全文获取类型
收费全文 | 339篇 |
免费 | 96篇 |
国内免费 | 128篇 |
专业分类
大气科学 | 16篇 |
地球物理 | 74篇 |
地质学 | 255篇 |
海洋学 | 106篇 |
综合类 | 27篇 |
自然地理 | 85篇 |
出版年
2024年 | 1篇 |
2023年 | 4篇 |
2022年 | 14篇 |
2021年 | 13篇 |
2020年 | 19篇 |
2019年 | 17篇 |
2018年 | 12篇 |
2017年 | 15篇 |
2016年 | 10篇 |
2015年 | 18篇 |
2014年 | 24篇 |
2013年 | 31篇 |
2012年 | 18篇 |
2011年 | 30篇 |
2010年 | 22篇 |
2009年 | 29篇 |
2008年 | 24篇 |
2007年 | 34篇 |
2006年 | 33篇 |
2005年 | 25篇 |
2004年 | 24篇 |
2003年 | 13篇 |
2002年 | 10篇 |
2001年 | 9篇 |
2000年 | 18篇 |
1999年 | 15篇 |
1998年 | 12篇 |
1997年 | 12篇 |
1996年 | 6篇 |
1995年 | 10篇 |
1994年 | 10篇 |
1993年 | 9篇 |
1992年 | 1篇 |
1991年 | 5篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有563条查询结果,搜索用时 31 毫秒
31.
Aspects of communities and events in the concentrating ponds (S.G. 1.130 to 1.214) and salt crystallizing ponds (S.G. 1.215 to 1.264) of solar saltworks pertinent to salt manufacture are described. Communities that aid salt manufacture enable continuous and efficient production of high quality salt at a saltworks' design capacity, and they provide important controls on levels of organic matter in the brine. Fluctuating salinities, high concentrations of nutrients, and petroleum products are disturbances that causeAphanothece halophytica andDunaliella salina to release excessive quantities of organic matter, and that suppress or cause death to nutrient stripping organisms. Disturbances result in decreased quality and quantity of salt and increased costs for salt harvest, washing, and pond upkeep. Organic matter can be controlled by management techniques that keep nutrient stripping communities at proper levels and maintain a narrow and unchanging range of salinities in each pond, by constructing pond dikes able to withstand wind and water erosion, and by preventing spills of petroleum products in the ponds. 相似文献
32.
本文利用等温溶解度法测定了H~+,Li~+,Mg~(2+)//Cl~-—H_2O四元水盐体系在—10℃±0.1℃时的溶解度并绘制了等温相图。相图由HCl·MgCl_2·7H_2O、MgCl_2·8H_2O、HCl·6H_2O和LiCl·2H_2O四个相区构成,只有一个零变量点I:LiCl·2H_2O+MgCl_2·6H_2O+HCl·MgCl_2·7H_2O+L_(?)利用坐标变换和直线外推法,对溶解度数据进行处理后,用湿渣结线法解决了低温平衡固相较难确定的问题。 相似文献
33.
Products and mechanisms for the gas-phase reactions of NO3 radicals with CH2=CHCl, CH2=CCl2, CHCl=CCl2,cis-CHCl=CHCl andtrans-CHCl=CHCl in air have been studied. The experiments were carried out at 295±2 K and 740±5 Torr in a 480-L Teflon-coated reaction chamber and at 295±2 K and 760±5 Torr in a 250-L stainless steel reactor. NO3 was generated by the thermal dissociation of N2O5. Experiments with15NO3 and CD2CDCl have also been performed. The initially formed nitrate peroxynitrates decay into carbonyl compounds, nitrates, HCl and ClNO2. In adidtion, there are indications of nitrooxy acid chlorides being produced. The reactions with CH2=CCl2 and CHCl=CCl2 are more complex due to release of chlorine atoms which eventually lead to formation of chloroacid chlorides.A general reaction mechanism is proposed and the observed concentration-time profiles of reactants and products are simulated for each compound. The rate constants for the initial step of NO3 addition to the chloroethenes are determined as: (2.6±0.5, 9.4±0.9, 2.0±0.4 and 1.4±0.4) × 10–16 cm3 molecule–1 s–1 for CH2=CHCl, CH2=CCl2, CHCl=CCl2 andcis-CHCl=CHCl, respectively. 相似文献
34.
本文研究了镉-5-Br-PADAP-溴化十六烷基三甲基铵-peregalo显色体系的光谱特征,显色条件,络合物的组成、干扰及其消除。实验证明该法灵敏度高,ε=1.3×10~5l·mol~(-1)·cm~(-1)。选择性较好,显色酸度范围较宽pH=8.0-9.5,络合物最大吸收波长为560nm,镉在0-10μg/25ml的含量范围内服从比尔定律。经标准水样、工业废水及生活用水验证,不经分离可测定水中PPb级的微量镉。 相似文献
35.
We report on the use of X-ray diffractometry under controlled conditions of temperature and relative humidity (RH-XRD) for
the investigation of NaCl deliquescence in the pore space of glass filter frits, which were used as model substrates. The
study confirms that RH-XRD is an appropriate experimental technique for the in situ observation of phase transformation in
porous materials. It is used for an investigation of both the deliquescence kinetics and the deliquescence humidity within
pores of different median pore diameter. Several major influences affecting deliquescence rates in the pore space close to
the surface of a porous material are discussed. It appears that quite short-term variation of ambient relative humidity, e.g.,
typical daily fluctuations, might induce damaging deliquescence–crystallization cycles within the pore space of building materials.
In agreement with theoretical considerations it was found that confinement of NaCl crystals in pores with median diameters
in the range 1.4–70 μm does not affect the deliquescence humidity of the salt. 相似文献
36.
土壤中铅铜锌镉的吸附特性 总被引:5,自引:0,他引:5
以徐州王庄矿(WZK)、奎河(KH)、背景-1(BG-1)和背景-2(BG-2)等4个土壤样品为供试对象,加入不同浓度梯度的铅、铜、锌、镉离子,通过静态实验研究了铅、铜、锌、镉的吸附特性。结果表明,土壤对4个重金属的吸附量与加入到土壤中的重金属离子浓度呈正相关性,它们之间大部分满足线性相关关系。在4个土壤样品中加入铅、铜、锌、镉离子的初始浓度比为10:10:10:1时,平衡浓度为Czn〉Ccu〉CPh〉Ccd,吸附量为Scd〉SPh〉Scu〉Szn,4个土壤样品对铅、铜、锌、镉离子的吸附能力依次为WZK〉KH〉BG-2〉BG-1。在所选实验条件下,土壤对铅、铜、锌、镉的吸附能力受土壤中铅、铜、锌、镉的含量、土壤有机质含量、阳离子交换量、土壤饱和含水量和土壤的pH值影响较大。 相似文献
37.
38.
39.
40.
WINDOW FACTOR ANALYSIS:THEORETICAL DERIVATION AND APPLICATION TO FLOW INJECTION ANALYSIS DATA 总被引:1,自引:0,他引:1
EDMUND R.MALINOWSKI 《地理学报(英文版)》1992,(1)
Window factor analysis(WFA)is a self-modeling method for extracting the concentration profiles ofindividual components from evolutionary processes such as flow injection,chromatography,titrationsand reaction kinetics.The method takes advantage of the fact that each component lies in a specificregion along the evolutionary axis,called the‘window’.Theoretical equations are derived.The methodis used to extract the concentration profiles and spectra of seven bismuth species from data obtained byGemperline and Hamilton,who injected bismuth perchlorate into a flowing stream of hydrochloric acid. 相似文献