Influence of Temporal Variations in River Discharge, pH, Alkalinity and Ca on the Speciation and Concentration of Heavy Metals in Some Mining Polluted Rivers     

Pål Gundersen  Eiliv Steinnes 《Aquatic Geochemistry》2001,7(3):173-193

Dissolved (dialysis in situ) and total concentrations ofCu, Zn, Cd and Al in eight mining polluted rivers in the Røros area, central Norway, were determinedby atomic absorption spectrometry (flame and graphite furnace) and compared to pH, Caconcentration and alkalinity through seasonal variations in river discharge. Totalconcentrations of the metals were highest during early spring flood and during summer andautumn rain episodes. Dissolved concentrations also increased as the spring floodproceeded, but small discharge peaks within this 2 month period as well as a considerableautumn flood episode appeared to lower rather than to raise the dissolved metal concentrations.Consequently the dissolved fractions of Zn, Cd and Al showed a significant negative correlationwith river discharge, and were low at the discharge peaks. Possibly high sediment concentrationsoccurring at high flood conditions more than counteracted desorption induced by pHdecrease, and led to decreased dissolved fractions through adsorption. Cu speciationon the other hand seemed to be more closely linked to pH. Alkalinity and Ca concentration,both assumed to protect aquatic life from metal pollution, were significantly lowerduring episodes with high Cu and Al total concentrations.  相似文献   

云南白水台钙华水池中水化学日变化及其生物控制的发现   总被引：11，自引：0，他引：11  

刘再华  李强  孙海龙  汪进良  吴孔运 《水文地质工程地质》2005,32(6):10-15

为弄清云南白水台泉及其下游钙华水池中水化学的日变化,选取1号泉及其流经的两个钙华水池(6号和10号)作为研究对象并对其水温、pH值和电导率进行了自动监测。根据Ca2 、HCO3-与电导率存在的线性关系,用WATSPAC软件计算了水中方解石的饱和指数和PCO2。监测发现:泉水不存在显著的水化学日动态变化,而两个钙华水池表现出显著的日动态变化。其中10号钙华水池在白天温度较高时水中的CO2大量逸出并通过水下水生植物的光合作用加速了水中碳酸钙的沉积。6号钙华水池水生植物生长茂盛,其叶片和部分枝干露出水面,因而光合作用主要发生在空中,所以此处水化学表现为白天pH值降低和电导率升高的反常现象,即由温度主导的根呼吸作用,在白天释放更多的CO2进入水体而使沉积下来的碳酸钙重新溶解。  相似文献   

ASSESSMENT OF 17β-ESTRADIOL IN AQUATIC ENVIRONMENTS AROUND KLANG VALLEY, MALAYSIA     

Ahmad Ismail　Syaizwan Zahmir Zulkifli　Ferdius Mohamat Yusuff　Usuki Yasuteru　Kitajima Sachiko　Arizono Koji 《湿地科学》2007,5(4):322-325

This study was conducted to assess the existing concentration of 17β-estradiol(E2)in the surface water samples collected from rivers and lakes around Klang Valley,Malaysia.E2,which is a natural feminizing chemical produced in female organisms,regularly used to compare with other environmental estrogens because they behave similarly and react effectively as a hormone at a very low concentration.It was found that the average concentration of E2 in the aquatic environment of Klang Valley was(14.08 ±3.67)pg/mL,which was 14 times higher than those in the Japanese aquatic environment in this study.The river system had the average concentration of(20.02±5.26)pg/mL while the lake had an average concentration of(5.91±3.39)pg/mL.The E2 concentration was presumed high if the sources occurred nearby the area.Current levels of E2 in the aquatic environment may possess threats to existing aquatic organisms.Since high level of E2 has been discovered in the aquatic environment around Klang Valley,further studies and monitoring of E2 and other EDCs concentrations are needed to determine their levels in Malaysian aquatic environment and help to control these chemicals pollution in the aquatic environment.  相似文献   

用离子色谱法测定金矿区水样中常规无机离子   总被引：6，自引：1，他引：6  

黄园英  刘芬  罗锡明  贾刚军 《黄金地质》2002,8(2):69-73

利用DX－120离子色谱仪进行阴阳离子的精密度和准确度测定，100mg/L时相对标准偏差范围为1．00％－3．80％，回收经95．83％－105．00％；5mg／L时相对标准偏差范围为1．18％－4．57％，回收率92．40％－103．20％，完全达到实际要求。用该离子色谱仪测定甘肃阳山金矿山水样中常规无机离子，数据表明该区域水质较好，所测离子浓度都未超过饮用水标准。  相似文献   

水资源中氯代烃污染物的去除方法   总被引：3，自引：0，他引：3  

李琳  刘菲 《黄金地质》2002,8(2):74-76

随着工业化的发展。氯代有机溶剂使用越来越广泛。并且难于去除。在20世纪90年代初期，人们就已认识到用Fe^0恢复污染的地下水的潜力。国外正在研究帮使用扔几种还原挥发性氯代烃的还原反应介质，尤其要提高的是双金属反应系统，反应速度快，而且脱Cl中国难解产物少，目前国也只停留在实验室研究阶段，个别做了地上反应器的验证实验，它的脱Cl机理、介质钝化和完全脱Cl问题还有待于进一步研究。  相似文献   

Assessment of flow–ecology relationships for environmental flow standards: a synthesis focused on the southeast USA     

Sarah Praskievicz  Cehong Luo 《水文科学杂志》2020,65(4):571-582

ABSTRACT

Environmental flow standards are a management tool that can help to protect the ecosystem services sustained by rivers. Although environmental flow requirements can be assessed using a variety of methods, most of these methods require establishing relationships between flow and habitat of species of concern. Here, we conducted a synthesis of past flow–ecology studies in the southeast USA. For each state or interstate river basin, we used the published data to determine the flow metrics that resulted in the greatest changes in ecological metrics, and the ecological metrics that were most sensitive to hydrologic alteration. The flow metrics that were most important in preserving ecological metrics were high-flow duration and frequency, 3-day maximum and minimum, and number of reversals. The ecological metrics most sensitive to hydrologic alteration were mostly related to presence or absence of key indicator species.  相似文献   

Bed waves at the basin scale: implications for river management and restoration     

L. Allan James 《地球表面变化过程与地形》2006,31(13):1692-1706

An extensive literature about fluvial sediment waves, slugs or pulses has emerged in the past 20 years. The concept has been useful in many respects, but has been applied to diverse phenomena using a variety of definitions. Moreover, inferred linkages between channel‐bed changes and sediment loads are often not justifiable. This paper reviews concepts of large fluvial sediment waves at scales extending to several tens of kilometres. It points out constraints on the inferences that can be made about sediment loads based on changes in channel‐bed elevation at this scale where channel sediment interacts with storage in floodplain and terrace deposits. The type area of G. K. Gilbert's initial sediment‐wave concept is re‐examined to show that neither wave translation nor dispersion occurred in the simple manner commonly assumed. Channel aggradation and return to graded conditions provide an alternative theory explaining Gilbert's observed bed‐elevation changes. Recognizing the evidence and implications of the former passage of a large‐scale bed wave is essential to the accurate diagnosis of catchment conditions and the adoption of appropriate river restoration goals or methods. Sediment loads, water quality, channel morphologic stability and aquatic ecosystems often reflect changes in sediment storage long after the channel bed has returned to grade. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

水生态区划方法及其在中国的应用前景   总被引：30，自引：0，他引：30       下载免费PDF全文

孟伟  张远  郑丙辉 《水科学进展》2007,18(2):293-300

系统总结了国际水生态区划的指标、方法和体系,分析了水生态区划在水质管理、河流生物监测、湖泊水库管理、湿地管理和水生生物区系研究中的作用和经验。在分析中国水体分区现状的基础上,结合中国水环境管理的要求,设想了我国水生态分区体系的构建思路,初步提出了适宜于我国的区划框架体系和主要选取指标。  相似文献   

工业废水和城市综合污水的环境风险管理   总被引：1，自引：0，他引：1       下载免费PDF全文

陈建  韩小波  丁登山  金洪钧 《水科学进展》2007,18(4):614-622

综述了国内外工业废水与城市综合废水的监控和环境风险管理进展。与发达国家比较,化学监测法是目前我国工业废水和城市综合污水监控的唯一手段,而且主要有赖于COD等极少参数,并不能有效监控复合有毒有机污染物的排放。采用生态毒性检测法,可弥补这一缺陷,满足环境风险管理要求。毒性鉴别评价鉴别出导致废水/污水生态毒性的关键有机毒物,是降低其环境风险的核心。还对生态毒性检测法应用于我国废水/污水排放的监控和环境风险管理前景做了评述。  相似文献   

风浪作用下水生植物对水流结构的影响——以太湖中两种典型沉水植物为例          下载免费PDF全文

张英豪  赖锡军  张琳  姚昕  邓焕广 《水科学进展》2020,31(3):441-449

为研究风浪作用下水生植物对水流结构的影响,选取太湖中两种典型沉水植物(苦草与马来眼子菜)为研究对象,分别对苦草植物斑块与马来眼子菜植物斑块内外水体的瞬时流速进行野外现场测量,利用瞬时流速的能量谱分布将波浪流速与紊动流速分离,分别分析水生植物对时均流速、波浪流速以及紊动能的影响。风浪影响下,水体中存在流向与测量时近水面处盛行风向一致的水流;波浪流速以垂向流速为主,且波浪流速自水面向床底逐渐减小;紊动能在水面处达到最大值,并向床底方向逐渐减小。与无植被条件相比,苦草与马来眼子菜的存在减小了时均流速、波浪流速以及紊动能。两种植物形态上的差异,导致其对水流结构的影响不同:苦草叶片阻流面积在冠层中部达到最大,使得时均流速与波浪流速在苦草中部位置的减小程度最大;马来眼子菜叶片主要集中于冠层顶部(水面附近),其对时均流速以及波浪流速的减小作用在水面处达到最大。  相似文献