; D3, 20 ± 4 eq wt% NaCl) of D2 and D3 suggest that they formed at later stages under mid-to deeper burial settings at higher temperatures from dolomitizing fluids of higher salinity, which is supported by higher estimated δ18O values of their parent dolomitizing fluids. This is also consistent with their high Fe (4462 ± 4888 ppm; and 1091 ± 1183 ppm, respectively) and Mn (556 ± 289 ppm and 1091 ± 1183 ppm) contents, and low Sr concentrations (53 ± 31 ppm and 57 ± 24 ppm, respectively).The similarity in shale-normalized (SN) REE patterns and Ce (Ce/Ce*)SN and La (Pr/Pr*)SN anomalies of the investigated carbonates support the genetic relationship between the dolomite generations and their calcite precursor. Positive Eu anomalies, coupled with fluid-inclusion gas ratios (N2/Ar, CO2/CH4, Ar/He), high F− concentration, high F/Cl and high Cl/Br molar ratios suggest an origin from diagenetic fluids circulated through volcanic rocks, which is consistent with the co-occurrence of volcaniclastic lenses in the investigated sequence. 相似文献
A large, euhedral crystal of fluorapatite (ca. 19.5 × 20.0 mm) from the Panasqueira tin-tungsten deposit (Portugal) was investigated in terms of the distribution of trace elements by using several microanalytical techniques. The studied material represents almost pure fluorapatite with minor amounts of other cations (mainly Sr, Mn, REE and Fe), OH and Cl. Particular interest was given to the distribution of rare earth elements with respect to the crystallographic orientation. A broad range of analytical techniques were used, including optical microscopy coupled with cathodoluminescence imaging, electron probe microanalysis (EPMA), laser ablation – inductively coupled plasma mass spectrometry (LA-ICPMS), Raman microspectroscopy, and simultaneous thermal analysis coupled with mass spectrometry. The investigated crystal consists of the main crystal with a distinct core and rim (Ap2core and Ap2rim, respectively), which grew on a previous, euhedral crystal (Ap1). The fluorapatite demonstrates various types of zoning: regular oscillatory, irregular, and internal sectoring, which is also reflected in trace elements concentrations. The rim Ap2rim has lower concentrations of Mn, Sr and Fe, and significantly higher concentrations of REE compared to the core Ap2core and older crystal Ap1. Furthermore, the rim Ap2rim is strongly depleted in Th, U and Pb. The entire crystal shows elevated Eu contents, expressed as a strong positive anomaly in chondrite-normalized REE patterns. With regards to the volatiles, F concentrations are constant in Ap1, Ap2core and Ap2rim, whereas Cl is below the EPMA detection limit. The Ap2rim was the only part of the investigated material containing OH and CO3, which were observed in the Raman spectra. Furthermore, part of the crystal Ap2core is extensively altered, likely due to fluid-induced metasomatic processes. LA-ICPMS U-Pb dating yielded highly discordant dates due to common Pb content. A lower intercept age of 297 ± 13 Ma (MSWD = 0.13) indicates the age of the fluorapatite crystallization. The overall analytical data constrain growth and post-growth processes, including crystallization of Ap1 and Ap2core, which both have typical hydrothermal Sn-W deposit characteristics, whereas Ap2rim is related to a carbonate stage of the mineralization in the Panasqueira deposit. 相似文献
Strong and rapid greenhouse gas (GHG) emission reductions, far beyond those currently committed to, are required to meet the goals of the Paris Agreement. This allows no sector to maintain business as usual practices, while application of the precautionary principle requires avoiding a reliance on negative emission technologies. Animal to plant-sourced protein shifts offer substantial potential for GHG emission reductions. Unabated, the livestock sector could take between 37% and 49% of the GHG budget allowable under the 2°C and 1.5°C targets, respectively, by 2030. Inaction in the livestock sector would require substantial GHG reductions, far beyond what are planned or realistic, from other sectors. This outlook article outlines why animal to plant-sourced protein shifts should be taken up by the Conference of the Parties (COP), and how they could feature as part of countries’ mitigation commitments under their updated Nationally Determined Contributions (NDCs) to be adopted from 2020 onwards. The proposed framework includes an acknowledgment of ‘peak livestock’, followed by targets for large and rapid reductions in livestock numbers based on a combined ‘worst first’ and ‘best available food’ approach. Adequate support, including climate finance, is needed to facilitate countries in implementing animal to plant-sourced protein shifts.
Key policy insights
Given the livestock sector’s significant contribution to global GHG emissions and methane dominance, animal to plant protein shifts make a necessary contribution to meeting the Paris temperature goals and reducing warming in the short term, while providing a suite of co-benefits.
Without action, the livestock sector could take between 37% and 49% of the GHG budget allowable under the 2°C and 1.5°C targets, respectively, by 2030.
Failure to implement animal to plant protein shifts increases the risk of exceeding temperate goals; requires additional GHG reductions from other sectors; and increases reliance on negative emissions technologies.
COP 24 is an opportunity to bring animal to plant protein shifts to the climate mitigation table.
Revised NDCs from 2020 should include animal to plant protein shifts, starting with a declaration of ‘peak livestock’, followed by a ‘worst first’ replacement approach, guided by ‘best available food’.