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201.
Paleomagnetic constraints on Zn–Pb ore genesis of the Pillara Mine, Lennard Shelf, Western Australia
The Pillara Zn–Pb deposit is the largest of several known Mississippi Valley-type (MVT) deposits in the Lennard Shelf of the Canning Basin. Paleomagnetic and rock magnetic measurements are reported for 294 specimens from 23 sites in mineralization and its carbonate host rocks from the deposit as well as on 15 artificial specimens of zinc and lead concentrate and of tailings. Pyrrhotite carries the characteristic remanent magnetization (ChRM) in nearly all specimens. The ChRM postdates most faulting as shown by breccia tests and most minor regional tilting as shown by the degraded fit on tilt correction. The mean ChRM direction for all sites is D=20.6°, I=–27.5° (N=23, 95=5.3°, k=34.1), yielding an age of 358±5 Ma (2) that is similar to the comparable age of 354±8 Ma (2) for the Kapok MVT deposit. Host rock diagenesis with attendant secondary remagnetization yields an age of 361±5 Ma (1) and the MVT mineralization with a primary chemical remanent magnetization gives an age of 356±3 Ma (1), co-eval with a published Rb–Sr sphalerite age of 357±3 Ma. Interpretation of this temporal data suggests that the MVT deposits of the southeastern Lennard Shelf originated during extension, probably in response to rift-related topography-driven fluid flow.Editorial handling: C. Brauhart 相似文献
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203.
Release of heavy metals during weathering of the Lower Cambrian Black Shales in western Hunan,China 总被引:8,自引:0,他引:8
Bo?PengEmail author Zhaoliang?Song Xiangling?Tu Meilian?Xiao Fucheng?Wu Huanzhe?Lv 《Environmental Geology》2004,45(8):1137-1147
Weathering of heavy metal enriched black shales may be one of the most important sources of environmental contamination in areas where black shales are distributed. Heavy metal release during weathering of the Lower Cambrian Black Shales (LCBS) in western Hunan, China, was investigated using traditional geochemical methods and the ICP-MS analytical technique. Concentrations of 16 heavy metals, 8 trace elements and P were measured for samples from selected weathering profiles at the Taiping vanadium ore mine (TP), the Matian phosphorous ore mine (MT), and Taojiang stone-coal mine (TJ). The results show that the bedrock at these three profiles is enriched with Sc, V, Cr, Co, Ni, Cu, Zn, Pb, Th, U, Mo, Cd, Sb, Tl, and P. Based on mass-balance calculation, the percentages of heavy metals released (in % loss) relative to immobile element Nb were estimated. The results show significant rates of release during weathering of: V, Cr, Co, Ni, Cu, Zn, U, Mo, Cd, Sn, Sb, and Tl for the TP profile; Sc, Cr, Mn, Co, Ni, Cu, Zn, Pb, Th, Cd, and Sn for the MT profile; and Sc, Mn, Co, Ni, Zn, Th, Cd, Sn, and Tl for the TJ profile. Among these heavy metals, Co, Ni, Zn, Cd, and Sn show very similar features of release from each of the three weathering profiles. The heavy metals released during weathering may affect the environment (especially topsoil and surface waters) and are possibly related to an observed high incidence of endemic diseases in the area. 相似文献
204.
205.
—The Rif belt forms with the Betic Cordilleras an asymmetric arcuate mountain belt (Gibraltar Arc) around the Alboran Sea, at the western tip of the Alpine orogen. The Gibraltar Arc consists of an exotic terrane (Alboran Terrane) thrust over the African and Iberian margins. The Alboran Terrane itself includes stacked nappes which originate from an easterly, Alboran-Kabylias-Peloritani-Calabria (Alkapeca) continental domain, and displays Variscan low-grade and high-grade schists (Ghomarides-Malaguides and Sebtides-Alpujarrides, respectively), shallow water Mesozoic sediments (mainly in the Dorsale Calcaire passive margin units), and infracontinental peridotite slices (Beni Bousera, Ronda). During the Late Cretaceous?-Eocene, the Alboran Terrane was likely located south of a SE-dipping Alpine-Betic subduction (cf. Nevado-Filabride HP-LT metamorphism of central-eastern Betics). An incipient collision against Iberia triggered back-thrust tectonics south of the deformed terrane during the Late Eocene-Oligocene, and the onset of the NW-dipping Apenninic-Maghrebian subduction. The early, HP-LT phase of the Sebtide-Alpujarride metamorphism could be hypothetically referred to the Alpine-Betic subduction, or alternatively to the Apenninic-Maghrebian subduction, depending on the interpretation of the geochronologic data set. Both subduction zones merged during the Early Miocene west of the Alboran Terrane and formed a triple junction with the Azores-Gibraltar transform fault. A westward roll back of the N-trending subduction segment was responsible for the Neogene rifting of the internal Alboran Terrane, and for its coeval, oblique docking onto the African and Iberian margins. Seismic evidence of active E-dipping subduction, and opposite paleomagnetic rotations in the Rif and Betic limbs of the Gibraltar Arc support this structurally-based scenario. 相似文献
206.
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208.
Nd-Sr-Pb isotopic constraints on metal and fluid sources in W-Sb-Au mineralization at Woxi and Liaojiaping (Western Hunan,China) 总被引:9,自引:0,他引:9
This paper presents Nd-Sr-Pb isotope data on scheelite, inclusion fluids and residues of gangue quartz, and sulfides from the W-Sb-Au ore deposits at Woxi and Liaojiaping (LJP) in the Xuefeng Uplift Belt (XUB), Western Hunan, China. Sm and Nd concentrations in scheelite from Woxi are much lower than in scheelite from LJP and can be distinguished by their high 147Sm/144Nd ratios of ~1.25 from the much lower ratios around 0.26 in scheelites from the LJP. Nd values (compared to values at 200 Ma, which is the average timing of granitoid emplacement during the Indosinian-Yanshanian periods in the XUB) are around –10 for the LJP and compare well with the range of –5 to –11 defined by the granitoids, whereas they are around –27 for scheelite from Woxi. This might indicate that REEs in the mineralizing fluids at LJP originated from granitoids that are concentrated along the southern border of the XUB, whereas in the case of Woxi, the original fluids might have been masked by REEs released during intense high-temperature wall rock alteration of unexposed Precambrian basement rocks at depth. Sr isotopes of scheelite from these two deposits show similar relations to host / nearby rocks, in that 87Sr/86Sr (T=200 Ma) ratios of ~0.721 for LJP scheelite agree with values ranging between 0.718 – 0.726 for granitoids, whereas these ratios are much higher (i.e. 0.745) for scheelite from Woxi and correspond to the 87Sr/86Sr (T=200 Ma) ratio range of 0.743 – 0.749 for Precambrian host slates. Crushing experiments to release inclusion fluids from gangue quartz and sulfides deposited during later stages of ore deposition in both deposits failed to provide accurate and geologically meaningful two-point (fluid-residue) tie lines in Rb-Sr isochron diagrams. However, Sr released from fluid inclusions generally reveals lower initial 87Sr/86Sr ratios than the respective residues and shows affinities to 87Sr/86Sr (T=200 Ma) values of Indosinian-Yanshanian granitoids, both at Woxi and LJP. Pb stepwise leaching of scheelite and sulfides did not result in sufficient spreads in Pb isotope diagrams and therefore no information regarding exact mineralization ages in the two deposits could be deduced. Overall, ore Pb isotopes reveal upper crustal signatures and are compatible with Pb isotope signatures of the predominant Precambrian slates in the Woxi area. Steep trajectories through late stage quartz-sulfide mineralization in Pb isotope diagrams may hint at mixing scenarios involving Pb from the host rocks and a component with lower 207Pb/204Pb and 208Pb/204Pb ratios relative to 206Pb/204Pb ratios, which cannot be linked to any known reservoir in the XUB mining district. Sr isotopes of four out of seven residual sulfide samples from Woxi plot along a paleomixing line at an age of 199 ± 8 Ma, supporting a mixing scenario for the fluids indicated by the Pb isotopes and pointing to a possible genetic relationship with the emplacement of Indosinian—Yanshanian granitoids. The budgets of REEs, Rb-Sr and Pb in the original fluids were severely affected by contamination of these elements apparently during intense wall rock alteration but, after sealing of the major pathways, the mineralizing fluids tend to have better preserved their original signatures. These attest a genetic relationship between the metallogeny in the XUB W-Sb-Au province and the emplacement of Indosinian-Yanshanian granitoids during Mesozoic intracontinental tectonic uplift and thrusting.Electronic Supplementary Material Supplementary material is available in the online version of this article at Editorial handling: B. Lehmann 相似文献
209.
M.?J.?Varas-MurielEmail author E.?Molina-Ballesteros 《International Journal of Earth Sciences》2004,93(1):132-143
During the Tertiary, the Hercynian basement of the Iberian Peninsula was uneven due to Alpine tectonism which led to the development of a set of horsts and grabens forming its main geological structure. One of these grabens is the Ciudad Rodrigo Basin, located close to the Portuguese border. The south-western margin of this graben is filled with arkosic sandstones of continental origin that, once deposited, underwent important low-grade diagenetic processes related to the surface processes. The main diagenetic processes were hydrolysis, replacement by carbonate, and argillization to palygorskite. These three processes led to the differentiation of three main levels within the outcrops studied: (1) the Lower Level, where the original clayey sandstone outcrops, displaying fairly hydromorphic traits; (2) the Middle Level, where part of the clayey matrix has been replaced by dolomitic carbonate; and (3) the Upper Level, where palygorskite is the new neoformed clay. The change in porosity seems to have been the controlling factor, since it governs the dynamics of the solutions inside the rocks. These conditions changed from being diffusion-driven, at the start of the diagenesis, to flow-driven as porosity increased. 相似文献
210.
Preliminary study on PAH degradation by bacteria from contaminated sediments in Xiamen Western Sea,Fujian, China 总被引:1,自引:0,他引:1
In order to estimate the biodegradation of three polycyclic aromatic hydrocarbons (PAHs) compounds, bacterial strains were isolated from marine sediments in three heavily contaminated sites (Yuandang Lake, Dongdu Port and Aquacultural zones in Maluan Bay) in Xiamen Western Sea. The results show three bacterial strains, which used pyrene as the sole carbon source, were identified as strains of Aureobacterium sp.,Arthrobacter sp., Rhodococcus sp. The PAH-degrading bacteria isolated had a strong ability to degrade phenanhrene, fluoranthene and pyrene at different degradation rates. The highest degradation rate was observed when three PAH compounds were mixed with an individual strain in the medium. The three PAHs were degraded after one week with a degradation rate of 89.94 % for phenanthrene and 93.4 % for both of fluoranthene and pyrene.In addition, after 25 days of incubation, the degradation rate was 99.98 % for phenanthrene and 99.97 % for both of fluoranthene and pyrene. Optical density was measured to estimate bacterial growth during the degradation of PAHs. Highest levels of bacterial growth were observed with a three PAH mixture in the culture, suggesting that the concentration of PAHs influenced bacterial growth and the highest levels of degradation for most series were detected after one week of incubation. 相似文献