Attenuation of Arsenic in Karst Subterranean Stream and Analysis of Its Influence Factors: Hydrogeochemical Factors     

ZHANG Liankai  YANG Hui 《《地质学报》英文版》2013,87(Z1):661-661

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悬浮液进样氢化物发生原子荧光法测定海洋沉积物样品中痕量砷   总被引：6，自引：0，他引：6  

程祥圣  秦晓光  刘富平 《海洋学报》2005,27(1):159-162

人类对砷的认识已有很长的历史,近几十年来关于砷对环境的污染以及对人体健康的影响日益受到人们的关注.砷是海洋沉积物中常见的主要环境污染元素之一,目前测定它的常用方法有砷钼酸-结晶紫分光光度法[1]、氢化物-原子吸收分光光度法[1]、催化极谱法[1]、氢化物-原子荧光光谱法[2],但是这些方法需将样品制备成溶液,处理过程冗长,易引起操作沾污和待测成分损失,而且试剂消耗量大,同时产生的酸气对操作人员的身体健康非常有害,为此分析工作者一直在寻求一些新的前处理技术.  相似文献   

氢化物原子荧光光谱法测定富马酸中的砷   总被引：1，自引：0，他引：1  

乐爱山 《岩矿测试》2000,19(2):155-157

用氢氧化钠溶液分解富马酸使其转化为水溶性富马酸钠 ,然后用氢化物发生 -原子荧光光谱法测定了试样中的砷。方法的检出限为 0 .2 μg/L ,对富马酸中As的测定结果与国标法结果相符 ,对w(As) =1 .5× 1 0 - 6的试样测定 1 2次 ,RSD为 4.8% ,加标回收率为 97.9%～ 1 0 7.5%。  相似文献   

Secondary geochemical dispersion in the Precambrian auriferous Hutti-Maski schist belt, Raichur district, Karnataka, India. Part I: anomalies of As, Sb, Hg and Bi in soil and groundwater     

N. R. Sahoo  H. S. Pandalai   《Journal of Geochemical Exploration》2000,71(3):353

The nature of secondary geochemical dispersion of As, Sb, Hg and Bi in soil and ground water of the semi-arid, tropical, Archaean, auriferous, Hutti-Maski greenstone belt has been investigated for identification of appropriate geochemical techniques for Au exploration in similar terrains.Results indicate that the <180 μm size-fraction of C-horizon soil is an appropriate sampling medium for delineating pedogeochemical anomalies of As, Sb, Hg and Bi related to gold mineralisation. These pedogeochemical anomalies along with anomalous values of alkalinity, chloride, sulphate, As and Sb in groundwater are controlled significantly by primary mineralisation located along shear zones in the greenstone belt. Arsenic anomalies in soil are broad, whereas, those of Sb and Bi are restricted to narrow zones directly over mineralised areas. In contrast, Hg anomalies around known mineralised areas are irregular and do not clearly demarcate the mineralised areas. The study indicates that anomalies of As, Sb and Hg in soil are principally hydromorphic, whereas those of Bi are clastic.The study recommends use of groundwater sampling at 2–3 km spacing with routine analysis of chloride, sulphate and alkalinity along with As and Sb in the first phase. This may be followed up with sampling of C-horizon of soils on a 1 km square grid for As-anomalies. Arsenic-anomalous areas may be sampled for As, Sb, Hg and Bi on a 500 m square grid for detailed exploration.  相似文献   

湘西表生环境中的砷及其生态健康效应   总被引：2，自引：0，他引：2  

卢新卫  王五一  解庆林  马东升 《地质科技情报》2000,19(4):79-82

湘西是金、砷、锑、汞等有色金属的重要成矿带,区域地层微量元素地球化学研究表明,湘西所出露的地层均显著富集砷,是砷的高区域地球化学异常区,元素存在相态的实验进一步表明,新元古界至寒武系中的砷以易迁移形式为主,母岩的这一性质决定了其风化土壤中的砷的含量较高,土壤砷的高背景特征受人为采矿活动的影响,局部地区呈现高异常,土壤、水体砷的高异常已影响到居民的身体健康。  相似文献   

北京市蔬菜和菜地土壤砷含量及其健康风险分析   总被引：58，自引：3，他引：55  

陈同斌  宋波  郑袁明  黄泽春  郑国砥  李艳霞  雷梅  廖晓勇 《地理学报》2006,61(3):297-310

通过对北京市蔬菜和菜地土壤砷含量状况进行大规模调查,研究了蔬菜和土壤砷含量及其健康风险,并筛选出抗砷污染能力强的蔬菜品种。根据蔬菜的消费量并兼顾品种多样性的原则,在北京市规模化蔬菜栽培基地 (采集蔬菜及土壤样品) 和蔬菜批发市场 (蔬菜样品) 共采集93种蔬菜400多份蔬菜样品和39个土壤样品系统地分析其砷含量。研究发现：北京市菜地土壤砷含量范围和平均含量分别为4.44~25.3和9.40 mg/kg,明显超过北京市土壤砷背景值;北京市蔬菜砷含量最高达0.479 mg/kg,平均含量为0.028 mg/kg,均未超过《食品中砷限量卫生标准》(GB4810-94) 的限量值,但其中有2个蔬菜样品 (萝卜和大蒜) 砷含量超过WHO/FAO制订的限量标准。北京市蔬菜砷含量在东偏北方向 (偏转11^o-30^o) 存在明显的"U"型趋势分布。裸露地蔬菜砷含量显著高于设施蔬菜。油菜、萝卜、小白菜、大葱、芥菜、黄瓜、大白菜和甘蓝抗砷污染能力较弱,而辣椒、云架豆、冬瓜、茄子、菠菜、西红柿、芹菜等抗砷污染能力则较强。北京市居民从蔬菜中摄入砷平均值为0.016 mg/(人·d),蔬菜砷对北京市部分人群存在一定的健康风险。  相似文献   

Mineralogical and Geochemical Constraints on Arsenic Mobility in a Philippine Geothermal Field     

Chelo PASCUA Tsutomu SATO Glenn GOLLA 《《地质学报》英文版》2006,80(2):230-235

Arsenic is usually associated with sulphide minerals formed in the geothermal environment. However, sulphide minerals are prone to dissolution after contact with meteoric water under surface oxidizing conditions. Secondary precipitates that form from the dissolution of the primary sulfides exert a greater influence on arsenic mobility in the geothermal environment. Fe-hydroxides have very good affinity with dissolved arsenate and are stable under most surface oxidizing conditions. Both amorphous silica directly precipitated from geothermal fluids and possibly a kaolinite alteration can host a small significant amount of arsenic. These silicates are also more stable under a wide range of pH and redox conditions.  相似文献   

氢化物原子荧光法测定天然水中痕量砷     

韦德平 《国土资源》1993,(1)

水样经王水分解,在酸度10％—25％介质中,As(v)用硫脲-抗坏血酸预还原,使As(Ⅱ)与硼氢化钾溶液生成气态氢化物(AsH_3),在原子荧光光度计上测定砷量。方法简便、快速、灵敏。方法检出限为0.08μg/l,相对标准偏差(R.S.D.)为5.05％,回收率为94.3％—105.4％。  相似文献   

Role of Quaternary stratigraphy on arsenic-contaminated groundwater from parts of Middle Ganga Plain,UP–Bihar,India     

Babar A. Shah 《Environmental Geology》2008,53(7):1553-1561

Late Quaternary stratigraphy and sedimentation in the Middle Ganga Plain (MGP) (Uttar Pradesh–Bihar) have influenced groundwater arsenic contamination. Arsenic contaminated aquifers are pervasive within narrow entrenched channels and flood plains (T₀-Surface) of fine-grained grey to black coloured argillaceous organic rich Holocene sediments (Newer Alluvium). Contaminated aquifers are often located close to distribution of abandoned or existing channels and swamps. The Pleistocene Older Alluvium upland terraces (T₂-Surface) made up of oxidized yellowish brown sediments with calcareous and ferruginous concretions and the aquifers within it are free of arsenic contamination. MGP sediments are mainly derived from the Himalaya with minor inputs from the Peninsular India. The potential source of arsenic in MGP is mainly from the Himalaya. The contaminated aquifers in the Terai belt of Nepal are closely comparable in nature and age to those of the MGP. Arsenic was transported from disseminated sources as adsorbed on dispersed phases of hydrated-iron-oxidea and later on released to groundwater mainly by reductive dissolution of hydrated-iron-oxide and corresponding oxidation of organic matter in aquifer. Strong reducing nature of groundwater is indicated by high concentration of dissolved iron (11.06 mg/l). Even within the arsenic-affected areas, dugwells are found to be arsenic safe due to oxyginated nature.  相似文献   

溆浦县龙王江锑金矿带地质特征   总被引：2，自引：0，他引：2  

鲍振襄 《湖南地质》1990,9(1):35-42

矿带主要赋存于板溪群五强溪组上段之韧性剪切断裂带内,由近80条规模不等、含金性不一的锑金石英脉组成。金的富集与金属硫(砷)化物关系密切,毒砂是其主要载金矿物。褪色带内硅化、毒砂化是近矿围岩标志,砷是其标型元素。  相似文献