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31.
The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface. 相似文献
32.
33.
在分散度不同的区域内进行区域采样用于水中硫酸根离子的测定,结果令人满意。应用此方法测定硫酸根离子的线性范围为200.0~3000mg/L;进样频率为120次/h;相对标准偏差为1.70% 相似文献
34.
大气季节内振荡对印度洋—西太平洋地区热带低压/气旋生成的影响 总被引:24,自引:4,他引:24
文中利用EOF分析大气季节内振荡 (MJO)的时空变化的方法 ,研究了 1996年 9月~ 1997年 6月间的MJO活动对生成在印度洋—西太平洋海域的热带低压 /气旋的影响。结果发现 ,除西北太平洋之外 ,发生在其他区域的热带低压 /气旋有半数以上生成在向东移动的MJO的湿位相中。伴随MJO的向东传播 ,热带低压 /气旋平均生成位置也随之向东移动 ,而生成在西北太平洋的热带低压 /气旋分别受到向东和向西传播的MJO影响 相似文献
35.
A Reflection on Mg, Cd, Ca, Li and Si Isotopic Measurements and Related Reference Materials 总被引:6,自引:1,他引:6
Jean Carignan Damien Cardinal Anton Eisenhauer Albert Galy Mark Rehkamper Frank Wombacher Nathalie Vigier 《Geostandards and Geoanalytical Research》2004,28(1):139-148
This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis. 相似文献
36.
Yin Xiulan China Institute of Geo-environmental Monitoring Beijing China Hu Ping Faculty of Earth Sciences China University of Geosciences Wuhan China Northeastern Illinois University Chicago IL USA Li Dien Division of Earth Environmental Sciences Los Alamos National Laboratory Los Alamos NM USA 《中国地质大学学报(英文版)》2004,15(4):355-360
The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ~1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=~5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献
37.
S. Y. Fu Q. G. Zong Z. Y. Pu C. J. Xiao A. Korth P. Daly H. Reme 《Surveys in Geophysics》2005,26(1-3):241-254
In this paper we report energetic ion behavior and its composition variations observed by the Cluster/RAPID instrument when the spacecraft was travelling in the high latitude magnetospheric boundary region on the day of the 31 March, 2001, strongest magnetic storm in the past 50 years. The Dst index reached −360 nT at about 09:00 UT. During its early recovery phase, large amounts of oxygen and helium ions were observed; the ratio of oxygen to hydrogen in the RAPID energy range reached as high as 250%, which suggests that the observed energetic particles might be of magnetospheric origin. The observations further show that enhanced energetic electron fluxes are confined in a very narrow region, while protons have occupied a larger region, and heavy ions have been observed in an even larger region. The flux of energetic electrons show a slight enhancement in a region where the magnetic field magnitude is around zero. These observed energetic ions could be quasi-trapped by the current sheet in the stagnation region of the cusp. 相似文献
38.
Water soluble components of PM10 Chongqing, China 总被引:1,自引:0,他引:1
The concentrations of water soluble ions (Na+, NH4
+, K+, Mg2+, Ca2+, NO3
-, Cl-, and SO
4
2-
) in PM10 samples collected on cellulose filters by a medium-volume cascade impactor were determined, which were obtained from three
kinds of areas in Chongqing: industrial area (Jiulongpo district), commercial and residential area (Jiangbei district) and
background area (Jinyun Mountain in the Beibei district). The results showed that except for the background site, the annual
average values of PM10 are 23% – 61% higher than the national air quality standard (GradeII) (0.1 mg/m3), even that the value of the control site is still 20% higher than American standard (0.05 mg/m3). This implied that serious pollution of fine particles occurred in Chongqing. Nine kinds of soluble ions in water of PM10 were analyzed by ion chromatography (IC) and the annual average concentrations follow the order of [SO
4
2-
] > [NO3
-] > [Cl-] > [F-], and [Ca2+] > [NH4
+] > [K+] > [Na+] > [Mg2+]. Their values were different in these areas: the industrial area > the commercial and living area > the control area. As
for NH4
+, K+, Ca2+, NO3
- and SO
4
2-
, their seasonal average concentrations show a similar variation trend: the values in spring and fall were higher than those
in summer and winter. The seasonal average concentrations of [Cl-], [F-], [Na+] and [Mg2+] are much lower than those of other ions. However, the concentrations of [Na+] changed more greatly in different seasons than those of the other three ions. Correlation coefficients showed that the three
areas have been polluted by coal smoke and dust to different extents, while some local resources of pollution should be taken
into consideration as well. 相似文献
39.
40.
保证Cd的高回收率以及彻底的Sn干扰去除是获得精确镉同位素组成的前提,目前报道的多种Cd分离与纯化方法获得的Cd回收率有较大差异(42.6%~99.8%),且去除Sn干扰的效果也不同(去除率在87.8%~97.4%之间),Cd回收率和Sn去除率均不理想。本文对前人报道的分离方法进行对比实验,发现0.1 mol/L氢溴酸-0.5 mol/L硝酸是分离Cd和Sn的有效试剂,增加该组混合酸的用量可淋洗出样品中更多的Sn且不会损失Cd,当混合酸的淋洗用量增加至30 mL时,Sn的淋洗率达到99.8%以上,Cd的回收率亦达到99.0%±0.5%,可满足土壤样品镉同位素的测定要求。本工作为获得高精度的镉同位素组成奠定了基础,为研究土壤环境中镉的污染来源提供了技术手段。 相似文献