东海钙质生物骨屑的矿物学特征     

朱而勤  李建华 《中国海洋大学学报(自然科学版)》1987,(4)

通过电镜、电子探针和X射线等项分析,对东海沉积物中的有孔虫、腹足类、双壳类、苔藓、珊瑚、海胆等骨屑进行了矿物学研究,确定了矿物成分与生物属种的关系,并基于有孔虫壳体化学成分将壳体分为均质壳和异质壳,生物碳酸盐中镁主要富集在方解石及镁方解石中,锶在方解石和镁方解石中的分配系数(D)相似,为0.11—0.14;在文石质骨屑中D=1.09-1.20。碳氧同位素组成与生物属种有明显关系。据一些有孔虫壳体氧同位素偏差值计算的水温来看,本次测定的有孔虫属种的骨屑不能作为理想的骨屑温度计。  相似文献   

黑海西北部冷泉碳酸盐岩的沉积岩石学特征及氧化还原条件的稀土元素地球化学示踪   总被引：3，自引：1，他引：2  

冯东  陈多福 《现代地质》2008,22(3):390-396

黑海西北部罗马尼亚大陆架(水深120m)和乌克兰陆坡(水深190m)发育冷泉碳酸盐岩结壳。XRD测试表明此结壳主要由高镁方解石和文石组成。结壳中与渗漏系统微生物活动有关的凝块和葡萄状文石等特殊的沉积组构非常发育。冷泉碳酸盐岩酸可溶部分(碳酸盐岩相矿物)的稀土元素含量很低(0.068×10-6~2.817×10-6),稀土元素页岩标准化配分模式显示罗马尼亚大陆架冷泉碳酸盐岩具有明显的Ce负异常,乌克兰陆坡冷泉碳酸盐岩具Ce的正异常,表明它们是分别在氧化和还原环境中沉积的。稀土元素和V、Cd和U等微量元素的含量在泥晶中最高,亮晶中最低,可能反映成岩过程对元素含量有控制作用。  相似文献   

Taxonomical and Biogeochemical Investigation of Elements in Holocene Mollusk Shells in the South and Southwestern Marmara Basin,Turkey     

Saday Azado?lu ALIYEV  Ali SARI  Bahadir ?KTEN 《《地质学报》英文版》2008,82(6):1160-1167

Concentrations of some heavy metals and trace elements such as Cr, Ga, Ni, Zn, Mo, Cu, Pb, Yb, Y, Nb, Ti, Sr, Ba, Mn, Sc, Co, V, Zr, Fe, Al, W, Se, Bi, Sb, As, Cd in recent mollusk shells and factors affecting their distribution and deposits collected from various depths in the southern and southwestern parts of the Marmara Sea are investigated. The distribution of the elements in the shells is categorized into four groups. Of these, concentrations of 12 elements （As, Bi, Cd, Co, Ga, Mo, Nb, Sb, Se, Sc, W and Yb） are below zero [（0.053-0.79）×10^-6]; concentrations of seven elements （Cr, Ni, Pb, V, Y, Zr and Cu） are （1.0-6.0）×10^-6; concentrations of four elements （Ti, Mn, Ba and Zn） are 10- 20×10^-6; and concentrations of five elements （Si, Al, Fe, Mg and Sr） are （47.44-268.11）×10^-6. The taxonomic characteristics of the 29 elements were studied separately in mollusk shells such as Chamalea gallina （Linn6）, Pitar rudis （Poli）, Nassarius reticulatus （Linn6）, Venerupis senescens （Coocconi）, Mytilus galloprovincialis （Lamarck）, Mytilaster lineatus （Gemelin in Linne） and Chlamys glabra. It was found that, in mollusk taxonomy, the elements have unique values. In other words, element concentrations in various mollusk shells depend mainly on the taxonomic characteristics of mollusks. In various bionomic environments different element distributions of the same species are attributed to the different geochemical characters of the each environment. Data obtained in this study indicate that the organisms are the most active and deterministic factors of the environment.  相似文献   

生物气CO_2还原途径中碳同位素分馏作用研究及应用   总被引：2，自引：0，他引：2  

李谨  胡国艺  张英  杨贵芳  崔会英  曹宏明  胡须龙 《地学前缘》2008,15(5):357

地质历史中,CO2/H2还原产甲烷作用对生物气的形成具有十分重要的意义。中国柴达木盆地第四系生物气主要为CO2/H2还原型生物气。笔者以CO2/H2还原生气理论为指导,进行不同初始碳同位素值和不同赋存状态碳源的生物模拟实验,研究CO2/H2还原产气过程中发生的碳同位素分馏作用。实验结果表明,产物中δ13CH4值与底物的δ13C值呈很好的正相关关系;在反应母质过量的情况下,碳源的赋存状态可以影响产物甲烷的碳同位素组成。以游离形式CO2还原产生的甲烷δ13C值,相对于以HCO3-、CO23-离子形式产生的甲烷δ13C值轻。通过柴达木盆地东部第四系生物气田实例分析,探讨了该区生物气的主要底物CO2的来源及赋存状态,对评价盆地生物气资源和有利勘探区预测有重要的参考价值。  相似文献   

Chrysophyte stomatocyst taxonomy — classification of snowflakes?     

Heikki Simola 《Journal of Paleolimnology》1991,6(3):257-260

The utility of classifying chrysophyte stomatocysts by their characteristic honeycomb and ridge patterns is questioned, because a strikingly similar expanding pattern appears on the surface of ionized polymer gels during osmotical swelling as a result of simple physical forces. The rapid accumulation of silicate into a spherical cyst inside a chrysophyte cell appears to be as a physical process sufficiently similar to result in an analogous pattern in microscopic scale. Chrysophyte stomatocysts that possess honeycomb or ridge patterns could be regarded as frozen moments of the pattern evolution during the silicate gel phase. As a consequence, such structures should have little taxonomical value.  相似文献   

Natural siliceous dust and human health： Pathways, toxicity, and impact     

Edward Derbyshire 《中国地球化学学报》2006,25(B08):219-219

Fine atmospheric dust includes mineral particles and aggregates, fibrous minerals and fibrous organic material. Generation, dislodgement and transport （deflation） of natural dust with the finer （〈4 microns） components suspended as silt-size aggregates, is widespread in and adjacent to the world＇s drylands, as well as deriving from volcanic vents. Silica is a highly fibrogenic agent in lung tissue. Long-term inhaling of siliceous dusts can lead to a number of fibrotic lung diseases, including natural （non-occupational） pneumoconioses （notably silicosis, but including asbestosis and others）. Different polymorphs of silica show different levels of toxicity in interaction with lung tissue. Particles with highly active surfaces may release radicals, causing cell damage. Some types of inhaled particulates are degraded by macrophages, but many are highly resistant and persist in the lungs, some stimulating fibroblastic cells to deposit collagen. Silicosis is an inflammation of the lung commonly caused by silicate mineral particles, leading to fibrosis. Three types are recognized： nodular pulmonary fibrosis （simple or chronic silicosis）, acute silicosis, and accelerated silicosis. Generally, finer particulates have greater oxidative capacity than the coarser fractions. They contain more reactive oxygen species, their greater bioreactivity making them more toxic to pulmonary tissue. Nevertheless, inhalation of large dust particles （〉 10μm） may constitute a health risk if the mineralogy is toxic, regardless of where the grains lodge in the respiratory system. Dust may absorb harmful gases, disease-generating bacteria and carcinogenic hydrocarbon compounds. Silica-related respiratory disease may also an exacerbate cardiac problem, and epidemiology suggests a link with tuberculosis. Quantification of dust loading and exposure requires study of spatial and temporal patterns, supported by meteorological analysis, airflow modeling and satellite-borne imagery. Some acute, short-term health impacts have been assessed using atmospheric and health records both before and after a dust storm or by comparison of populations within and outside such events. Analysis of the size, shape, mineralogy and geochemistry of ambient dust particulates provides information on natural dust sources, dust concentrations, and potential particulate toxicity, as well as providing a datum for assessment of human exposure levels.  相似文献   

生物气研究现状与勘探前景   总被引：16，自引：1，他引：16  

林春明  李艳丽  漆滨汶 《古地理学报》2006,8(3):317-330

综合论述了生物气的特征及其研究进展,着重探讨了生物气成因、地球化学特征、勘探研究现状、生物气形成机制和控制因素,并介绍了生物气系统概念和特征,最后叙述了生物气藏的分布和我国生物气藏的远景。生物气是在还原环境的生物化学作用带内有机质为厌氧微生物所分解的最终产物,它以甲烷为主,并含部分二氧化碳及少量氮气和其它微量气体组分,生物甲烷气δ13C1值一般小于-55‰。生物甲烷气的形成途径主要有乙酸发酵和CO2还原2种类型。生物气生成与其所处的沉积环境、古气候、有机质的类型和丰度、水介质性质、地质作用、沉积时间等众多因素密切相关。生物气埋藏浅,分布广泛,一般存在于三角洲、大陆架和部分陆相沉积环境中,储层时代主要为白垩纪、古近纪、新近纪和第四纪。白垩纪的储量最丰富,古近纪、新近纪次之,第四纪生物气藏的规模一般较小。我国生物气勘探研究历史虽然不长,但生物气资源量丰富,具有良好的勘探前景。  相似文献   

大洋粘土制备白炭黑后的铝回收实验研究     

刘娟娟  张培萍  石学法  吕华华  王宝君  邵冬梅 《吉林大学学报(地球科学版)》2006,(Z1)

为了回收大洋粘土制备白炭黑后残液中的Al3 ,并获得氧化铝超细粉体,实验选用NH3.H2O为沉淀剂,在常温下采用沉淀法使残液中Al3 以氢氧化铝形式沉淀并去除其它杂质离子,然后将得到的沉淀在1200℃灼烧,保温1h。利用IR和XRD测试了产物的物相组成和结构,证实实验可以获得纯度较高的α-Al2O3;而SEM和粒度分析结果显示产物粒度细小,部分颗粒可以达到纳米级;BET结果显示Al2O3的比表面积可达32m2/g。根据氧化铝结构和性能等优选的实验条件为大洋粘土的进一步开发利用提供了参考依据。  相似文献   

秦岭泥盆系硅岩岩石类型对比研究   总被引：2，自引：0，他引：2  

杨吉  李英 《吉林大学学报(地球科学版)》2002,32(4):325-328

硅岩可以通过化学沉积（真溶液或胶体沉淀）和内碎屑堆积而成。由于热水有较强的化学活动性，因而在水岩界面附近也会形成交代成因的硅岩。在许多情况下，硅岩既具有沉积岩的岩石学特征，又具有交代岩的岩石学特征，其成岩环境十分特殊。因此，虽然有许多地球化学方法可以区分不同类型的硅岩，但岩石学特征是最基本的和最直接的标志。  相似文献   

Unstable Climate Oscillations during the Late Holocene in the Eastern Bransfield Basin, Antarctic Peninsula     

Boo-Keun Khim  Ho Il Yoon  Cheon Yun Kang  Jang Jun Bahk 《Quaternary Research》2002,58(3):234

Core A9-EB2 from the eastern Bransfield Basin, Antarctic Peninsula, consists of pelagic (diatom ooze-clay couplets and bioturbated diatom ooze) and hemipelagic (bioturbated mud) sediments interbedded with turbidites (homogeneous mud and silt–clay couplets). The cyclic and laminated nature of these pelagic sediments represents alternation between the deposition of diatom-rich biogenic sediments and of terrigenous sediments. Sediment properties and geochemical data explain the contrasting lamination, with light layers being finer-grained and relatively rich in total organic carbon and biogenic silica content. Also, the high-resolution magnetic susceptibility (MS) variations highlight distinct features: high MS values coincide with clastic-rich sections and low MS values correspond to biogenic sections. The chronology developed for core A9-EB2 accounts for anomalous ages associated with turbidites and shows a linear sedimentation rate of approximately 87 cm/10³ yr, which is supported by an accumulation rate of 80 cm/10³ yr calculated from ²¹⁰Pb activity. The late Holocene records clearly identify Neoglacial events of the Little Ice Age (LIA) and Medieval Warm Period (MWP). Other unexplained climatic events comparable in duration and amplitude to the LIA and MWP events also appear in the MS record, suggesting intrinsically unstable climatic conditions during the late Holocene in the Bransfield Basin of Antarctic Peninsula.  相似文献