Environmental monitoring of magnetic iron phases of urban water reservoir lake sediments (Taiaçupeba Lake,metropolitan region of São Paulo,Brazil) by using Mössbauer spectroscopy     

D. R. Franco  T. S. Berquó  R. A. L. Imbernon  C. S. M. Partiti  J. Enzweiler 《Environmental Geology》2007,52(5):831-842

In the present work, we investigate the iron oxides and oxyhydroxides behavior and evolution, related to the geochemical behavior of some metals, which could be retained as solid phases in the sediments from an urban water reservoir lake, placed in Taiaçupeba, Great São Paulo, Brazil. These tasks were performed by the establishment of a proceduring setting for environmental monitoring analysis through Mössbauer spectroscopy measurements associated to hysteresis loops measurements and chemical analysis [X-ray fluorescence (XRF)]. We inferred the possibility of goethite occurrence in broad particle size distribution (5–50 nm), and related to ferrihydrite, and small grain-size hematite (about 8 nm). The magnetometry results pointed to the paramagnetic/superparamagnetic behavior of the magnetic phases present in the samples and also suggested the occurrence of small grain-size magnetite. We also verified the presence of clay minerals related to Fe, as well as the occurrence of Fe³⁺ and/or Fe²⁺ in short-range structural order. Through a straight correlation among Mössbauer spectra data gained at T = 77 K and Al-metal, metal-Fe molar ratios, provided through XRF data, we found remarkable indications of interference on meta-stable phases evolution to its final products. Such results can be pointing for evidences about the possible isomorphic replacing and/or adsorption of Al and other metals in goethite and hematite.  相似文献   

盐度对镭同位素在海南红树林沉积物解吸行为的影响   总被引：1，自引：0，他引：1  

谷河泉  赵峰  季韬  温廷宇  张经  杜金洲 《海洋与湖沼》2015,46(1):65-76

天然放射性镭同位素在沉积物上的解吸行为是影响其在陆-海交换过程中的关键所在。采用沉积物室内解吸实验和现场采集间隙水测量224Ra含量两种方法,对水体盐度梯度控制镭在海南八门湾红树林沉积物的解吸行为进行了讨论。结果表明:沉积物上可交换态224Ra的最大量为0.44dpm/g,解吸比为35%。利用间隙水的224Ra含量确定镭的分配比Kd与水体盐度S呈反比例函数:Kd=8.4×102/S,与室内解吸实验的结果相比更能代表镭在沉积物上的真实解吸行为。在深度25—40cm内,湿地沉积物的224Ra处于与其母体228Th的平衡状态,但223Ra很可能处于相对其母体227Th亏损状态。  相似文献   

基于ECOMSED 模型的湛江湾水道三维潮流数值模拟   总被引：1，自引：0，他引：1  

赵婉璐  郝瑞霞 《海洋科学》2015,39(4):82-86

采用半隐式的ECOMSED(Estuarine,Coastal and Ocean Modeling System with Sediments)三维海洋紊流模式,建立湛江湾湾顶水道的三维潮流数值模型。模型的水平方向采用加密的正交网格以贴合岸线边界,垂向上采用σ坐标以更好地拟合海底地形。通过验证,模拟结果与实测数据符合良好,表明运用该模型可以较好地预报湛江湾的潮流动力特性。为进一步研究湛江湾水道附近水域的温盐变化、泥沙输运提供技术支持。  相似文献   

Molecular and stable carbon isotopic characterization of PAH contaminants at McMurdo Station, Antarctica     

Kim M  Kennicutt MC  Qian Y 《Marine pollution bulletin》2006,52(12):1585-1590

The molecular and stable carbon isotopic compositions of contaminant polycyclic aromatic hydrocarbons (PAHs) at McMurdo Station, Antarctica were analyzed in samples collected from land and sub-tidal area. PAHs in the study areas were characterized by high amounts of naphthalene and alkylated naphthalenes from petroleum products introduced by human activities in the area. Principal component analysis (PCA) of PAH composition data identified multiple sources of PAH contamination in the study area. Compositional assignments of origins were confirmed using compound specific stable carbon isotopic analysis.  相似文献   

The Comparison of Sediment Contamination in the Area of Estuary and the Lower Course of the Odra Before and After the Flood of Summer 1997     

M. Protasowicki  E. Niedz?agwiecki  W. Ciereszko  A. Perkowska  E. Meller 《洁净——土壤、空气、水》1999,27(5):338-342

The concentration of heavy metals (Hg, Cd, Pb, Cu, Zn, Cr, Ni, Mn) and chloroorganic substances (γ-HCH, ΣDDT, PCB) in surface sediments of the Western and the Eastern Odra River was analyzed after the 1997 flood and compared with data from 1995. The research has shown that, like in 1995, the Western Odra sediments were more contaminated with heavy metals and PCBs than the Eastern Odra ones. In comparison with the state of 1995, after the flood in both arms of the Odra, the amount of Cr, Mn, and PCBs has increased while the amount of Pb concentration decreased. The levels of Cd, Zn, and Ni have remained unchanged. The changes of the other pollutants were not so clear. The concentration of Hg and Cu increased in the Western Odra, while it decreased in the Eastern Odra; changes of γ-HCH and ΣDDT content were inverted.  相似文献   

Trends und Verteilungsmuster in der Schadstoffbelastung von Sedimenten aus östlichen Bundeswasserstraßen     

P. Heininger  J. Pelzer 《洁净——土壤、空气、水》1998,26(4):218-225

Trends and Patterns in the Contamination of Sediments from Federal Waterways in Eastern Germany The following study presents a concept for a sediment pollution cadastre and the results of systematic investigations of sediment contamination for eight toxic heavy metals and arsenic, as well as for eight classes of organic priority pollutants in all together 21 reaches in the Elbe and Oder waterway systems. Based on data from the years 1991 to 1995; multivariate statistical evaluations were carried out to identify local and temporal trends in the overall contamination. It was possible to differentiate between more non-point and point sources of sediment contamination. Because of the closure of substantial parts of the industry in Eastern Germany and by common sanitation efforts of both the German and the Czech sides since 1990, the situation in the Elbe river system with respect to the heavy metals has improved markedly. For the Oder river system, a comparable trend does not exist yet, and the sediment contamination by heavy metals is stagnant there. As a consequence, the pollution situation in both German parts of the rivers has become similar except for mercury and arsenic. Regarding organic pollutants, the picture is quite different. With the exception of PAHs, Oder sediments are contaminated by organics only to a lower extent and compare better with the ones from unpolluted waters found in parts of Brandenburg and Mecklenburg-Western Pomerania than with those of rivers Elbe, Mulde, and Saale with its tributaries. On the one hand, organic pollution generally also decreased since 1991 in these rivers. On the other hand, due to continuing inputs from plants in the Czech Republic and from old contaminated sites, both in Czechia and Germany, a decreasing trend is not significant or cannot be found at all for such pollutants as HCB, PCBs, or PAHs. The general trends are discussed in detail, e.g., by comparison with quality targets for sediments and suspended matter, and illustrated at the example of individual contaminants being typical for the overall situation.  相似文献   

Discovery and exploration of the Gosowong epithermal gold deposit, Halmahera, Indonesia   总被引：1，自引：0，他引：1  

J. C. Carlile  G. R. Davey  I. Kadir  R. P. Langmead  W. J. Rafferty 《Journal of Geochemical Exploration》1998,60(3):207-227

The Gosowong epithermal gold deposit, on the island of Halmahera in eastern Indonesia, is located in an area of primary tropical rain forest with no previous history of gold mining or record of gold mineralisation. The deposit occurs in a newly recognised mineral district which contains a number of epithermal vein systems and at least two centres of low-grade porphyry style Cu–Au mineralisation. Several zones of argillic and advanced argillic alteration have been noted which may be related to additional centres of mineralisation. Gosowong is classified as a low-sulphidation epithermal quartz vein. Bonanza-grade gold–silver mineralisation is developed in shoots over a 400-m strike section of the vein system. Three types of veining are recognized; quartz–adularia veins and breccias; quartz–chlorite–illite veins and breccias; and crystalline or chalcedonic quartz vein stockworks. The area was targetted using a simple geological concept and the deposit was discovered and tested using basic exploration techniques commonly applied in the rugged tropical terrains of Indonesia. Sequential exploration methods comprised reconnaissance drainage sampling of stream sediment, BLEG and float media, ridge and spur soil sampling, prospect scale grid soil sampling, hand trenching and diamond drilling. Lapse time from identification of the initial reconnaissance anomaly to an inferred resource estimate of almost 1 million ounces of gold was less than 3.5 years. This case history illustrates that very detailed exploration is necessary to locate high-grade vein-type gold deposits in a tropical environment, but demonstrates that such resources still remain to be discovered in the relatively under-explored Neogene magmatic arcs of Indonesia.  相似文献   

不同岩性盐湖沉积物中挥发性有机质的特征          下载免费PDF全文

卢晓航  韩凤清  易磊  马喆  张光武  陈富洪 《盐湖研究》2021,29(1):18-24

通过不同岩性盐湖沉积物中C/N值,确定其有机质的来源均为藻类,然后采用气相色谱—离子迁移谱(GC-IMS)联用技术对不同岩性盐湖沉积物中的挥发性有机质进行了研究.结果显示,不同岩性沉积物的挥发性有机质虽然来源相同,但是其种类和含量存在显著差异.在砂岩沉积物中,检测出16种挥发性有机质,而石盐中共检测出30种挥发性有机质...  相似文献   

黄河与长江入海沉积物中碳酸盐含量和矿物颗粒形态特征及影响因素   总被引：1，自引：0，他引：1       下载免费PDF全文

杨作升  王海成  乔淑卿 《海洋与湖沼》2009,40(6):674-681

利用X射线物相分析、扫描电镜及能谱分析等方法分析了长江和黄河入海沉积物矿物颗粒形态特征及不同粒级的碳酸盐矿物百分含量分布。结果表明,长江和黄河入海沉积物的碳酸盐矿物含量均在9%左右,差异不大。长江碳酸盐矿物含量在粗粒级较高,随着粒度变细波动式降低,黄河碳酸盐矿物含量则随粒度变细而逐步增加;黄河方解石含量高而白云石低,长江的情况正好相反。长江和黄河入海沉积物中的白云石颗粒大多比较完整,侵蚀沿完全解理面发生,菱面体形态明显。长江白云石上可以见到大量的磨蚀和溶蚀形态。黄河白云石保存较好,侵蚀程度较低,磨蚀和碰撞形态明显,溶蚀形态很少,发现典型的马鞍状白云石颗粒。长江和黄河的方解石均遭受强烈侵蚀。长江方解石溶蚀特征特别明显,深入矿物颗粒内部。黄河方解石侵蚀深度相对浅表,侵蚀形态多为磨蚀、碰撞和溶蚀等物理和化学综合侵蚀特征。长江某些方解石表面布满细小鲕状方解石颗粒,似为局部自由空间的胶体-陈化成因特征。黄河方解石呈现多个次生微晶集合体,显示其黄土粘粒空隙胶结物成因形态。碳酸盐矿物的菱面体形态和菱面体完全解理所特有的60°和120°交角,是其电镜下的最佳识别特征。长江和黄河沉积物物源、流域风化强度以及矿物晶体结构本身的特...  相似文献