Shock metamorphism on the moon     

Yasunori Miura  Toshio Kato 《Celestial Mechanics and Dynamical Astronomy》1992,54(1-3):245-248

Shock metamorphism of the lunar samples is discussed. All types of lunar glasses formed by various-size collision-type impact are found as impact glass, ropy glass and agglutinates. The agglutinates bonded by crystal and glassy materials contain hydrogen and helium from the solar wind components. Lunar shocked minerals of plagioclase and silica show anomalous compositions and densities. There are typical two formation processes on planetary materials formed by shock events; that is (1) shocked quartz formed by silica-rich target rocks (esp. on evolved planets of the Earth and Mars), and (2) shocked silica with minor Al contents formed from plagioclase-rich primordial crusts of the Moon. The both shocked silica grows to coarse-grain normal crystals after high-temperature metamorphism which cannot distinguish the original main formation event of impact process.  相似文献   

FTIR Spectrum of Phenocryst Olivine as an Indicator of Silica Saturation in Magmas   总被引：3，自引：0，他引：3  

MATVEEV  S.; PORTNYAGIN  M.; BALLHAUS  C.; BROOKER  R.; GEIGER  C. A. 《Journal of Petrology》2005,46(3):603-614

Fourier Transform infrared (FTIR) absorption spectra of hydroxylwere measured on olivine phenocrysts from hydrous basaltic meltsthat originated in island-arc tectonic settings. The basalticmelts encompass a wide range of silica activities from orthopyroxene-saturatedhypersthene-normative to nepheline-normative compositions. Theintensities and wavenumber placement of hydroxyl absorptionbands correlate with the degree of silica saturation of theparent melt from which the olivine crystallized. Olivines fromsilica-undersaturated nepheline-normative melts absorb IR radiationin the wavenumber range 3430–3590 cm^–1 (Group 1).In contrast, olivines from orthopyroxene-saturated boniniticmelts exhibit hydroxyl absorption bands in the wavenumber range3285–3380 cm^–1 (Group 2). Olivines crystallizedat intermediate silica activities exhibit a combination of thetwo groups of hydroxyl IR bands, where the proportion of Group2 bands increases with increasing silica saturation of the parentmelt. The positions of hydroxyl absorption peaks observed herefor natural samples are consistent with previous measurementson experimentally annealed olivines. Thus protonation experimentscan be employed to make spectroscopically dry olivine structuresvisible by IR, yielding information on the silica saturationof the parental magmas. Hydroxyl concentrations in the studiedolivines were estimated to be 1–2 ppm, corresponding toan olivine–melt partition coefficient of (1·0 ±0·3) x 10^–4. KEY WORDS: nominally anhydrous minerals; olivine; water; mantle; silica activity; melt inclusions  相似文献   

A shrinking particle—shrinking core model for leaching of a zinc ore containing silica     

Vida Safari  Gilnaz Arzpeyma  Fereshteh Rashchi  Navid Mostoufi   《International Journal of Mineral Processing》2009,93(1):79-83

A new mathematical model was developed for leaching of zinc ores containing silicates such as hemimorphite which produce a gel during leaching with sulfuric acid. This model is based on the shrinking core model in which the particle size and the reacting core shrink simultaneously. It was shown that the actual dissolution time of the ore particles is longer than the time corresponding to the dissolution of chemical zinc oxide itself. It was suggested that because of the existence of silicates in the ore, a gelatinous layer was formed around the reacting core. Since the gel product is soft, it breaks apart when the particles collide and as a result, the particles shrink. However, a thin gelatinous layer always covers the reacting core which increases the mass transfer resistance and increases the leaching time. This model was applied to leaching of a zinc-rich tailing containing hemimorphite and the thickness of the gelatinous layer as well as the diffusion coefficient in this layer was determined.  相似文献   

Silica diagenesis in Eocene shallow-water platform carbonates, southern Pyrenees   总被引：1，自引：0，他引：1  

Jordi Giménez-Montsant  Francesc Calvet  & Maurice E. Tucker 《Sedimentology》1999,46(6):969-984

Spectacularly developed lower Eocene chert in the Corones platform carbonates of the Spanish Pyrenees is concentrated within a restricted, brackish-water, laminated ostracod-rich facies, which also contains abundant sponge spicules. The chert occurs as nodular, bedded and mottled varieties, and four petrographic types of quartz are developed: microquartz; length-fast (LF) chalcedony; megaquartz; and microspheres. δ¹⁸O values of chert range from 29·6‰ to 30·9‰ (SMOW), which correspond to a broad isotope rank common for biogenic and diagenetic replacement cherts. Calcian dolomite crystals with high Fe and Na are disseminated within the microquartz and LF-chalcedony, but are absent from the megaquartz and host carbonate. The chert is closely associated with desiccation cracks and with interstratal dewatering structures. Load casts are silicified, and laminae rich in sponge spicules are convoluted. Early cracks related to dewatering are filled by microquartz and quartz cements. Ostracod shells within chert are locally fractured; those in the host carbonate are commonly flattened. Late fractures are filled by LF-chalcedony and megaquartz. There is much evidence for the dissolution of sponge spicules and their calcitization in the carbonate host rock. Silica for the Corones cherts was derived from sponges during early diagenesis and shallow burial. Early mechanical compaction and sediment dewatering played a major role in sponge spicule dissolution, migration of silica-rich fluids and the consequent precipitation of chert. Quartz cements continued to be precipitated into the burial environment.  相似文献   

硅灰加固宁波软土的试验研究     

王泽平  王常明  江南  张在恒 《岩土工程技术》2020,(2):111-116,121

为探索硅灰对软土的力学性质的影响,以宁波鄞州地区一种淤泥质黏土为试样,掺入不同量的硅灰,对硅灰加固土的力学性质和结构特征进行了测试。采用三轴不固结不排水剪切试验,测试分析了不同掺入量的硅灰加固土的应力应变关系,通过扫描电镜SEM照片分析了不同硅灰掺入量的硅灰加固土的结构特征。结果表明:(1)硅灰可以提高软土的黏聚力,黏聚力随着硅灰掺入量的增加而增大;(2)随着硅灰掺入量的增加,硅灰加固土的抗变形能力呈先增加后减小的趋势;(3)同一围压条件下,随着硅灰掺入量的增加,硅灰加固土的破坏偏应力逐渐增加;(4)随着硅灰掺入量的增加,硅灰加固土中大孔隙逐渐减少,小孔隙逐渐数量增加,孔径<1μm的小孔隙组分逐渐占优。  相似文献   

福建北部近岸东台山岛火山岩形成时代、地球化学与古太平洋板块俯冲的响应          下载免费PDF全文

王飞飞  张勇  韩宗珠  宋维宇  吴浩  宁泽 《中国地质》2020,47(5):1426-1437

福建北部沿岸岛屿岩石组合以晚中生代火成岩为主,研究认为是古太平洋俯冲消减的产物,对反演洋盆构造演化具有重要的指示意义。本次对其中的福建北部海域东台山岛上广泛发育的酸性火山岩进行了锆石U-Pb定年以及全岩主微量地球化学分析工作。2件年代学样品分别获得了92 Ma和86 Ma的锆石U-Pb年龄,确定东台山岛火山岩形成于晚白垩世。全岩地球化学特征指示火山岩样品以酸性钙碱性岩石为主,整体富集Rb、Ba等元素,亏损Nb、Ta、Sr、Eu等元素,显示弧型岩浆岩的地球化学组成。研究认为东台山岛火山岩起源于古老下地壳变沉积岩熔融,并在浅层岩浆房内经历了不同程度的结晶分异过程。结合区域上晚中生代岩浆作用由陆向海的时空迁移特征,福建北部沿岸岛屿火山岩形成的深部动力学机制应该与古太平洋俯冲过程中的板片回转过程相关。  相似文献   

Adsorption characteristics of copper ion on nanoporous silica     

Yanhui Niu  Wenbin Yu  Zonghua Qin  Xin Nie  Shuguang Yang  Quan Wan 《Acta Geochimica》2019,(4):517-529

Adsorption by nanoporous media is critically involved in many fundamental geological and geochemical processes including chemical weathering,element migration and enrichment,environmental pollution,etc.Yet,the adsorption behavior of metal ions on nanoporous materials has not been systematically investigated.In this study,MCM-41 material with a monodisperse pore size(4.4 nm)and a large BET specific surface area(839 m^2/g)was hydrothermally prepared and used as a model silica adsorbent to study the adsorption characteristics of Cu^2+as a representative metal ion.The Cu^2+adsorption capacity was found to increase with increasing suspension pH in the range from 3 to 5 and to decrease in the presence of NaNO3.At 25℃,pH=5,and a solid-to-liquid ratio of 5 g/L,the adsorption capacity was determined to be 0.29 mg/g,which can be converted to a dimensionless partition coefficient of 45,indicating a strong enriching effect of nanoporous silica.The adsorption isotherm and kinetic data were fitted to several commonly used thermodynamic,kinetic,and diffusion models.The adsorption mechanism was also studied by Fourier transform infrared spectroscopy,X-ray photoelectron spectroscopy and synchrotron-based X-ray absorption spectroscopy.The results suggest that Cu2+ion adsorption is an entropy-driven endothermal process,possibly involving both outer-sphere and inner-sphere complexes.  相似文献   

南大洋普里兹湾沉积物中生物硅的溶解度研究          下载免费PDF全文

扈传昱  孙维萍沈忱 张海生 《极地研究》2012,24(4):339-345

本文利用中国南极科学考察航次获得的沉积物样品,采用分批（batch）实验方法,获取实验室生物硅溶解度,并结合间隙水中可溶性硅剖面,对普里兹湾沉积物中生物硅的溶出过程进行了初步研究。研究结果如下：在25℃,pH 8条件下,普里兹湾IV-10、 IS-4站表层沉积物中生物硅的实验室溶解度分别为1936、1539μmol/dm3,不同层次沉积物溶出结果显示随深度增加溶解度值降低。根据实验室溶解度数据与间隙水硅酸盐Cd的分析比较,表明研究站位沉积物生物硅的早期成岩过程中生物硅的溶出还伴随有其他化学过程。  相似文献   

The silica supersaturated waters of northern Evia and eastern central Greece     

G. Stamatis  E. Gartzos 《水文研究》1999,13(17):2833-2845

The area of north Evia and eastern central Greece is characterized by strong geomorphological contrast and is built up mainly of consolidated rocks. Unconsolidated young sediments of Pleistocene to Holocene age cover the valley and basin flats, forming the most productive aquifers in this area. However, two more types of aquifers can be distinguished within the consolidated rock area. The first one is associated with karstified limestones and the second with strongly tectonized ultramafic rocks. The schist–chert formation, with intercalations of shales and cherts, seals the ultramafic masses underneath. Surface and spring waters associated with ultramafic rocks in north Evia and eastern central Greece were studied. Two types of water can be distinguished: (1) high Mg²⁺ and SiO₂ , bicarbonate as the dominant anion, pH 7·4–9·2, temperature 9·5–16·3 °C, low TDS (total dissolved solutes) (459–1037 mg/l), found both in peridotite and serpentinite areas, classified as Mg–HCO₃ type; (2) high Ca²⁺, low Mg²⁺ and SiO₂ , hydroxyl ion as the major anion, pH 11·2, temperature 28 °C, very low TDS (122 mg/l), found in peridotite areas, classified as Ca–OH type. The studied waters are highly supersaturated with respect to quartz, amorphous silica, brucite and most low temperature magnesium silicates (antigorite, sepiolite, talc, etc.). These waters show relatively narrow SiO₂ concentration ranges and a trend parallel to the amorphous silica saturation surface. The silica supersaturated waters have the potential to precipitate silica and consequently could affect the people of the local communities that use it as drinking water, causing health problems (kidney stones). Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

东昆仑西段祁漫塔格群的重新厘定   总被引：5，自引：0，他引：5  

王向利  高小平  刘幼骐  李新林  周小康  杜少喜  崔继刚  戴新宇  曾忠诚 《西北地质》2010,43(4):168-178

通过区域地质调查和研究,认为前人所建立的的祁漫塔格群或滩间山群包括了不同时代的浅变质碎屑岩、中酸性火山岩及基性-超基性岩。根据在东昆仑原划奥陶系祁漫塔格群第一亚群(下部碎屑浊积岩)中采集到早志留世笔石化石组合(这是首次证实东昆仑地区存在志留系地层)及同位素测年资料(鸭子大板火山岩年龄),其时代包含了奥陶纪、志留纪和三叠纪等,根据中国地层指南及中国地层指南说明书和地层清理,对祁漫塔格群进行了解体,将其重新厘定为奥陶纪滩间山群(OT)、志留纪白干湖岩组(Sb)弧后盆地复理石沉积和鸭子泉组(Sy)岛弧火山岩、石炭纪鸭子大坂硅质岩(S i)、三叠纪鄂拉山组(T3e)、蓟县纪狼牙山岩组(Jx l)和南华—奥陶纪阿牙克库木湖蛇绿混杂岩[(N h—O)aΣ]。该成果对于祁漫塔格地区早古生代地层划分对比、构造演化提供了重要新证据。  相似文献