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11.
根据Taylor的湍流扩散理论和Hay、Pasquill提出的拉格朗日流和欧拉流的相关函数的相似性,用黄河三角洲埕北海域的实测资料,按四种不同方案计算出该海域的水平扩散系数和谱密度分布。指出:该海区潮流扩散系数主要受潮流的影响,其分布特征与潮流的分布基本一致,所求的水平扩散系数主要是由周期性的潮运动给予潮流扰动所致。方案4是通过富氏变换滤波消去了周期性潮流扰动,本方案计算的水平扩散系数是由周期为6h以下的小尺度涡提供能量。 相似文献
12.
Lars Chresten Lund-Hansen Morten Pejrup Jens Valeur Anders Jensen 《Estuarine, Coastal and Shelf Science》1994,38(6)
Gross sedimentation rates (GSR) have been measured using sediment traps placed at nine different levels above the bed (0·3, 0·5, 0·8, 1·0, 2·0, 4·0, 6·0, 8·0 and 10·0 m). The sediment traps were deployed for 1·25 years and recovered 28 times during the study period. Low average GSR values of 5·5 g m-2 day-1 were obtained at 10·0 m, and high average GSR values of 114·8 g m-2 day-1 were obtained at 0·3 m. An expression for the eddy diffusion coefficient of suspended particulate matter (Ks), based on the measured GSR is given. The expression has been used for modelling of Ks at the different trap levels above the bed. High values (≈42 cm2 s-1) of Ks were obtained at the upper traps, whereas low values (≈2 cm2 s-1) were obtained near the bed. Comparison between level of turbulent energy in terms of shear stress at the boundaries of the water column, i.e. from the wind and the bed flow, showed that wind energy exceeded that of the bed flow by a factor 16. At 5·0 m Ks was positively correlated (r=0·66) to the eddy diffusion coefficient of momentum (Km) derived from the wind energy transfer to the water, giving an average β of 0·5 for Ks =βKm. The density difference between surface and bottom waters has been designated a parameter of stratification, and is discussed in relation to variations of Ks and Km . 相似文献
13.
本文考虑一维扩散方程的反问题,利用变分同化方法通过观测资料来确定方程中的未知初值,通过分析观测误差对于初值误差的影响,证明变分同化初值收敛于原问题的真实参数,并得到了参数的收敛精度。同时将得到的初值代入预报模式中,得到预报解,并分析了预报解的收敛性和预报误差。 相似文献
14.
用矩阵方法,求解McCreary和Fickian铅垂向湍扩散形式下,无界海洋条件时在风应力和深层浮力作用下的线性解。得出不同的湍扩散系数A情况下McCreary与Fickian湍扩散形式的流场结构。指出随湍扩散系数的增加,McCreary和Fickian湍扩散形式下u分量结构及其量值差异增大。在Fickian湍扩散形式下,能量穿越密度跃层的传递能力较强。当A=0.1cm~2s~(-3)时,在风应力和深层浮力作用下两种湍扩散形式造成流场的差异很小。提出在小湍扩散系数下,用McCreary湍扩散形式研究热带海洋环流,其结果和Fickian形式应相当一致。 相似文献
15.
16.
An in situ method of estimating the effective diffusion coefficient for a chemical constituent that diffuses into the primary porosity of a rock is developed by abruptly changing the concentration of the dissolved constituent in a borehole in contact with the rock matrix and monitoring the time-varying concentration. The experiment was conducted in a borehole completed in mudstone on the campus of the University of the Free State in Bloemfontein, South Africa. Numerous tracer tests were conducted at this site, which left a residual concentration of sodium chloride in boreholes that diffused into the rock matrix over a period of years. Fresh water was introduced into a borehole in contact with the mudstone, and the time-varying increase of chloride was observed by monitoring the electrical conductivity (EC) at various depths in the borehole. Estimates of the effective diffusion coefficient were obtained by interpreting measurements of EC over 34 d. The effective diffusion coefficient at a depth of 36 m was approximately 7.8×10?6 m2/d, but was sensitive to the assumed matrix porosity. The formation factor and mass flux for the mudstone were also estimated from the experiment. 相似文献
17.
Neal T. Skipper Peter A. Lock James O. Titiloye Jan Swenson Zakaria A. Mirza W. Spencer Howells Felix Fernandez-Alonso 《Chemical Geology》2006,230(3-4):182-196
The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH3OD and (CH2OD)2 in deuterated clay allows us to measure the diffusion of the CH3- and CH2-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution. 相似文献
18.
含水矿物在真空下的释Ar机制:Ar-Ar热年代学面临的新问题 总被引:2,自引:0,他引:2
地质体的实际情况、激光显微探针束研究、XRD和SEM观测以及真空加热下Ar的释放特征都表明体积扩散不是含水矿物在真空加热中释放Ar的唯一机制。在低温下 ,Ar的释放主要受由缺陷引起的短程扩散和体积扩散共同作用的多途径扩散机制制约 ;而在高温下 ,由于含水矿物在真空中不够稳定 ,Ar的释放受到脱羟基、脱氢、氧化反应、分层作用等造成的晶体结构改变的强烈影响。含水矿物在高温下的氧化分解会导致矿物中原始Ar浓度梯度的均一化 ,因而无法得到真实的Ar分布剖面 ,也无法据此计算矿物的封闭温度 ,并进而可能影响到ArAr年龄坪的地质意义。 相似文献
19.
地震次生毒气泄漏与扩散的数值模拟与动态仿真 总被引:16,自引:1,他引:16
文章对破坏性地震中可能发生的次生毒气泄漏与扩散灾害进行了数值模拟与动态仿真研究,设定了几种有实际意义的数值分析模型,分别进行了结构地震破坏,有毒有害气体泄漏,在一定泄漏和气象条件下的向周围空间扩散的动态仿真研究,给出了典型毒气扩散过程中可致人员死亡,严重危险和有感区域的范围的动态变化结果,作者认为地震次生毒气泄漏与扩散研究对大地震应急、城市和大型企业防灾都有重要的意义和广阔的应用前景。 相似文献
20.