On the transfer of stratospheric ozone into the troposphere near the north pole     

Samuel J. Oltmans  Wolfgang E. Raatz  Walter D. Komhyr 《Journal of Atmospheric Chemistry》1989,9(1-3):245-253

A series of nearly daily ozone vertical profiles obtained at station T-3 on Fletcher's Ice Island (85°N, 90°W) during the period January-March 1971 shows several significant ozone intrusions into the troposphere. These intrusions are not only associated with enhanced ozone amounts in the stratosphere but also require tropopause folding events to transport ozone into the troposphere. These folds in the Arctic tropopause appear to be capable of contributing significantly to the ozone budget of the Arctic troposphere during the late winter and spring seasons. The importance of tropopause folding for bringing ozone into the troposphere seen in the daily ozone profiles confirms the results found in the Arctic Gas and Aerosol Sampling Program aircraft flights.  相似文献   

Annual heat balance and equilibrium temperature of Lake Aegeri,Switzerland   总被引：1，自引：0，他引：1  

David M. Livingstone  Dieter M. Imboden 《Aquatic Sciences - Research Across Boundaries》1989,51(4):351-369

The mean heat budget of Lake Aegeri, Switzerland, is 950 MJ·m^–2, comparable to that of neighbouring lakes. The annual variation in the net heat flux can be adequately described using a six-term heat balance equation based on 12 years of monthly mean meteorological and surface temperature data. Although the magnitude of the net heat flux is dominated by the radiative terms of the equation, the one-month backward shift of the net flux and total heat content extrema from the solstices and equinoxes respectively is due to the phase shift of the non-radiative with respect to the radiative terms. A linear approximation was used to express the net heat flux in terms of a heat exchange coefficient and an equilibrium temperature. The former varies from 17 to 28 W·m^–2·K^–1 in the course of a year; fluctuations in the latter are found to depend mainly on fluctuations in cloud cover and relative humidity, whilst the effect of fluctuations in air temperature and wind speed is slight.  相似文献   

M17树脂对岩石中痕量硒碲的分离富集研究及应用     

林猷璧  朱玉伦 《岩矿测试》1993,12(2):81-84

M_(17)树脂在>6mol/L的HCl介质中能同时吸附Se和Te,Se和Te可用水和丙酮分别洗脱,也可用丙酮同时洗脱。从而建立了两个新的Se、Te分离富集体系,使原子荧光测定达到纳克量级。  相似文献   

单柱离子色谱测定二氧化锰产品中无机阴离子杂质     

肖正元  黎宏彦 《岩矿测试》1994,13(2):128-130

采用了单柱离子色谱法测ＭｎＯ２产品中无机离子杂质；提出了消除干扰的可行途径，将Ｌａ（ＯＨ）３加入后能同时消除进样峰的干扰和溶剂峰的出现。选用１．７５ｍｍｏｌ／Ｌ邻苯二甲酸１．７５ｍｍｏｌ／Ｌ三羟甲基氨基甲烷为混合淋洗剂测定Ｆ＾－，Ｃｌ＾－，ＮＯ３＾和ＳＯ＾２－４，其标准加入回收率为９５％－１０５％；ＲＳＤ（ｎ＝７）为２．４７％－８．０８％。  相似文献   

空间运输联系的分布与交流规律研究   总被引：29，自引：6，他引：29  

张文尝  唐秀芳 《地理学报》1994,49(6):490-499

空间运输联系是指在自然、社会、经济诸要素综合作用下，区域间通过交通运输设施进行旅客和货物交流产生的相互联系与作用。采用定量与定性相结合的实证分析方法，本文研究了客货运输的地域分布特征、地域间交流联系生成的内在机制、基本类型和增长演变的趋势，划分出客运联系“单中心”、“多中心”，货运联系“互补性交流”、“竞争性交流”、“递接性交流等类型，并提出了非均衡系数、集中度、首位联系量等评价指标。  相似文献   

The biogeochemical sulfur cycle in the marine boundary layer over the Northeast Pacific Ocean   总被引：1，自引：0，他引：1  

T. S. Bates  J. E. Johnson  P. K. Quinn  P. D. Goldan  W. C. Kuster  D. C. Covert  C. J. Hahn 《Journal of Atmospheric Chemistry》1990,10(1):59-81

The major components of the marine boundary layer biogeochemical sulfur cycle were measured simultaneously onshore and off the coast of Washington State, U.S.A. during May 1987. Seawater dimethylsulfide (DMS) concentrations on the continental shelf were strongly influenced by coastal upwelling. Concentration further offshore were typical of summer values (2.2 nmol/L) at this latitude. Although seawater DMS concentrations were high on the biologically productive continental shelf (2–12 nmol/L), this region had no measurable effect on atmospheric DMS concentrations. Atmospheric DMS concentrations (0.1–12 nmol/m³), however, were extremely dependent upon wind speed and boundary layer height. Although there appeared to be an appreciable input of non-sea-salt sulfate to the marine boundary layer from the free troposphere, the local flux of DMS from the ocean to the atmosphere was sufficient to balance the remainder of the sulfur budget.  相似文献   

离子色谱—双电导法同时测定水样中多种阴离子的研究   总被引：2，自引：0，他引：2  

吕伟  徐魁安 《岩矿测试》1991,10(1):25-29

本文在Dionex2020i离子色谱仪上,选用0.61×10~(-3)mol/L NaHCO_3-1.61×10~(-3)mol/LNa_2CO_3水溶液作淋洗液,在HPIC-AS4A阴离子分离柱上分离痕量F~-、NO_2~-、Br~-和较高浓度的Cl~-、NO_3~-、SO_4~(2-);选用2.0×10~(-3)mol/L TBAOH-6％CH_3CN水溶液作淋洗液,在MPIC-NS1分离柱上分离痕量F~-、Br~-和较高浓度的Cl~-,然后用串联双电导检测器的不同输出范围分别同时定量测定。本法特别适用于相邻两种离子浓度相差较大,前面高含量的离子对后面痕量离子测定有干扰的样品。用本文拟定的HPIC方法测定除铬后的地下水样中多种阴离子的结果与文献值吻合。  相似文献   

M17树脂分离富集原子荧光测定岩矿中痕量碲   总被引：4，自引：1，他引：4  

林猷璧  朱玉伦 《岩矿测试》1991,10(4):283-286

本文研究了不同种类树脂对Te的吸附能力,提出了在3mol/L HCl介质中,用M_(17)二甲胺树脂吸附,然后用水洗脱的新途径,使Te有效且无污染地得到分离和富集,实现了原子荧光测定地质试样中ppb级痕量Te。经地矿部标准参考样GSR7-12考察,分析结果与推荐值相符。  相似文献   

离子交换与吸附研究方法   总被引：2，自引：0，他引：2  

张绍成 《盐湖研究》1994,2(1):74-81

综合文献资料，结合本人研究实践，对离子交换与吸附研究的一些方法做专门介绍．  相似文献   

Trace gas measurements during aircraft flights in the tropopause region over Europe and North Africa     

M. Schmidt  R. Borchers  P. Fabian  G. Flentje  W. A. Matthews  A. Szabo  S. Lal 《Journal of Atmospheric Chemistry》1984,2(2):133-143

During aircraft flights in May 1981 from Munich (40°N) to north of the Spitsbergen Islands (82°N) and to Monrovia, Liberia (6°N), air samples were obtained in the altitude range of 8 to 11 km and during the ascents and descents near the airports. These samples have been analyzed for the trace gas mixing ratios of CH₄, CO and N₂O. The results of these analyses are presented and discussed.The results provide new evidence of tropospheric-stratospheric exchange events in the vicinity of the subpolar and subtropical tropopause foldings and possibly show a case of transport of CO-enriched air in the upper troposphere above the North Atlantic Ocean.  相似文献