碳酸钠浸取一紫外荧光光谱法测定地质样品中痕量铀     

刘金巍  王彦丽  杨金荣  罗治定  刘庆学 《岩矿测试》2007,(2)

地质样品经HF-HNO_3-HCl-HClO_4溶解后,用50 g/L碳酸钠溶液浸取分离,采用紫外荧光光谱法直接测定上清液的铀含量。浸取时间选择30 min,Fe、Zn、Ca、Co、Ni、Cu和Mn等元素留在残渣中不产生干扰。方法精密度(RSD,n=12)为3．37%～7．06%,检出限为0．009μg/g(进样量100μL)。方法参加区域地球化学考核样品的测试,合格率100%,适用于土壤、水系沉积物、岩石及Fe、Zn、Ca、Co、Ni、Cu和Mn含量较高的样品中痕量铀的测定。  相似文献   

用石灰改良高速铁路路基黄土填料化学机理分析     

王先龙 《岩土工程技术》2007,21(6):319-323

通过分析某高速铁路客运专线路基黄土填料土质改良试验成果,对采用石灰改良黄土的化学机理进行了分析探讨,指出经过改良的黄土能够作为高速铁路路基的填料,土质改良试验的主要任务是确定经济合理的配合比及最佳含水量。  相似文献   

华北克拉通破坏的物理、化学过程:地幔橄榄岩证据   总被引：1，自引：0，他引：1  

郑建平  路凤香  余淳梅  汤华云  张志海  储玲林 《矿物岩石地球化学通报》2007,26(4):327-335

本文对比了华北东部不同时代、不同位置捕虏体/地质体橄榄岩的地幔属性,讨论了华北克拉通破坏的物理、化学过程。结果表明,拆沉作用不能很好地解释古老难熔、过渡型和新生饱满地幔并存的事实;单纯的熔体-橄榄岩相互作用也不易解释中、新生代岩石圈巨大减薄和新生饱满地幔Cpx中LREE亏损现象,即具复杂演化历史的克拉通地幔向演化历史简单的"大洋型"岩石圈的转换。华北东部克拉通破坏作用包括地幔伸展、熔-岩作用、侵蚀置换等复杂的物理、化学过程。岩石圈先大幅减薄、后小幅增厚实现了最终的地幔置换和岩石圈整体减薄过程。喷发时代为100 Ma的阜新玄武岩所捕获的橄榄岩主体是饱满的,说明华北东部部分地区在此之前有过地幔置换作用。  相似文献   

小波包变换在面波分离中的应用     

张华  潘冬明  刘松 《物探与化探》2007,31(2):167-170

作为一种时频分解方法，小波包变换有着广泛的用途，它不仅优于小波变换，而且与传统Fourier变换相比，它能刻画出具有相同频率的有效波与面波在时间一空间域的分布，然后可以从中分离面波，再进行重构，即可得到分离面波后的结果，该方法在成功分离面波的同时，可使有效波的能量（尤其是其低频能量）损失减小，有效地保持信号的频宽不变，提高记录的信噪比。实际资料的处理结果表明，此方法在分离面波方面具有良好的效果。  相似文献   

冀东铁精矿的物化性能测试   总被引：1，自引：0，他引：1  

亢立明李福民  刘曙光吕庆 《岩矿测试》2007,26(3):201-204

对冀东铁精矿进行了系统的物化性能测试。结果表明，铁精矿粒度较粗、颗粒表面光滑、比表面积小、SiO2含量较高。结合矿相结构分析了冀东铁精矿成球性能比较差的原因。采用3％的优质膨润土作铁精矿球团的黏结剂，制得球团的性能能够满足生产要求。  相似文献   

库布齐沙漠颗粒物中磷的化学形态分析     

李北罡  郭博书 《岩矿测试》2007,26(1):9-12

采用7步连续浸提法对库布齐沙漠响沙湾沙粒中磷的各种存在形态进行了分析测定，并对沙粒样进行了分级形态研究。结果表明：在库布齐沙漠响沙湾沙粒中总磷（TP）的含量为137．21～362．09μg／g，其主要成分为无机磷（IP），平均占TP的比例为94．60％；而有机磷（Or—P）的含量为7．88～19．12μg／g，平均占TP的5．40％。在所有不同粒度的沙样中，自生钙结合磷（Ca—P）含量最高，占TP的58．95％～80．05％，其次是原生碎屑磷（De—P）。占TP的8．13％～30．22％，二者占IP的绝大部分；其他各形态磷含量的高低顺序为：有机磷（Or—P）〉吸附态磷（Ads—P）〉铁结合态磷（Fe—P）〉闭蓄态磷（Obs—P）〉铝结合态磷（AI—P）。在所取沙漠颗粒物样中TP、Ca—P、De—P、Or—P、AI—P各自的含量都是随颗粒物粒度的减小而增大，而Ads—P含量则相反；Fe—P、Obs—P的含量受颗粒物粒度变化的影响不大。  相似文献   

双墩彩陶颜料来源的测试研究     

董俊卿  冯敏  王昌燧  王洪敏  阚绪杭 《岩矿测试》2007,26(1):13-16

利用激光拉曼光谱、X射线衍射和波长色散X射线荧光光谱等方法对安徽蚌埠双墩遗址出土的5片彩陶和两块红色矿料进行测试分析，明确了彩陶红彩的主要物相为赤铁矿、α-石英、白云石和方解石；黑彩未使用矿物颜料，而是利用渗碳工艺中炭黑的自然效果。同时证明了综合利用这三种测试方法对于考古样品物相鉴定与成分分析的有效性。  相似文献   

Equilibration Scales in Silicic to Intermediate Magmas Implications for Experimental Studies   总被引：5，自引：0，他引：5  

Pichavant  Michel; Costa  Fidel; Burgisser  Alain; Scaillet  Bruno; Martel  Caroline; Poussineau  Stephane 《Journal of Petrology》2007,48(10):1955-1972

Experimental phase equilibrium studies are increasingly beingused for the determination of intensive variables (P, T, fH₂O,fO₂ ) in silicic to intermediate magmas. In contrast, silicicigneous bodies are now perceived as open, periodically recharged,systems involving only limited chemical equilibration. Thus,the use of laboratory-determined crystal–liquid equilibriumdata needs clarification. Here we review the field, petrologicaland geochemical evidence concerning states and scales of chemicalequilibrium in silicic magma bodies. It is concluded that totalchemical equilibrium is generally not the rule. However, a subsystemin local equilibrium (the reactive magma) can be identified.Equilibration scales in silicic magmas are rate-limited eitherby diffusive flux in crystals (DICL regime) or by diffusiveflux in the melt (MD regime). The recognition that equilibriumin magmas is limited to a reactive subsystem requires phaseequilibrium studies to be chemically scaled. Experiments, eitherof total or partial equilibrium type, should aim at a closereproduction of equilibrium states specific to natural systems.The laboratory reconstruction of the natural equilibrium statesguarantees a precise determination of the pre-eruptive parametersand a reliable application of the experimental data to activevolcanic systems. KEY WORDS: silicic magmas; chemical equilibrium; timescales; experimental studies  相似文献   

Manganese metalliferous sediments of the Deryugin Basin (Sea of Okhotsk): Chemical composition and geological setting     

A. S. Astakhov  V. V. Sattarova  A. I. Svininnikov  N. V. Astakhova  M. M. Domanov  M. V. Ivanov 《Russian Journal of Pacific Geology》2007,1(5):418-434

This paper reports the results of an investigation of the chemical composition and distribution of manganese-rich metalliferous sediments in the Deryugin Basin. They compose an upper sedimentary layer up to 30 cm thick within a strip up to 40 km wide and 180 km long in the central part of the basin along the East Deryugin suture zone bounding the Deryugin sedimentary basin to the east. The sediments are enriched relative to the regional background composition in Mn (by a factor of 35); Au; Ni; Zn; Co (by a factor of 3–5); and, locally, in Mo, V, Ba, Cu, Pb, and Hg. It was supposed that their formation was controlled by several processes: precipitation of Mn and some other trace elements from hydrothermal plumes of seawater that occasionally form above submarine hot vents in the northern part of the basin, precipitation from anoxic bottom waters at the eastern boundary of the Deryugin sedimentary basin, and early diagenetic migration of Mn into the surface sediments.  相似文献   

Sodic metasomatism in a dacite weathering profile in Pinxiang, Guangxi, China     

GU Shangyi WAN Guojiang MAO Jianquan 《中国地球化学学报》2007,26(4):434-438

The Pinxiang weathering profile is well developed on Early Triassic dacite lavas of the Baisi Formation. At the top of the profile is developed a red clay zone which is characterized mineralogically by kaolinite, iron oxide minerals, quartz, and a small amount of illite, montmorillonite and vermiculite. In going downwards the red clay zone gives way to a saprolite zone in which plagioclase pseudomorphs have been well preserved although replaced by kaolinite. Beneath the saprolite zone is the saprock zone characterized by less weathering for dacite. At the bottom of the weathering profile is the parent material, dacite, which is composed mainly of plagioclase, quartz, K-feldspar and biotite which have been largely altered into chlorite owing to submarine extrusion of dacite lavas. Some layers in the weathering profile show obvious sodium enrichment and potassium depletion relative to others. In the Al2O3-(CaO* Na2O)-K2O triangular diagram, the weathering trends of these layers in the middle stage are remarkably deviated from normal ones. Both mineralogy and micro-morphology of these layers indicate such deviation resulted from sodic metasomatism of orthoclase.  相似文献