溶剂萃取原子吸收光谱法测定高纯石英砂中痕量铁          下载免费PDF全文

李茂巨  王基伟  孙继南 《山东国土资源》2005,21(10):53-55

高纯石英砂用HF等溶剂溶解并蒸干后,在微酸性介质中用抗坏血酸还原Fe^3＋为Fe^2＋,与1,10-二氮杂菲形成Fe2＋3络合物,加入适量ClO4^-阴离子与之形成离子缔合物,用硝基苯萃取,原子吸收测定有机相,本法检出限1.1μg/g,样品分析结果的RSD%为：4.52～10.3.  相似文献   

Characteristics of aeolian grain transport over a fluvio-glacial lacustrine braid delta,Lake Tekapo,New Zealand     

Hamish A. McGowan  Andrew P. Sturman 《地球表面变化过程与地形》1997,22(8):773-784

This paper presents results from one of the few scientific studies to examine the physical characteristics of aeolian sediment transport in an alpine area, where topographically reinforced foehn winds initiate dust storm events. The major objective of this study is to improve knowledge of aeolian processes in mid-latitude alpine regions experiencing extreme wind speeds. Of particular interest is the role of surface characteristics in contributing to the unusually deep saltation layer which is seen to form over fluvio-glacial deposits in the Southern Alps of New Zealand. Sediment was collected at several heights (0ċ5, 1, 2 and 4 m) and locations over a large alpine braided river delta, and standard laboratory techniques used to examine grain size characteristics. An image processing technique was also used to evaluate grain roundness. Grains filtered from the airstream at 0ċ5 m and 1 m above such surfaces were found to display a mean grain size of approximately 300 to 435 μm, resembling grain size characteristics of saltation clouds previously observed in high latitude, cold climate locations, in contrast to desert and prairie environments. Samples collected at 2 and 4 m above the surface were found to consist of 60 to 65 per cent sand-sized material, with some grains exceeding 1–1ċ5 mm in diameter. Grain shape analysis conducted on silt- and clay-sized grains filtered from the airstream above mixed sand and gravel surfaces showed such grains to display an increase in grain roundness with height. This characteristic is thought to reflect the airstream's shape-sorting ability and has important implications with respect to the often observed increase in grain roundness in aeolian deposits with increasing distance from source areas. Namely, if more rounded grains are preferentially carried higher into the airstream and therefore into regions of higher wind speed, they should theoretically be transported further from the entrainment zone before being deposited. The high wind speeds observed, often exceeding 30 m s⁻¹, are seen to transport significantly larger sediment than reported in the literature for desert and prairie environments. In addition, the mixture of grain sizes, and especially the pebble- and cobble-sized clasts that dominate the fluvio-glacial deposits associated with the braided rivers in this mountain region, also appear to increase significantly the trajectory height of saltating sand grains. As a result of these two factors, the depth of the saltation cloud often exceeds 1 m. Observations made in this study therefore highlight the need for field and laboratory aeolian process studies to be extended to examine grain transport over coarse-grained beds during much higher wind velocities than typically reported in the literature. Such studies would provide a valuable insight into aeolian processes in high latitude/altitude environments, such as loess genesis. © 1997 by John Wiley & Sons, Ltd.  相似文献   

晋北煅烧高岭土用煤矸石的应用矿物学特征   总被引：1，自引：0，他引：1  

侯龙超  王哲皓  汪灵  周东晓 《矿物学报》2020,(2):149-154

为了给晋北煅烧高岭土用煤矸石的评价和开发利用提供科学依据,采用XRD、XRF、SEM和白度计等现代分析测试技术,研究了晋北煅烧高岭土用煤矸石的应用矿物学特征。结果表明:1)根据造纸和涂料用煅烧高岭土的国家标准,晋北煤矸石主要可分为3种类型:合格原料、基本合格原料和不合格原料。2)与合格和基本合格原料相比,不合格原料煅烧产物的化学成分中SiO2、Al2O3、Fe2O3含量以及碱金属与碱土金属总含量都与前者有较大差异。3)合格和基本合格原料主要由高岭石(85%~94%)组成,不合格煤矸石矿物组合为高岭石(30%~60%)+石英(23%~38%)+伊利石(14%~26%),并含少量黄铁矿和白云石等杂质矿物,石英等杂质矿物和含铁矿物是分别导致煅烧产物化学成分和白度不合格的主要原因。4)合格原料中高岭石结晶度较好,主要为不规则片状、书册状和弯曲片状,片表面光滑,片径大小范围较大,为0.05~51.22μm,平均2.80μm,径厚比41.24。  相似文献   

Relationship Between Electrical Properties and Sedimentary Environment of the Longmaxi Formation Shale, Southern Sichuan     

YANG Kai  ZHANG Bing  WANG Xuben  HE Lanfang  YANG Hongyu  WANG Pengwan  TANG Jialin  DENG Jixin  ZHANG Cong 《《地质学报》英文版》2020,94(5):1531-1546

The Lower Silurian Longmaxi Formation in the south of Sichuan is a key player in the exploration and development of shale gas in China. Due to a highly complex topographic area, electromagnetic methods (EM) become important exploration means in this area. Many studies have been conducted on the shale mineral composition and electrical properties of shale, however, the correlation between sedimentary environments and the electrical properties of shale remain poorly understood. The electrical properties and sedimentary environment of the organic-rich shale of the Longmaxi Formation have been studied by means of X-ray diffraction, organic geochemistry, scanning electron microscopy and complex resistivity measurements. The discovered high quartz content of the Longmaxi Formation shale results in low resistivity. Deep-water shelf biogenic quartz contributes lower resistivity more than that of shallow-water terrigenous quartz. The deep-water anoxic and organic sedimentary environment led to major enrichment of pyrite, leading to a high polarization effect in shale. We present the correlation between the lithofacies types and electrical properties of Longmaxi Formation. The mixed siliceous shale lithofacies is the most favorable among the three lithofacies, which is characterized by high total organic carbon (TOC) content, high brittleness mineral content, high polarization and low resistivity (“three high and one low”). This feature is an effective identification of shale gas reservoirs by electromagnetic prospecting. Our study can provide constraints on electrical parameters of rocks for electromagnetic “sweet spot” exploration of shale gas, and so this has important geological significance to shale gas exploration and development.  相似文献   

莺歌海盆地乐东地区石英裂隙内流体包裹体特征及其对天然气成藏制约          下载免费PDF全文

税蕾蕾  梁茹  孟祥豪  郭来源  许克伟 《沉积与特提斯地质》2020,40(1):45-52

莺歌海盆地乐东地区是我国典型高温超压天然气勘探领域,其关键储层黄流组砂岩以天然气富含CO_2为特征,对其中石英颗粒内裂隙包裹体的研究能为CO_2来源和天然气成藏信息提供重要线索。本文通过对黄流组砂岩石英颗粒内包裹体进行岩相学、显微测温与激光拉曼分析,结果表明黄流组砂岩石英颗粒内正常捕获流体包裹体均一温度主要分布在155～165℃与170～180℃两个温度区间,流体包裹体成分为CO_2(气)和H_2O(液)两种或CO_2(气)和CO_2(液)、H_2O(液)三种。这些特征表明乐东地区黄流组至少经历两期富含CO_2的热液活动,记录了埋藏晚期无机CO_2在火山活动或深大断裂发育期充注成藏的信息。  相似文献   

内蒙古碾子沟钼矿床成矿流体来源、演化及成矿机理     

孙丰月  王睿  王一存  李顺达  王可勇  石开拓  孙清飞  王文元 《吉林大学学报(地球科学版)》2020,50(3):768-780

内蒙古自治区碾子沟钼矿床地处华北地台北缘西拉木伦钼成矿带西段,为一典型的中型石英脉型钼矿床。该钼矿床矿脉（体）主要产于燕山早期二长花岗岩-钾长花岗岩内NNW、NW向断裂构造体系之中,成矿作用过程经历了黄铁矿±辉钼矿＋石英（Ⅰ）、辉钼矿＋黄铁矿±黄铜矿＋石英（Ⅱ）、黄铜矿＋黄铁矿±闪锌矿＋石英（Ⅲ）及石英±方解石（Ⅳ）4个阶段。系统的流体包裹体岩相学、包裹体组分析、包裹体显微测温研究表明,矿床初始成矿流体为高温、中低盐度（490~550℃,盐度（w（NaC1））2%~10%,50~62 MPa）均匀的NaCl-H₂O体系热液,δ¹⁸O_H2O-SMOW（2.21‰）及δD_H2O-SMOW（-68.9‰）表明其主要来源于岩浆热液;成矿流体上升并不断汇聚于容矿断裂空间,伴随温度、压力降低（380~460℃,26~40 MPa→360~420℃,25~30 MPa）而进入两相不混溶区,流体开始发生沸腾→强烈沸腾作用,导致成矿元素Mo大量沉淀富集成矿,成矿晚期残余流体与大气降水混合（δ¹⁸O_H2O-SMOW为-2.41‰~2.51‰,δD_H2O-SMOW为-110.1‰~-105.5‰）,矿床属燕山早期中高温岩浆热液型钼矿床。  相似文献   

Terrestrial LiDAR monitoring of coastal foredune evolution in managed and unmanaged systems     

I. Conery  K. Brodie  N. Spore  J. Walsh 《地球表面变化过程与地形》2020,45(4):877-892

Coastal dunes provide essential protection for infrastructure in developed regions, acting as the first line of defence against ocean-side flooding. Quantifying dune erosion, growth and recovery from storms is critical from management, resiliency and engineering with nature perspectives. This study utilizes 22 months of high-resolution terrestrial LiDAR (Riegl VZ-2000) observations to investigate the impact of management, anthropogenic modifications and four named storms on dune morphological evolution along ~100 m of an open-coast, recently nourished beach in Nags Head, NC. The influences of specific management strategies – such as fencing and plantings – were evaluated by comparing these to the morphologic response at an unmanaged control site at the USACE Field Research Facility (FRF) in Duck, NC (33 km to the north), which experienced similar environmental forcings. Various beach-dune morphological parameters were extracted (e.g. backshore-dune volume) and compared with aeolian and hydrodynamic forcing metrics between each survey interval. The results show that LiDAR is a useful tool for quantifying complex dune evolution over fine spatial and temporal scales. Under similar forcings, the managed dune grew 1.7 times faster than the unmanaged dune, due to a larger sediment supply and enhanced capture through fencing, plantings and walkovers. These factors at the managed site contributed to the welding of the incipient dune to the primary foredune over a short period of less than a year, which has been observed to take up to decades in natural systems. Storm events caused alongshore variable dune erosion primarily to the incipient dune, yet also caused significant accretion, particularly along the crest at the managed site, resulting in net dune growth. Traditional empirical Bagnold equations correlated with observed trends of backshore-dune growth but overpredicted magnitudes. This is likely because these formulations do not encompass supply-limiting factors and erosional processes. © 2019 John Wiley & Sons, Ltd.  相似文献   

不同类型洞体应变仪的观测差异性分析          下载免费PDF全文

孙伶俐  蒋玲霞  吕琳  张辉  邓建刚 《地震工程学报》2020,42(1):129-135

运用SPSS中聚类及PCA方法对湖北省7个台站三类基线(石英管、铟钢棒、铟钢管)洞体应变观测记录进行相关统计分析,归纳总结其潮汐参数变化特征差异,并针对观测中自然环境因素影响进行定量分析。结果显示:(1)三类基线中,铟钢棒类M2波潮汐因子、中误差及M1波相对噪声水平较低,铟钢棒管年均漂移量最小;(2)自然环境因素(气压、降水、雷雨、温度)对湖北地区洞体应变观测影响较为显著,等量气压影响下应变量最小的为铟钢管型,等量温度影响下应变量最小的为铟钢棒型。  相似文献   

Horizontal water trap for measurement of aeolian sand transport     

Ping Wang  Nicholas C. Kraus 《地球表面变化过程与地形》1999,24(1):65-70

A new type of horizontal trap was developed for measuring the aeolian sand transport rate on a flat surface. The trap consists of an adjustable frame that is embedded level with the sand surface, into which a plastic liner is installed and filled with water to capture the blown sand. The water trap has high efficiency and does not disturb the wind field or induce upwind scour. Deployment on Padre Island, Texas, indicated that this portable and adjustable trap catches and retains all the sand blown into it, even under relatively strong wind. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

内蒙古额仁陶勒盖银矿床石英的矿物标型特征研究   总被引：3，自引：0，他引：3  

吕志成  段国正  郝立波  张培萍  董广华 《矿物学报》2001,21(2):251-258

对额仁陶勒盖银矿床中石英的稀土元素，包裹体测温、包裹体成分、同位素、化学成分及红外光主普学特征等进行了研究，认为额仁陶勒盖银矿床属于浅成中温热液成因，早期成矿流体为岩浆热液，晚期成矿流体天水臧主导地位，矿床形成于弱碱性条件下及还原环境中。石英的红外光谱学特征、石英的化学成分及形态是该银矿床重要的找矿矿物学标志。  相似文献