生物气CO_2还原途径中碳同位素分馏作用研究及应用   总被引：2，自引：0，他引：2  

李谨  胡国艺  张英  杨贵芳  崔会英  曹宏明  胡须龙 《地学前缘》2008,15(5):357

地质历史中,CO2/H2还原产甲烷作用对生物气的形成具有十分重要的意义。中国柴达木盆地第四系生物气主要为CO2/H2还原型生物气。笔者以CO2/H2还原生气理论为指导,进行不同初始碳同位素值和不同赋存状态碳源的生物模拟实验,研究CO2/H2还原产气过程中发生的碳同位素分馏作用。实验结果表明,产物中δ13CH4值与底物的δ13C值呈很好的正相关关系;在反应母质过量的情况下,碳源的赋存状态可以影响产物甲烷的碳同位素组成。以游离形式CO2还原产生的甲烷δ13C值,相对于以HCO3-、CO23-离子形式产生的甲烷δ13C值轻。通过柴达木盆地东部第四系生物气田实例分析,探讨了该区生物气的主要底物CO2的来源及赋存状态,对评价盆地生物气资源和有利勘探区预测有重要的参考价值。  相似文献   

首都减灾圈的思考与建议     

张少泉  吕庆书 《地震》1993,(5):47-61

首都减灾圈,系首都减轻自然灾害预测防治圈。1991年12月20—21日在北京召开了《首都圈自然灾害及其减灾对策研讨会》。本文根据这次会议所提供的材料,在从整体上实现减灾的思想指导下,就首都减灾圈的“成灾背景”、“首都减灾圈的组成”、“首都减灾圈的灾害预测与防治状况”、“首都减灾圈的灾害关联性分析”、“首都减灾圈的减灾实效预估”和“首都减灾圈的减灾对策与实施”等六个带有共同性的问题,进行了讨论。供制定首都圈减灾方案时参考。  相似文献   

基于遥感影像大数据、卷积神经网络的福建省有效致灾雷电分布模型及应用     

张烨方  刘冰  冯真祯  朱彪 《气象科技》2021,49(6):953-959

为了研究福建省有效致灾雷电的分布情况，基于福建省2004—2012年闪电定位数据及雷击人员伤亡数据、福建省L17级谷歌遥感影像瓦片，引入卷积神经网络模型对遥感影像所在区域是否属于人员活动的属性进行建模、训练和预测，得到福建省人员活动属性的格点产品，结合福建省历史雷电数据对有效致灾的雷电分布情况进行了分析，结果表明：①设计的遥感影像+CNN识别模型具有一定的可行性和准确率，通过显著性水平为0.01的假设检验；②福建省有63.55%的格点为无人员活动区域；③平均有45.36%的闪电落在无人员活动的区域，因地制宜地对其他致灾闪电进行预警是提高应急减灾服务效果的可行途径；④有效致灾雷电密度与历史雷击人员伤亡数据的相关性远大于常规雷电密度与历史雷击人员伤亡数据的相关性，有效致灾雷电分布在表征雷电灾害上比常规雷电分布更具有指示意义。  相似文献   

Low temperature volatile production at the Lost City Hydrothermal Field, evidence from a hydrogen stable isotope geothermometer   总被引：1，自引：0，他引：1  

Giora Proskurowski  Marvin D. Lilley  Deborah S. Kelley  Eric J. Olson 《Chemical Geology》2006,229(4):331-343

Although commonly utilized in continental geothermal work, the water-hydrogen and methane-hydrogen isotope geothermometers have been neglected in hydrothermal studies. Here we report δD-CH₄ and δD-H₂ values from high-temperature, black smoker-type hydrothermal vents and low-temperature carbonate-hosted samples from the recently discovered Lost City Hydrothermal Field. Methane deuterium content is uniform across the dataset at − 120 ± 12‰. Hydrogen δD values vary from − 420‰ to − 330‰ at high-temperature vents to − 700‰ to − 600‰ at Lost City. The application of several geothermometer equations to a suite of hydrothermal vent volatile samples reveals that predicted temperatures are similar to measured vent temperatures at high-temperature vents, and 20-60 °C higher than those measured at the Lost City vents. We conclude that the overestimation of temperature at Lost City reflects 1) that methane and hydrogen are produced by serpentinization at > 110 °C, and 2) that isotopic equilibrium at temperatures < 70 °C is mediated by microbial sulfate reduction. The successful application of hydrogen isotope geothermometers to low-temperature Lost City hydrothermal samples encourages its employment with low-temperature diffuse hydrothermal fluids.  相似文献   

Impact of Changes in Redox Conditions on Leaching of Some Elements from MSW Fly Ash     

Lallan Prasad Gupta    Hodaka Kawahata    Mio Ltakeuchi  Hidekazu Ohta  Yoshiro Ono 《Resource Geology》2006,56(2):191-196

Abstract. Oxidation and reduction processes can influence extent of leaching of elements from solid waste. Three samples of municipal solid waste combustion fly ash were subjected to oxidizing and reducing conditions in order to evaluate leaching of elements in the Milli-Q water and fly ash (liquid to solid ratio, 100) mixtures. Although the oxidizing and reducing conditions were applied for 6 hours only, elements like Cs, Li, Mg, Sb, Tl and V leached more under oxidizing condition than under reducing condition in the case of all three ash samples. Cadmium, Pb and Zn leached more from all samples under reducing condition than under oxidizing condition. Leaching of other elements like Al, Ba, Cr, Cu, Ni and Rb was inconsistent with oxidizing or reducing conditions and varied from sample to sample, suggesting that factors other than redox may be more important in controlling leaching of these elements. Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions.  相似文献   

Speciation of sulfate components in size-fractionated aerosol particles using sulfur K-edge X-ray absorption near-edge structure （XANES）     

Yoshio Takahashi Yutaka Kanai Hikari Kamioka Atsuyuki Ohta Takuro Miyoshi Hiroshi Shimizu 《中国地球化学学报》2006,25(B08):222-222

Sulfates are a main constituent of aerosols, which sulfate aerosols, it is necessary to determine what can cause various environmental problems sulfate ions are contained in these aerosols In the evaluation of the influence of In this study, sulfur K-edge XANES was used to determine sulfate species present in size-fractionated aerosol particles based on the post-edge structure after the main absorption peak in the XANES region. Aerosol samples were collected as part of the Japan-China joint project, ＂Asian Dust Experiment on Climate Impact＂ using a low-volume Andersen-type air sampler. XANES was measured at Beamline BL-9A at Photon Factory, Japan. A comparison of the XANES spectra of reference sulfate materials and aerosol samples collected in Tsukuba in Japan clearly showed that （NH4）2SO4 was the main sulfur species in particles with a smaller diameter and gypsum was the main sulfur species in particles with a larger diameter. A simulation of the XANES spectra by reference materials allows us to obtain the quantitative mixing ratios of the different sulfate species present in the aerosol samples. The presence of minor sulfur species other than （NH4）2SO4 and gypsum at the surface of mineral aerosols is suggested in our simulations and by a surface-sensitive conversion electron/He-ion yield XANES. In the absence of a contribution from a large dust event, the mole concentration of gypsum in the mineral aerosol fraction determined by XANES is similar to that of Ca which is determined independently using ion chromatography. This shows that the Ca and sulfate in the mineral aerosols are present only as gypsum. Considering that calcite is the main Ca mineral in the original material arising from an arid and semi-arid area in China, it is strongly suggested that gypsum is formed in aerosol during its long-range transportation by a reaction between calcite and sulfate ions.  相似文献   

用强度折减法和FLAC^3D计算边坡的安全系数   总被引：4，自引：0，他引：4  

李新坡陈永波  王永杰何思明 王成华 《山地学报》2006,24(B10):235-239

对采用强度折减法和FLAC^3D计算边坡的安全系数问题进行了研究。对边坡破坏的判断标准、边坡滑面位置的确定及计算参数对安全系数计算结果的影响进行了分析。结果表明，用FLAC计算时，边坡的破坏可以通过节点最大不平衡力突变、节点最大速度突变、特定点位移的不收敛等特征进行判断，同时边坡破坏的滑面也可以由速度等值线图等方法表示出来。另外，通过分析发现，弹性常数、剪胀角等参数对安全系数计算结果的影响不大。  相似文献   

湿地生态系统碳循环过程及碳动态模型     

仝川  曾从盛 《福建地理》2006,(3)

从地上、地下有机物质生产对湿地碳输入的贡献,湿地土壤碳库以及土地利用变化对湿地土壤碳库和碳排放的影响,甲烷排放和可溶性有机碳输出以及影响因子,湿地生态系统碳循环动态模型4个方面对湿地生态系统碳循环国内外研究进展和研究成果进行综述、分析,提出了我国亚热带区域天然湿地碳循环研究的主要热点和方向:⑴沿海湿地碳库估算及土地利用转化对土壤碳库和温室气体排放的影响;⑵酸沉降对于我国东南沿海低纬度地区湿地甲烷排放的影响;⑶沿海湿地生态系统碳循环动态模型的应用与开发;⑷湿地系统可溶性有机碳的输出机理探讨.  相似文献   

RTK在大比例尺地形图航测数字化测图中的应用   总被引：3，自引：0，他引：3  

苏衍坤 王瑞薛志宏  赵亚蓓 《测绘学院学报》2005,22(3):191-193

结合某开发区1：2000地形图航测数字化测图工程，探讨了采用GPSRTK的自由基站二步法拟合方式测量航外像控点（平高点），实施大比例尺地形图野外检测的可行性。对比测量实验表明，该方式在像控点要求的特定位置不仅能保证平面精度，也可以保证高程精度；与常规的RTK相比，该方式具有基站设置位置灵活、不需单独提前解算基准转换参数，以及显著提高工效等优点。  相似文献   

InSAR系列讲座4InSAR数据处理及关键算法   总被引：1，自引：0，他引：1  

刘国祥 《四川测绘》2005,28(1):45-47

作为InSAR系列讲座的第四篇，本文介绍并讨论InSAR数据处理方法和关键算法，并对主要的数据处理流程以数学模型的形式进行了概括。  相似文献