成都平原区水稻土成土剖面Cd形态分布特征及影响因素研究   总被引：8，自引：2，他引：6  

侯青叶  杨忠芳  杨晓燕  杨艳  赖木收 《地学前缘》2008,15(5):36

成土过程中不同形态镉(Cd)迁移转化的影响因素研究对于了解Cd的地球化学行为具有非常重要的意义。以四川省成都平原区农田生态系统水稻土剖面中不同形态Cd分布特征为例,探讨成土过程中不同形态Cd的迁移转化影响因素及其生态危害性。结果表明:总量Cd、离子交换态Cd和碳酸盐Cd均表现出表层富集,深层含量稳定的特征;岷江流域和沱江流域水稻土Cd含量的背景值分别为0.147,0.215mg·kg-1。外源输入耕层土壤中Cd主要为活动态,其增加量占Cd总量增加量的60.71%~90.52%,向下垂向迁移能力非常弱。成土过程随着土壤中Cd总量增加,稳定态Cd含量显著增加,而活动态Cd含量明显降低。土壤的pH值主要对碳酸盐态Cd含量有影响,pH值越大,其含量越高;随着土壤成熟度增高,粉粒和粘粒含量增加的同时,残渣态Cd含量显著降低,而有机结合态Cd含量显著增高。耕层土壤中Cd的生物有效性系数高达0.59~0.65,已经严重地影响到农作物安全。  相似文献   

A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance     

Delphine Aran  Armand Maul  Jean-Franois Masfaraud 《Comptes Rendus Geoscience》2008,340(12):865-871

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH₃)₆³⁺ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.  相似文献   

Changes to cadmium associations in canal sediments on drying and oxidation     

Samantha R. Cook John M. Chamock Andrew Parker 《中国地球化学学报》2006,25(B08):247-247

The mainly 19th Century canal system in the UK, largely managed by British Waterways, has been increasingly brought back into operation over the last few decades, and is now widely used for both leisure, and, increasingly, transport. Both initial and routine dredging of the canal sediment is carried out and these sediments are generally disposed of to land. Because many of the canals were connected with primary industries, their sediments can locally be significantly contaminated with heavy metals, and the behaviour of these metals under differing redox conditions, when introduced into a new environment （i.e., on land） is of importance for environmental risk-assessment purposes. Canal sediments are often rich in sulfidic mineral phases, and we have attempted to quantify the influence of these sulfidic phases on the release and retention of metals in dredged canal sediments, using a combination of traditional chemical techniques （e.g. sequential extraction） and X-ray absorption spectroscopy （XAS）. Sediment samples have been collected from urban fresh-water canals, one in the British Midlands and one in Northern France. It appears from XAS that Cd is largely associated with oxygen in air-dried sediment, and with sulphur in vacuum-dried sediment.  相似文献   

Chloride removal from wastewater by thermally treated hydrotalcite     

《中国地球化学学报》2006,25(B08):255-256

  相似文献   

镉的地球化学研究现状及展望   总被引：13，自引：0，他引：13  

叶霖潘自平  李朝阳刘铁庚 夏斌 《岩石矿物学杂志》2005,24(4):339-348

镉是重金属有毒元素,其环境污染一直是众多学者研究的焦点。近年来研究发现,镉等分散元素并不“分散”,它在特定的条件下会富集,甚至形成独立矿床或矿体,因此有必要对镉等分散元素的地球化学行为进行重新认识和再研究。本文介绍了有关镉的分布和赋存状态的一些研究进展,总结了我国镉矿资源的分布及特点和地球化学研究现状,提出应加强镉的超常富集机制、铅锌矿床表生地球化学过程中镉的释放及其对环境的影响方面的研究。  相似文献   

环境矿物材料治理镉（Cd^2＋）污染研究进展   总被引：4，自引：0，他引：4  

商平  王丽娜 《岩石矿物学杂志》2005,24(6):681-685

近年来,环境矿物材料以其经济、有效、无二次污染等特点,在重金属废水处理和土壤修复方面显示出了众多优势,可替代传统的镉污染处理方法。本文综述了国内外环境矿物材料在处理镉污染方面的研究进展,并对今后应用环境矿物材料治理镉污染提出了一些建议。  相似文献   

氯化钠浮选剂概述   总被引：2，自引：0，他引：2       下载免费PDF全文

王爱丽  张全有  李海民 《盐湖研究》2003,11(4):42-46

综述了各类氯化钠浮选剂对氯化钠的浮选。并对各类浮选剂的浮选性能进行了比较。  相似文献   

Adsorption of Copper, Nickel, and Cadmium on Goethite in the Presence of Organic Ligands   总被引：2，自引：0，他引：2  

Diane Buerge-Weirich  Philippe Behra  Laura Sigg 《Aquatic Geochemistry》2003,9(2):65-85

Adsorption of copper, cadmium and nickel at low concentrations on goethite was studied in the presence of the simple organic ligands oxalate, salicylate, and pyromellitate. The experimental metal adsorption behavior was compared to calculations with a surface complexation model to evaluate the most important interactions. Oxalate mostly decreased Cu and Ni adsorption at high pH-values by competition between solution and surface complexation but had no effect on Cd adsorption. Cu adsorption in the presence of oxalate below pH 6 could best be described by defining a ternary complex of type A (surface-metal-ligand). Salicylate had only minor effects on metal adsorption. The adsorption of Cu in the presence of salicylate above pH 5 could be explained by a ternary complex of type A. Pyromellitate increased the adsorption of Cu and Cd in the acidic pH-range, likely by formation of ternary surface complexes of type B (surface-ligand-metal).  相似文献   

无水氯化镍及芳烃基二膦酸四乙酯的制备          下载免费PDF全文

董亚萍 《盐湖研究》1997,5(2):57-63

1，4—二溴苯，4，4’—二溴联苯、4，4’—二溴三联和亚磷酸三乙酯在催化剂无氯化镍催化下，干燥氮气保护．反应得到相应的有机二磷酸四乙酯。  相似文献   

确定干旱—半干旱地区降水入渗补给量的新方法——氯离子示踪法   总被引：7，自引：0，他引：7  

陈植华  徐恒力 《地质科技情报》1996,15(3):87-92

在干旱－半干旱地区由于入渗水分大部分滞留在包气带中，强烈地蒸发、蒸作用导致包气带中土壤水的氯离子浓度改变。氯离子示踪方法从质量守恒角度，通过比较土壤水分的氯离子浓度和降水输入的氯离子浓度大小，可以定量确定降水入渗量和降水入渗补给的历史变化过程。本文介绍了目前国外应用较普遍的氯离子均衡法和氯离子累积法，并讨论了方法应用时存在的一些问题。  相似文献