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991.
Immature Torbanite and the resistant biopolymer (PRB A) isolated from extant B. braunii were previously compared using bulk spectroscopic methods. In the present work, analysis of 400°C pyrolysis products and pyrolysis residues provided further information on their structure and possible relationships. It appears that such polymers are based upon unbranched, saturated, cross-linked hydrocarbon chains up to C31. In addition to these bridging structures, a substantial part of the alkyl chains is singly bound, as esters of unbranched, saturated or cis unsaturated, even fatty acids. These esters are sterically protected, against chemical degradations, by the network of the bioand geopolymer.Quantitative and qualitative observations derived from 400°C pyrolysis confirm that the chemical structure of PRB A and immature Torbanite are closely related. The pyrolysis residues show a similar evolution and numerous common features are noted, with respect to the nature and the distribution of the major constituents of the pyrolysates (hydrocarbons and fatty acids). Accordingly, Botryococcus provides what seems to be the first example of a close structural relationship between a biopolymer produced in large amounts by an extant alga and the geopolymer of an immature kerogen. The essential role of PRB A in Torbanite formation is ascertained. Moreover, it is found that the resistant biopolymer does not undergo important structural changes during the first stages of diagenesis. Thus, owing to steric protection, the esters of immature Torbanite show a distribution quite close to the one of PRB A esters, with exclusively even constituents and a large contribution of unsaturated acids.Recent observations pointed to the possible genesis of some algal kerogens principally by selective preservation of resistant macromolecules. Such a type of formation is clearly predominant in Torbanite, where the bulk of the fossil organic matter corresponds to a selectively preserved and weakly altered, resistant biopolymer, while incorporation of lipids into the kerogen structure during diagenesis seems to play a minor role. 相似文献
992.
本文介绍带电收集片测定土等粉末样品的 Ra 含量来找 U 矿的方法,称为 Ra 法。此法灵敏度高,操作简便,成本低,可以使用~(210)Po 法曲仪器和铜片,便于推广使用。文中介绍了测 Ra 流程,测定误差和灵敏度.Ra 法在详查和区调阶段的用途。总结了深部盲矿、地表矿化和非矿异常地段上地表的 Ra、Po 和γ异常的特征,指明 Ra 法和 Po 法结合可用于评价异常,提高找深部铀矿的能力。 相似文献
993.
994.
995.
Recent evaluations of acute and chronical toxicity of arsenic resulted in a reduction of the standard value for total arsenic from 40 μg/L to 10 μg/L in drinking water which will be valid in Germany after a transition period as from January 1996. Arsenic is well known as substance of deep groundwaters, mainly of geogenic origin and normally found as As(III) or As(V). As(V) is well removable by flocculation and filtration after adding iron salts. As(III), however, has to be oxidized first to As(V). Therefore, it is important for treatment techniques to be able to distinguish between As(III) and As(V). A modified determination of As(III) using flow injection analysis was installed and optimized in order to investigate whether As(III) may be oxidized to As(V) by bacteria in natural waters. The results showed that at 4°C, no As(III)-oxidation was observed within 14 days. At room temperature, however, in the bacteria-containing samples, an As(III)-oxidation was found starting after 3 to 7 days. After 14 days, no As(III) was left over. In contrast, in the sterile samples, no As(III)-oxidation could be observed within 14 days. These results demonstrated that microbial processes influence the oxidation of As(III) to As(V) in natural waters. 相似文献
996.
The sensitive and selective determination of polyalcohols without chromophores or fluorophores in the lower ppb-level is still an analytical task of high interest, especially in the field of environmental investigations. This paper describes a cation-exchange HPLC procedure for the separation and fluorescence detection of two quaternary ammonium compounds with polyalcoholic groups (degradation products of fabric softener) after derivatization with 9-fluorenylmethyl chloroformate (FMOC). Detailed experiments were carried out to determine optimum reaction conditions (pH, reaction time, temperature), linear range, detection limits, and kinetics of the reaction. The HPLC separation on a cation-exchange column includes a gradient program which provides complete separation from neutral compounds also reacting with FMOC and its hydrolysis products formed during the reaction in alkaline medium. High specificity for both investigated ammonium compounds with detection limits in the range of 1 ppb could be achieved. 相似文献
997.
陕西境内的陶湾群和大片出露的寒牙纪地层之间,发育一套以千枚岩夹白云岩透镜体为主的复杂岩系。这套岩系实际上构成一个剪切混杂带,成为秦岭造山带和华北地台的界线,该带不是一个沉积地层单位,而应视为岩石-构造组合体,带内发育一系列冲断层,在洛南柏峪寺地区,从中可以分出3个构造岩片,其中的白云岩岩块为构造岩块。根据显微,小构造分析及岩性对比,认为冲断层由北向南逆冲,带内至少卷入有晚元古代大庄组,震旦纪罗圈组 相似文献
998.
通过龙门山区和川西前陆盆地岩石样品的裂变径迹和镜质体反射率的测定和计算机模拟得出:1)松潘-甘孜褶皱带10Ma以来至少隆升了3-4km,隆升速率最低为0.3-0.4mm/a;(2)龙门山逆冲推覆构造带10Ma以来至少隆升了5-6km,隆升速率最低为0.016-0.032mm/a;(4)川西前陆盆地60Ma以来降升1-2km,降升速率为0.028-0.05mm/a;(5)10Ma以来北川-映秀-小关 相似文献
999.
福建紫金山铜(金)矿与台湾金瓜石金(铜)矿的对比及其意义 总被引:5,自引:0,他引:5
福建西部的紫金山铜(金)矿与台湾北部的金(铜)矿其矿床(田)的很多特征十分相似,成矿的物理化学条件也很类同,表明其成矿作用在本质上是相同的,二者可以对比。依此为基础能够建立起一个综合性的有关火山/潜火山热液-斑岩成矿系到的两阶段三层模式。此模式环太平洋地区中、新生代火山活动地区类似床具有启示意义。 相似文献
1000.
本文研究了以磷酸三丁酯为固定相,大孔聚乙烯苯(X-5型)为担体的浸渍树脂、垂直型反相色谱柱,对铀分离富集的基本性能,以及铀(Ⅳ)-间硝基苯基萤光酮(m-NPF)一氨三乙酸(NTA)-吐温-80显色体系的反应条件,提出了TBP(X-5)分离,m-NPF-NTA-吐温-80光度法测定铀,经标准样品验证,结果满意。 相似文献