煤层气在煤储层中的扩散及其影响因素   总被引：4，自引：0，他引：4  

曹成润  牛伟  张遂安  霍永忠  陈秀艳  孙英男 《世界地质》2004,23(3):266-269

煤层气在煤储层中的扩散是指从煤基质孔隙表面上解吸的煤层气运移到割理系统的主要过程。发生扩散的前提条件是气体浓度差的出现，衡量扩散能力大小的重要参数是扩散系数。前者为由解吸速度、解吸气量和煤层气产量、井孔压力降等因素控制的动态参数，而后者为主要受扩散物质性质、扩散介质特征、扩散系统的温度、压力和孔隙结构形态等因素影响的静态参数。煤层气在煤储层中的扩散量与煤层气浓度差和扩散系数呈正比关系。  相似文献   

时域瞬变场电磁场有限差分法   总被引：1，自引：2，他引：1  

徐凯军  李桐林 《世界地质》2004,23(3):301-305

模拟电磁场在地下介质中的传播规律是理解地下介质响应的重要手段，直接应用有限差分法在时间域对二维、三维瞬变场进行数值分析是一种有效方法。应用反映电磁场基本规律的麦克斯韦方程组，导出时域场量的齐次扩散方程，对所研究的空间区域作差分离散，源作为初始条件加入，采用合适的边界条件，利用差分方程进行计算，从而得到场量的数值结果，展现瞬变场在地下随时间扩散的全过程，对电磁场的瞬态响应有更加直观的了解。  相似文献   

吉林市第二松花江江段污染物-NH4+分布特征研究     

肖长来  兰盈盈  梁秀娟  盛洪勋  刘耀莹  王德成 《世界地质》2004,23(4):382-385,396

针对吉林市铁合金厂排污口下游江水的污染情况，设计研究江段，分段、分层取样。通过野外与室内实验，分析研宄了江水污染物的主要成分，并对NH4^ 的纵向、横向、垂向上的分布特征及其影响因素进行了详细研究。结果表明，垂直方向污染物扩散可以瞬时完成，在极短的时间内基本能达到完全混合；在横向和纵向上，岸边排放污染物一般只在近岸扩散，污染范围一般也只在靠近排污口一带；随着离排污口距离增大，污染物浓度降低，横向变化率较纵向大。本研究为排污口的污染物控制与治理、水资源保护提供了科学依据。  相似文献   

水质大涡模拟数学模型研究   总被引：2，自引：0，他引：2       下载免费PDF全文

张昌兵  熊朝坤  桂林  刘华  莫政宇 《水科学进展》2004,15(4):431-435

建立了基于弱可压缩流基础上的水质大涡模拟数学模型及污染物质扩散系数与平均运动的关系。数值计算采用有限体积法和预测校正法,固壁边界条件采用"部分滑移条件"。并应用该模型对重庆嘉陵江、长江两江交汇段的流场,污染物质浓度分布进行了计算,计算结果与实测值比较吻合。研究表明,横向扩散与流动状态有关,当支流流量相对较小时,横向扩散较弱,形成岸边污染带,当支流流量相对较大时,横向扩散较强,污染带向江心移动。  相似文献   

High-pressure experimental growth of diamond using C–K₂CO₃–KCl as an analogue for Cl-bearing carbonate fluid     

Emma Tomlinson  Adrian Jones  Judith Milledge 《Lithos》2004,77(1-4):287-294

High-pressure, high-temperature diamond growth experiments have been conducted in the system C–K₂CO₃–KCl at 1050–1420 °C, 7.0–7.7 GPa. KCl is of interest because of the strong effect of halogens on the phase relations of carbonate-rich systems [Geophys. Res. Lett. 30 (2003) 1022] and because of the occurrence of KCl coexisting with alkali silicate–carbonate fluids in natural-coated diamond [Geochim. Cosmochim. Acta 64 (2000) 717]. We have used system C–K₂CO₃–KCl as an analogue for these mantle fluids in diamond growth experiments. The presence of KCl reduces the potassium carbonate liquidus to ≤1000 °C at 7.7 GPa, allowing it to act as a solvent catalyst for diamond growth at temperatures below the continental geotherm. This is a reduction on the minimum diamond growth temperature reported in the alkali-carbonate–C–O–H system [Lithos 60 (2002) 145]. Diamond growth using carbonate solvent catalysts is characterised by a relatively long induction period. However, the addition of KCl also reduced the period for diamond growth in carbonate to 5 min; no such induction period appears to be necessary. It is suggested that KCl destabilises carbonate, allowing greater solubility and diffusion of carbon.  相似文献   

Postglacial topographic evolution of glaciated valleys: a stochastic landscape evolution model   总被引：1，自引：0，他引：1  

Simon J. Dadson  Michael Church 《地球表面变化过程与地形》2005,30(11):1387-1403

The retreat of valley glaciers has a dramatic effect on the stability of glaciated valleys and exerts a prolonged influence on the subsequent fluvial sediment transport regime. We have studied the evolution of an idealized glaciated valley during the period following retreat of ice using a numerical model. The model incorporates a stochastic process to represent deep‐seated landsliding, non‐linear diffusion to represent shallow landsliding and an approximation of the Bagnold relation to represent fluvial sediment transport. It was calibrated using field data from several recent surveys within British Columbia, Canada. We present ensemble model results and compare them with results from a deterministic linear‐diffusion model to show that explicit representation of large landslides is necessary to reproduce the morphology and channel network structure of a typical postglacial valley. Our model predicts a rapid rate of fluvial sediment transport following deglaciation with a subsequent gradual decline, similar to that inferred for Holocene time. We also describe how changes in the model parameters affect the estimated magnitude and duration of the paraglacial sediment pulse. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Evolution of the Magma Chamber beneath Usu Volcano since 1663: a Natural Laboratory for Observing Changing Phenocryst Compositions and Textures   总被引：2，自引：1，他引：2  

TOMIYA  AKIHIKO; TAKAHASHI  EIICHI 《Journal of Petrology》2005,46(12):2395-2426

We have investigated the evolution of an active silicic magma-feedingsystem beneath Usu volcano, Japan, where eight eruptions havebeen recorded since AD 1663. All magmatic products contain similartypes of plagioclase and orthopyroxene phenocrysts that consistof homogeneous cores with uniform compositions, and a zonedmantle that increases in size with time. The compositions ofplagioclase and orthopyroxene phenocrysts vary gradually andregularly with time, as do the bulk-rock compositions. The textureof these phenocrysts also changes systematically, caused byprogressive crystal growth, dissolution and diffusion. On thebasis of these observations, we conclude that the same magma-feedingsystem has persisted at Usu volcano since AD 1663. Compositionalvariation of magnetite phenocrysts differs from that of plagioclaseand orthopyroxene, because magnetite has large diffusion coefficientsand should represent magmatic conditions immediately beforethe eruption. Most pumices from Usu volcano contain two typesof magnetite phenocryst, each with a different composition andcrystallization temperature, indicating that two magmas mixedbefore each eruption (approximately several days before). Theend-members changed with time: rhyolite + basaltic andesite(1663); dacite ± rhyolite (1769, 1822, 1853); dacite± dacite (1977, 2000). The temperature of the magma apparentlyincreases with time, and the increase can be explained by sequentialtapping from a magma chamber with a thermal and chemical gradientin addition to injection of high-temperature magma. KEY WORDS: continuous existence of magma chamber; dacite; dissolution and diffusion of phenocrysts; magma mixing; magnetite  相似文献   

Plastic Deformation and Recrystallization of Garnet: A Mechanism to Facilitate Diffusion Creep   总被引：5，自引：0，他引：5  

STOREY  C. D.; PRIOR  D. J. 《Journal of Petrology》2005,46(12):2593-2613

Elongate and deformed garnets from Glenelg, NW Scotland, occurwithin a thin shear zone transecting an eclogite body that hasundergone partial retrogression to amphibolite facies at circa700°C. Optical microscopy, back-scattered electron imaging,electron probe microanalysis and electron back-scatter diffractionreveal garnet sub-structures that are developed as a functionof strain. Subgrains with low-angle misorientation boundariesoccur at low strain and garnet orientations are dispersed, aroundrational crystallographic axes, across these boundaries. Towardshigh-strain areas, boundary misorientations increase and thereis a loss of crystallographic control on misorientations, whichtend towards random. In high-strain areas, a polygonal garnetmicrostructure is developed. The garnet orientations are randomlydispersed around the original single-crystal orientation. Somegarnet grains are elongate and Ca-rich garnet occurs on thefaces of elongate grains oriented normal to the foliation. Commonly,the garnet grains are admixed with matrix minerals, and, wherein contact with other phases, garnet is well faceted. We suggestthat individual garnet porphyroclasts record an evolution fromlow-strain conditions, where dislocation creep and recoveryaccommodated deformation, through increasing strain, where dynamicrecrystallization occurred by subgrain rotation, to higheststrains, where recrystallized grains were able to deform bydiffusion creep assisted grain boundary sliding with associatedrotations. KEY WORDS: diffusion creep; EBSD; garnet; plastic deformation; recrystallization  相似文献   

水文重力效应改正中一维地下水模拟算法的对比     

贺前钱  孙和平 《大地测量与地球动力学》2018,38(5):529-532

基于一维地下水渗透方程详细推导其有限差分解算过程，引入不同于显式差分的隐式差分和中心差分格式，对比分析不同差分格式对地下水模拟结果及其相应地下水重力效应的影响，并对其中的层间参数取值和非线性方程的线性化问题进行探讨。结果表明，在日本Isawa扇形地区超导台站，不同层间参数加权公式能够引起最大约0.15 μGal的重力效应差异，影响在1.9%以内；不同差分格式和线性化方法组合形式能够引起最大约0.12 μGal的重力效应差异，影响在1.5%以内。  相似文献   

Intergranular diffusion rates from the analysis of garnet surfaces: Implications for metamorphic equilibration          下载免费PDF全文

Tim J. Dempster  Shona Symon  Peter Chung 《Journal of Metamorphic Geology》2017,35(6):585-600

Novel approaches to garnet analysis have been used to assess rates of intergranular diffusion between different matrix phases and garnet porphyroblasts in a regionally metamorphosed staurolite‐mica‐schist from the Barrovian‐type area in Scotland. X‐ray maps and chemical traverses of planar porphyroblast surfaces reveal chemical heterogeneity of the garnet grain boundary linked to the nature of the adjacent matrix phase. The garnet preserves evidence of low temperature retrograde exchange with matrix minerals and diffusion profiles documenting cation movement along the garnet boundaries. Garnet–quartz and garnet–plagioclase boundaries preserve evidence of sluggish Mg, Mn and Fe diffusion at comparable rates to volume diffusion in garnet, whereas diffusion along garnet–biotite interfaces is much more effective. Evidence of particularly slow Al transport, probably coupled to Fe³⁺ exchange, is locally preserved on garnet surfaces adjacent to Fe‐oxide phases. The Ca distribution on the garnet surface shows the most complex behaviour, with long‐wavelength heterogeneities apparently unrelated to the matrix grain boundaries. This implies that the Ca content of garnet is controlled by local availability and is thought likely to reflect disequilibrium established during garnet growth. Geochemical anomalies on the garnet surfaces are also linked to the location of triple junctions between the porphyroblasts and the matrix phases, and imply enhanced transport along these channels. The slow rates of intergranular diffusion and the characteristics of different boundary types may explain many features associated with the prograde growth of garnet porphyroblasts. Thus, minerals such as quartz, Fe‐oxides and plagioclase whose boundaries with garnet are characterized by slow intergranular diffusion rates appear to be preferentially trapped as inclusions within porphyroblasts. As such grain boundary diffusion rates may be a significant kinetic impediment to metamorphic equilibrium and garnet may struggle to maintain chemical and textural equilibrium during growth in pelites.  相似文献