单道扫描电感耦合等离子体发射光谱法测定地质样品中的微量稀土元素     

郭振华  张立英  杜百娟 《化工矿产地质》2003,25(1):57-60

采用Na_2O_2熔融矿样,水提取,加三乙醇胺、EGTA做掩蔽剂。经氢型阳离子交换树脂交换分离富集稀土元素,由于选择了合适的仪器条件及测定波长,有效地消除了电感耦合等离子体发射光谱法(ICP-AES)测定过程中的基体干扰和光谱干扰。应用于地质样品中的稀土元素分析,获得了满意的准确度、精密度及检出限。  相似文献   

环电流区中性原子观测特性模拟研究   总被引：2，自引：1，他引：2       下载免费PDF全文

沈超  刘振兴 《地球物理学报》2003,46(1):1-1

为了给双星计划中性原子(ENA)探测仪的研制提供可靠 的理论依据，并为未来中性原子探测数据的分析及研究做好准备，针对双星轨道初步模拟计 算了双星ENA探测仪对磁暴时中性原子的观测特性. 建立了磁暴主相期间环电流离子分布的 一 个近似理论模式，并模拟计算了极轨卫星在极区上空、赤道面以及其他位置上对不同强度磁 暴主相期间环电流区ENA空间角分布及能谱的观测结果. 研究表明，存在环电流区方向和南 北极区环电流粒子沉降带两个中性原子强度极大区域；磁暴越强烈，注入区高度越低，环电 流区观测到的ENA通量越高；处于有利位置的ENA探测器可分辨注入区内边界或注入前沿；EN A探测器能够分辨环电流带离子分布的不均匀性；由于离子交换截面的差异，H，O，He 3种E NA的能谱分布不同；在10～80keV能谱范围内通量较强，易于观测；环电流区H，O两种ENA 通 量较强，有利于观测；而环电流区He ENA通量很弱，不易于观测. 模拟计算研究表明，双星 极轨卫星能够对环电流区ENA进行有效探测；低纬轨道上的ENA探测器也能够对环电流区ENA 进行一些观测；ENA探测器的研制应重视低、中能量范围ENA的探测.  相似文献   

Atmospheric Methyl Iodide at Cape Grim, Tasmania, from AGAGE Observations     

D. S. Cohan  G. A. Sturrock  A. P. Biazar  P. J. Fraser 《Journal of Atmospheric Chemistry》2003,44(2):131-150

Atmospheric mixing ratios of methyl iodide (CH₃I) and other methyl halides have been measured at Cape Grim, Tasmania (41°S, 145°E), since early 1998 as part of the Advanced Global Atmospheric Gases Experiment (AGAGE). This paper analyses about 1700 ambient air CH₃I measurements from the 14-month period (March 1998–April 1999). Mixing ratios peaked during the summer, despite faster photolytic loss, suggesting local oceanic emissions were about 2.2–3.6 times stronger in summer than in winter. Back trajectories show that CH₃I levels are strongly dependent on air mass origin, with highest mixing ratios in air from the Tasman Sea/Bass Strait region and lowest levels in air originating from the Southern Ocean at higher latitudes. CH₃I mixing ratios were not well correlated with other methyl halides in unpolluted marine air. The large variations with season and air mass origin suggest that high frequency, continuous data from key locations will make a significant contribution to the understanding of sources and sinks of this important short-lived atmospheric species.  相似文献   

A STUDY ON TYPHOON MOVEMENT PART Ⅲ:EFFECT OF THE HORIZONTAL MOMENTUM EXCHANGE BETWEEN TYPHOONS AND ENVIRONMENT     

贺海晏  董惠菁 《热带气象学报(英文版)》1997,3(1):1-10

Two semi-asymmetric flow patterns of typhoons are chosen to qualitatively determine the effect of exchange of horizontal momentum between inflow and outflow layers and the environment on the motion of typhoons. The results show that only the asymmetric flow component (residual after azimuthal mean flow has been removed) could cause a net momentum input into or output from a typhoon and therefore contribute to the changes in speed and direction of the typhoon movement. A typhoon with major inflow and/or outflow channels on its right (left) side would tend to accelerate and turn left (decelerate and turn right); On the other hand, a typhoon with major inflow and/or outflow channels in the rear (front) semicircle would tend to accelerate and turn right (decelerate and turn left).  相似文献   

碲的泡塑预分离M17树脂富集原子荧光测定法   总被引：7，自引：0，他引：7  

杨理勤 《黄金地质》1997,3(1):67-71

采用王水溶样，泡沫塑料预分离金等干扰组分，以Ｍ１７树脂富集Ｔｅ并使之与大部分共存的干扰元素分离，建立了原子荧光含金地质样品中碲的方法，用地矿部标准参考样品和含金地质试样分析考察，结果满意。方法检测下限为０．００９×１０＾－６。  相似文献   

The respiratory environment of the Namib Desert Golden Mole     

Roger S. Seymour  Mary K. Seely 《Journal of Arid Environments》1996,32(4):453-461

We measured the partial pressure of oxygen (PO₂) in the interstitial gas surrounding the sand-swimming Namib moleEremitalpa granti namibensis. At a sand temperature of 26 °C, which produced a nearly maximal rate of oxygen consumption, thePO₂near the noses of the animals averaged only 0·9 kPa (6·7 Torr) below the level in the free atmosphere. High oxygen availability was a result of the notably low metabolic rate in the 20 g mammals and the dry, porous and metabolically inactive nature of dune sand. A mathematical model indicated that normal mammals weighing 200 g or more could comfortably exist completely encased in dune sand. We concluded that the moles' small size and low metabolic rate are not adaptations to hypoxia or hypercapnia underground but are probably related to low food availability and the energetic cost of foraging in their desert environment.  相似文献   

含金硫化物基岩区红土型金矿的成矿作用   总被引：8，自引：0，他引：8  

李志群 《矿产与地质》1996,10(6):380-387

实验表明，在含金硫化物基岩区，硫代硫酸金络阴离子团和硫酸金络阴离子团是金在表生条件下的主要迁移形式，它们的沉淀与铁、锰氢氧化物的形成有密切联系。金的表生迁移－沉淀条件除一般的表生地质条件外，还有特殊的物理化学－生物化学条件。络阴离子团的地球化学性质，控制着红土型金矿床的垂向分带与金的次生富集。  相似文献   

Oxygen Isotope Exchange Kinetics Between Coexisting Minerals and Water in the Aral Granite Pluton of the Altay Mountains, Northern Xinjiang   总被引：2，自引：0，他引：2  

Liu Wei  Research Center of Mineral Resources Exploration  Chinese Academy of Sciences  Chinese Academy of Sciences  BeijingHe Baichu  Changsha Institute of Geotectonics  Chinese Academy of Sciences  Changsh  Hunanand Chen ZhenshengYichang Institute of Geology  Mineral Resources  Chinese Academy of GeologicalSciences  Yichang  Hubei 《《地质学报》英文版》1996,70(4)

Coexisting quartz, feldspar and biotite vary widely in their δ18O values and display a remarkable 18O/16O disequilibrium relation; especially, a quartz-feldspar reversal (△ 18OQUartz_feldspar< 0) exsists in the Aral granite pluton of the Altay Mountains, northern Xinjiang. The 18O / 16O exchange reaction definitely occurred between granite and water. Initial δ18O values of the granite and exotic fluid are evaluated by the mass balance consideration. The conventional method of discrimination between various magma derivations simply with δ18O values of either whole rock or separate minerals is misleading and unreliable. Experiments carried out by the authors show that the 18O / 16O exchange reaction is not accompanied by what geologists describe as petrological and mineralogical alteration effect. This decoupling relation implies that exchange reaction occurs at a relatively high temperature during subsolidus-postmagmatic cooling of magmas. The exchange mechanism is mainly diffusion-controlled. It is  相似文献   

Hypolimnetic density currents traced by sulphur hexafluoride (SF6)     

Jürg W. Schlatter  Alfred Wüest  Dieter M. Imboden 《Aquatic Sciences - Research Across Boundaries》1997,59(3):225-242

The artificial tracer sulphur hexafluoride (SF₆) has been used to study the density-driven deep water exchange between two sill-separated basins of Lake Lucerne, Gersauersee and Urnersee. The sources of the density gradients between the two basins are (1) salinity differences between the major inlets due to the different geology of their drainage areas, and (2) temperature differences due to spatial variation of wind forcing. Wind speeds are generally larger in Urnersee, especially in spring during the so-called Föhn events, when winds blow from the south. In contrast, Gersauersee is protected form these winds. In spring 1989, a total of 630 g of SF₆ was released at 80 to 120 m depth in the small Treib Basin located between Urnersee and Gersauersee. During about 100 days the distribution of SF₆ in the lake was determined by gaschromatography. Two models are used to quantify the exchange flow, (1) a one-box mass balance model for SF₆ in the deep part of Treib Basin, and (2) a one-dimensional diffusion/advection model describing the temporal and vertical temperature variation in Urnersee. According to the first model, the flow into the deep hypolimnion of Urnersee, decreases from 21·10⁶ m³·d^?1 at the end of March to about 8·10⁶ m³·d^?1 in late April. The second model yields similar flow rates. The decrease of the flow rate during spring, confirmed by both approaches, is consistent (1) with the decreasing strength of the density gradient above the sill during spring and early summer, and (2) with hydrographic information collected in Lake Lucerne during other years.  相似文献   

地质速率计—矿物氧扩散的应用     

傅斌  郑永飞 《地球科学进展》1997,12(5):428-433

概述了同位素封闭体系内的矿物氧扩散和同位素交换机制及其在地质速率计上的应用。火成岩从高温冷却或变质岩从高峰主质温度冷却过程中，由于冷却速度不同，扩散作用导致的矿物晶体内部及晶粒间氧同位素再平衡也有所不同。通过实测岩石中各组成矿物氧同位素比值，模式含量和颗粒半径，据矿物氧扩散和同位素交换模型，可以估算出岩石的冷却速率。  相似文献