使用纳米碳酸钙降低低孔低渗煤层气储层伤害          下载免费PDF全文

谷穗  蔡记华  常德武  维克多·费多罗维奇·契霍特金 《地球科学》2015,40(6):1093-1100

传统暂堵剂难以封堵低孔低渗煤层气储层中的大量纳米级别孔隙.通过煤岩显微观测、钻井液基本性能测试、泥饼清除实验、煤岩孔隙分布实验和气体渗透率实验,探讨了纳米碳酸钙降低低孔低渗煤层气储层伤害的效果.结果表明:纳米碳酸钙材料只有在水溶液中保持纳米级的分散状态,才可能对低渗煤岩起到暂堵作用;基于纳米碳酸钙的可降解钻井液既能封堵低孔低渗煤岩中微米级别孔隙,也能封堵其中的纳米级别孔隙;经过生物酶和稀盐酸双重解堵后,煤岩渗透率恢复值达77.17%~97.98%,储层保护效果好;煤岩孔隙分布实验可以在纳米尺度上研究纳米材料对低孔低渗储层的暂堵效果.研究成果可为纳米碳酸钙在低孔低渗煤层和页岩钻完井过程中的应用奠定良好技术基础.   相似文献   

脑动脉粥样硬化斑块中钙化物矿物学特征研究     

李源  王长秋  孟繁露  李艳  鲁安怀  杨重庆  于启  李康 《岩石矿物学杂志》2015,34(6):963-970

脑动脉钙化与脑动脉系统病变有密切联系。本文从矿物学角度出发,使用偏光显微镜(POM),扫描电子显微镜(SEM)、透射电子显微镜(TEM)、显微红外光谱(micro-FTIR)、同步辐射微区X射线衍射(μ-SRXRD)以及同步辐射微区X射线荧光光谱(μ-SRXRF)对脑动脉粥样硬化斑块中的钙化样品进行了研究。结果表明,钙化主要有球状和块状两种集合体形态,球状钙化具有同心环状或同心放射状构造,直径约0.3~5μm;块状钙化中可见球状钙化被杂乱分布的柱状纳米晶体包裹。钙化主要矿物相为B型碳羟磷灰石(B-CHA),并含Na、Mg、Zn、Fe和Sr等元素,与主动脉钙化中的矿物组成类似。钙化在其形成初期呈分散的小球状,后期大量球体逐渐被CHA纳米晶体充填胶结形成了致密的块状钙化。  相似文献   

WATER　RESOURCES　TRANSFORMATION　AND　WATER　QUALITY　VARIATION　IN　THE　URUMQI　RIVER　BASIN     

曲耀光  骆鸿珍 《中国地理科学(英文版)》1995,5(4):325-335

ＷＡＴＥＲＲＥＳＯＵＲＣＥＳＴＲＡＮＳＦＯＲＭＡＴＩＯＮＡＮＤＷＡＴＥＲＱＵＡＬＩＴＹＶＡＲＩＡＴＩＯＮＩＮＴＨＥＵＲＵＭＱＩＲＩＶＥＲＢＡＳＩＮＱｕＹａｏｇｕａｎｇ（曲耀光）；ＬｕｏＨｏｎｇｚｈｅｎ（骆鸿珍）（ＬａｎｚｈｏｕＩｎｓｔｉｔｕｔｅｏｆＧ...  相似文献   

Propagation of Extremely Low Frequency Waves Through the Ionosphere     

Singh  Ashok K.  Narayan  D.  Singh  R. P. 《Earth, Moon, and Planets》2002,91(3):161-179

The propagation features of extremely low frequency electromagnetic waves through the multicomponent ionospheric plasma are studied. It is shown that at relatively lower frequencies refractive index for right hand mode is higher than the left-hand mode, which is reversed at higher frequencies. The thermal temperature of plasma particle causes decrease in phase and group velocities of both right and left-hand modes. The crossover frequencies for different plasma models are computed and variation with ion concentration and thermal velocity is studied. Explicit expression for group velocity and travel time has been derived and studied numerically. Finally, we have presented simulation of the ion whistler spectrograms for Hydrogen, Helium and Oxygen ions present in the ionospheric plasma. The results are compared with the experimentally detected hydrogen and helium ion whistlers. The importance of the present study in the exploration of ionospheric plasma is illustrated.  相似文献   

Identification and evolution of hydrogeochemical processes in the groundwater environment in an area of the Palar and Cheyyar River Basins,Southern India   总被引：5，自引：0，他引：5  

N.?Rajmohan  L.?ElangoEmail author 《Environmental Geology》2004,46(1):47-61

The Palar and Cheyyar River Basins in Tamil Nadu state of Southern India are characterised by different geological formations, and groundwater is the major source for domestic, agricultural and other water-related activities. Hydrogeochemical studies were carried out in this area with the objective of identifying the geochemical processes and their relation to groundwater quality. Groundwater samples were collected once a month from 43 groundwater wells in this area from January 1998 to July 1999. Sampling procedures and chemical analysis were carried out as per the standard methods. Chemical data are used for mathematical calculations and graphical plots to understand the chemical process and its relation to the groundwater quality. The chemical composition of groundwater in the central part of the study area mainly depends on the recharge from lakes and the river, which is explained by a mixing mechanism. In addition, weathering of silicate minerals controls the concentration of major ions such as sodium, calcium, magnesium and potassium in the groundwater of this area. Further, the activity ratios indicate that the groundwater is in equilibrium with kaolinite, smectite and montmorrillonite. The reverse ion exchange process controls the concentration of calcium, magnesium and sodium in hard rock formations, and dissolution of carbonate minerals and accessory minerals is the source of Ca and Mg, in addition to cation exchange in the sedimentary formations. In general, the chemical composition of the groundwater in this area is influenced by rock–water interaction, dissolution and deposition of carbonate and silicate minerals, ion exchange, and surface water interactions.  相似文献   

Residence, Resorption and Recycling of Zircons in Devils Kitchen Rhyolite, Coso Volcanic Field, California   总被引：15，自引：1，他引：14  

MILLER  JONATHAN S.; WOODEN  JOSEPH L. 《Journal of Petrology》2004,45(11):2155-2170

Zircons from the Devils Kitchen rhyolite in the PleistoceneCoso Volcanic field, California have been analyzed by in situPb/U ion microprobe (SHRIMP-RG) and by detailed cathodoluminescenceimaging. The zircons yield common-Pb-corrected and disequilibrium-corrected²⁰⁶Pb/²³⁸U ages that predate a previously reported K–Arsanidine age by up to 200 kyr, and the range of ages exhibitedby the zircons is also approximately 200 kyr. Cathodoluminescenceimaging indicates that zircons formed in contrasting environments.Most zircons are euhedral, and a majority of the zircons areweakly zoned, but many also have anhedral, embayed cores, witheuhedral overgrowths and multiple internal surfaces that aretruncated by later crystal zones. Concentrations of U and Thvary by two orders of magnitude within the zircon population,and by 10–20 times between zones within some zircon crystals,indicating that zircons were transferred between contrastingchemical environments. A zircon saturation temperature of 750°Coverlaps within error a previously reported phenocryst equilibrationtemperature of 740 ± 25°C. Textures in zircons indicativeof repeated dissolution and subsequent regrowth are probablycaused by punctuated heating by mafic magma input into rhyolite.The overall span of ages and large variation in U and Th concentrations,combined with calculated zircon saturation temperatures andresorption times, are most compatible with crystallization inmagma bodies that were emplaced piecemeal in the crust at Cosoover 200 kyr prior to eruption, and that were periodically rejuvenatedor melted by subsequent basaltic injections. KEY WORDS: zircon geochronology; residence time; rhyolite; ion microprobe; California  相似文献   

原子吸收分光光度法快速测定铬铁矿中钙、镁、锰   总被引：2，自引：0，他引：2  

熊艳 《安徽地质》2006,16(4):270-272

通过在标液中加入相应的Sr来消除离子干扰,采用原子吸收分光光度法快速测定CaO、MgO、MnO的含量,方法经国家标准物质验证,其RSD<2%(n=6)。其结果与标准值相符。方法达到了准确、简便、快速、实用性强。  相似文献   

罗布泊红柳沙包落叶阳离子含量及环境指示意义   总被引：1，自引：0，他引：1       下载免费PDF全文

沈睿媛  李秀丽  夏训诚  赵元杰 《干旱区地理》2012,35(1):109-115

 红柳沙包沉积纹层是恢复古环境序列的一种新方法。通过对罗布泊地区红柳沙包沉积纹层中红柳落叶阳离子含量以及与环境变化关系研究表明：K+、Na+、Ca2+、Mg2+等4种阳离子平均含量分别为3.70 mg/g、40.33 mg/g、13.67 mg/g和8.08 mg/g,变化幅度排序为Ca2+ > K+ > Mg2+ > Na+。4种阳离子含量年际变化都较为明显,且变化规律较为一致,4种阳离子含量变化间的相关系数为0.653 0 ~ 0.813 8,表现为良好的正相关关系;各种阳离子与4种阳离子总量变化的相关系数为0.814 4 ~ 0.959 9,其中Na+含量与4种阳离子总量变化的相关系数最高,表明可以用Na+含量的变化或阳离子总量的变化分析变化趋势。阳离子含量与气温变化呈良好的正相关、与年降水量和湖水面积变化呈负相关;地下水水位降低、水质变差时,土壤水质也变差,阳离子含量增加;反之,地下水水位升高、水质变好时,土壤水质变好,阳离子含量降低。红柳落叶有机质阳离子含量的变化进一步验证了利用红柳沙包沉积纹层计年的可靠性和对罗布泊环境变化的可行性。  相似文献   

板桥稀土矿遥感找矿信息提取与矿产预测研究   总被引：1，自引：0，他引：1  

章钦瑜  张登荣  黄国成  朱骏 《国土资源遥感》2012,(1):120-126

通过对离子吸附型稀土矿成矿规律的分析,从浙江省板桥地区的遥感地质特征研究入手,在研究区地表范围内进行稀土遥感找矿信息的提取。首先利用SPOT图像和DEM数据构建的坡度数据对与稀土成矿相关的地貌单元进行解译;然后通过光谱特征分析和基于ASTER图像的矿物遥感异常提取,获取与成矿相关的高岭土、绢云母、绿泥石等风化特征矿物的分布信息;最后叠合分析地貌、坡度及异常提取结果,进行稀土遥感找矿预测。与地质调查资料及化探数据的对比分析证实,上述方法对圈定1∶5万的大比例尺离子吸附型稀土矿分布范围是有效的,可为更详细的稀土矿产资源潜力评价提供依据。  相似文献   

Nuclear modification factor for quarkonium production in high energy proton-nucleus collisions within the parton saturation approach     

Érison S. Rocha  Magno V. T. Machado 《Astronomische Nachrichten》2024,345(2-3):e230165

In this work, we analyze nuclear effects in the inclusive production of quarkonium in proton-nucleus collisions at high energy regime. A theoretical framework that includes initial state effects like nuclear shadowing and gluon density saturation is considered. Numerical results for nuclear modification factor, $R_{pA}(y)$, as a function of meson rapidity in proton-nucleus collisions are presented. The parameter-free predictions are compared to the available data from the Large Hadron Collider. Discussion on the main theoretical uncertainties is made, with emphasis on the phenomenological models for the nuclear saturation scale.  相似文献