From an initial transient-state to a steady-state in metamorphic reactions: An experimental approach in the system dolomite-quartz-H₂O     

Tadao  Nishiyama  Aiko  Tominaga  Hiroshi  Isobe 《Island Arc》2007,16(1):16-27

Abstract We carried out hydrothermal experiments in the system dolomite‐quartz‐H₂O to track the temporal change in reaction rates of simultaneous reactions during the development of reaction zones. Two types of configurations for the starting materials were prepared: dolomite single crystals + quartz powder + water and quartz single crystals + dolomite powder + water, both sealed separately in gold capsules. Runs at 0.1GPa and 600°C with cold seal pressure vessels gave the following results. (i) In short duration (45–71 h) runs metastable layer sequences involving wollastonite and talc occur in the reaction zone, whereas they disappear in longer duration (168–336 h) runs. (ii) The layer sequence of the reaction zones in short duration runs differs from place to place on the dolomite crystal even in the same run. (iii) The diversity of layer sequences in the short duration runs merges into a unique layer sequence in the longer duration runs. (iv) The reaction zone develops locally on the dolomite crystal, but no reaction zone was observed on the quartz crystal in any of the runs. The lines of evidence (i)–(iii) show that the system evolves from an initial transient‐ to a steady‐state and that the kinetic effect is important in the development of reaction zones. A steady diffusion model for the unique layer sequence Qtz/Di/Fo + Cal/Dol + Cal/Dol shows that the Dol + Cal layer cannot be formed by diffusion‐controlled process and that the stability of the layer sequence Qtz/Di/Fo + Cal/Dol depends not only on L‐ratios (a = /L_CaOCaO and b = /L_MgOMgO) but also on the relative rate P = (−2ξ₁ − ξ₂)/(–ξ₁ − 2ξ₂) of competing reactions: Dol + 2Qtz = Di + 2CO₂ (ξ₁) and 2Dol + Qtz = Fo + 2Cal + 2CO₂ (ξ₂). For smaller P the stability field will shift to higher values of a and b. The steady diffusion model also shows that the apparent‐non‐reactivity on the quartz surface can be attributed to void formation in a large volume fraction in the diopside layer.  相似文献   

Numerical estimation of effective diffusion coefficients for charged porous materials based on micro-scale analyses     

Arash Mohajeri  Guillermo A. Narsilio  Peter Pivonka  David W. Smith 《Computers and Geotechnics》2010

In order to describe diffusive transport of solutes through a porous material, estimation of effective diffusion coefficients is required. It has been shown theoretically that in the case of uncharged porous materials the effective diffusion coefficient of solutes is a function of the pore morphology of the material and can be described by the tortuosity (tensor) (Bear, 1988 [1]). Given detailed information of the pore geometry at the micro-scale the tortuosity of different materials can be accurately estimated using homogenization procedures. However, many engineering materials (e.g., clays and shales) are characterized by electrical surface charges on particles of the porous material which strongly affect the (diffusive) transport properties of ions. For these type of materials, estimation of effective diffusion coefficients have been mostly based on phenomenological equations with no link to underlying micro-scale properties of these charged materials although a few recent studies have used alternative methods to obtain the diffusion parameters (Jougnot et al., 2009; Pivonka et al., 2009; Revil and Linde, 2006 2, 3 and 4). In this paper we employ a recently proposed up-scaled Poisson–Nernst–Planck type of equation (PNP) and its micro-scale counterpart to estimate effective ion diffusion coefficients in thin charged membranes. We investigate a variety of different pore geometries together with different surface charges on particles. Here, we show that independent of the charges on particles, a (generalized) tortuosity factor can be identified as function of the pore morphology only using the new PNP model. On the other hand, all electro-static interactions of ions and charges on particles can consistently be captured by the ratio of average concentration to effective intrinsic concentration in the macroscopic PNP equations. Using this formulation allows to consistently take into account electrochemical interactions of ions and charges on particles and so excludes any ambiguity generally encountered in phenomenological equations.  相似文献   

扩散法——EA-IRMS测定天然水体铵态氮同位素实验条件研究   总被引：2，自引：0，他引：2  

胡婧  刘卫国 《矿物岩石地球化学通报》2010,29(1):31-37

稳定氮同位素是研究氮循环和氮污染源示踪的一个有效手段。然而目前国内对水体中铵态氮同位素测定方法研究较少,限制了水体氮循环和污染机理的深入探讨。本文采用改进的扩散法(EA-IRMS)测定水中铵态氮同位素,探讨了样品制备过程中扩散溶液的体积、浓度和扩散时间对回收率及氮同位素测定值的影响。实验得出最佳扩散条件为:1.50 mg/L氯化铵溶液400 mL扩散14天,回收率大于95%,且不会产生氮同位素分馏。本研究为高精度测定天然水体中铵态氮同位素提供了更可靠的实验条件。  相似文献   

Electrodynamic Disaggregation: Does it Affect Apatite Fission-Track and (U-Th)/He Analyses?     

Jörg Giese  Diane Seward  Finlay M. Stuart  Eliane Wüthrich  Edwin Gnos  Daniel Kurz  Urs Eggenberger  Guido Schreurs 《Geostandards and Geoanalytical Research》2010,34(1):39-48

Apatite fission-track and (U-Th)/He analyses require the liberation of intact idiomorphic apatite grains from rock samples. While routinely being carried out by mechanical methods, electrodynamic disaggregation (ED) offers an alternative approach. The high-voltage discharges produced during the ED process create localised temperature peaks (10000 K) along a narrow plasma channel. In apatite, such high temperatures could potentially reduce the length of fission tracks, which start to anneal at temperatures > 60 °C, and could also enhance He diffusion, which becomes significant at 30–40 °C over geological time scales. A comparison of fission-track analyses and (U-Th)/He ages of apatites prepared both by mechanical (jaw crusher, disk mill) and ED processing provides a way of determining whether heating during the latter method has any significant effect. Apatites from three samples of different geological settings (an orthogneiss from Madagascar, the Fish Canyon Tuff, and a muscovite-gneiss from Greece) yielded statistically identical track length distributions compared to samples prepared mechanically. Additionally, (U-Th)/He ages of apatites from a leucogranite from Morocco prepared by both methods were indistinguishable. These first results indicated that during electrodynamic disaggregation apatite crystals were not heated enough to partially anneal the fission tracks or induce significant diffusive loss of He.  相似文献   

Radium-traced nutrient outwelling from the Subei Shoal to the Yellow Sea: Fluxes and environmental implication     

Jian’an Liu  Dongyan Liu  Jinzhou Du 《海洋学报(英文版)》2022,41(6):12-21

The Subei Shoal is the largest sandy ridge in the southern Yellow Sea and is important source for nutrient loading to the sea. Here, the nutrient fluxes in the Subei Shoal associated with eddy diffusion and submarine groundwater discharge（SGD） were assessed to understand their impacts on the nutrient budget in the Yellow Sea. Based on the analysis of 223 Ra and 224 Ra in the field observation, the offshore eddy diffusivity mixing coefficient and SGD were estimated to be 2.3×10⁸ cm  相似文献   

农业技术扩散中的农户采用行为研究:国外进展与国内趋势   总被引：3，自引：0，他引：3  

龙冬平  李同昇  于正松 《地域研究与开发》2014,(5)

农户是我国农区的微观经济单元,是农业技术采用的行为主体。以农户为对象的农业技术扩散采用行为的研究对于诱导农户行为、提高农业技术的采用效率、促进农区发展具有重要的理论和应用价值。从研究视角、研究方法、研究内容3个方面对国内外相关研究成果进行较为系统的梳理,总结评述最新进展和特点,并在此基础上对农户技术采用行为的研究趋势进行展望,希冀有助于推进国内对农户技术采用行为的深入研究,进而为促进农业技术扩散与推广、提高农业科技成果转化率提供参考。  相似文献   

绥中一次暴雪伴雷电天气过程的成因分析     

孟振雄  于亚薇  唐帅 《内蒙古气象》2014,(1):7-11

为了探讨绥中一次暴雪伴雷电天气过程的成因,利用常规观测资料、NCEP每6h间隔的1°×1°的再分析资料和营口多普勒雷达的资料,分析此过程的天气形势特点、高低空急流的作用、雷达回波的特征及反映动力、热力和水汽条件的相关物理量场的特征。结果发现:雷电发生在对流层中层的西南风急流和底层偏东风均处在最强的时刻,当对流云团发展到-20℃温度层时,温差起电产生雷电;雷电发生在低层850hPa附近存在的逆温层消失之后,同时配合低层水汽的辐合,产生了暴雪天气;雷电和强降雪发生在大气底层南风和北风转换的过程中,强降雪的时间与冷空气扩散加强的时间比较一致,当冷空气扩散到整个大气底层时强降雪结束;引起雷电和强降雪的对流不稳定层结主要处在对流层中层,并为上升运动的发生提供了动力和热力条件,促使雷电发生和强降雪的维持。  相似文献   

Energetics of lateral eddy diffusion/advection：Part Ⅱ. Numerical diffusion/diffusivity and gravitational potential energy change due to isopycnal diffusion   总被引：1，自引：1，他引：0  

HUANG Rui Xin 《海洋学报(英文版)》2014,33(3):19-39

Study of oceanic circulation and climate requires models which can simulate tracer eddy diffusion and ad vection accurately. It is shown that the traditional Eulerian coordinates can introduce large artificial hori zontal diffusivity/viscosity due to the incorrect alignment of the axis. Therefore, such models can smear sharp fronts and introduce other numerical artifacts. For simulation with relatively low resolution, large lateral diffusion was explicitly used in models; therefore, such numerical diffusion may not be a problem. However, with the increase of horizontal resolution, the artificial diffusivity/viscosity associated with hori zontal advection in the commonly used Eulerian coordinates may become one of the most challenging ob stacles for modeling the ocean circulation accurately. Isopycnal eddy diffusion （mixing） has been widely used in numerical models. The common wisdom is that mixing along isopycnal is energy free. However, a careful examination reveals that this is not the case. In fact, eddy diffusion can be conceptually separated into two steps： stirring and subscale diffusion. Due to the thermobaric effect, stirring, or exchanging water masses, along isopycnal surface is associated with the change of GPE in the mean state. This is a new type of instability, called the thermobaric instability. In addition, due to cabbeling subscale diffusion of water parcels always leads to the release of GPE. The release of GPE due to isopycnal stirring and subscale diffusion may lead to the thermobaric instability.  相似文献   

The Characteristics of Atmospheric Ice Nuclei Measured at Different Altitudes in the Huangshan Mountains in Southeast China简   总被引：3，自引：0，他引：3  

JIANG Hui  YIN Yan  YANG Lei  YANG Shaozhong  SU Hang  and CHEN Kui 《大气科学进展》2014,31(2):396-406

The concentration of ice nuclei （IN） and the relationship with aerosol particles were measured and analyzed using three 5-L mixing cloud chambers and a static diffusion cloud chamber at three altitudes in the Huangshan Mountains in Southeast China from May to September 2011.The results showed that the mean total number concentration of IN on the highest peak of the Huangshan Mountains at an activation temperature （Ta） of-20℃C was 16.6 L-1.When the supersaturation with respect to water （Sw） and with respect to ice （Si） were set to 5％,the average number concentrations of IN measured at an activation temperature of-20℃C by the static diffusion cloud chamber were 0.89 and 0.105 L-1,respectively.A comparison of the concentrations of IN at three different altitudes showed that the concentration of IN at the foot of the mountains was higher than at the peak.A further calculation of the correlation between IN and the concentrations of aerosol particles of different size ranges showed that the IN concentration was well correlated with the concentration of aerosol particles in the size range of 1.2-20 μtm.It was also found that the IN concentration varied with meteorological conditions,such as wind speed,with higher IN concentrations often observed on days with strong wind.An analysis of the backward trajectories of air masses showed that low IN concentrations were often related to air masses travelling along southwest pathways,while higher IN concentrations were usually related to those transported along northeast pathways.  相似文献   

Climate policy innovation in the South – Domestic and international determinants of renewable energy policies in developing and emerging countries     

《Global Environmental Change》2014

This article attempts to disentangle the determinants of the adoption of renewable energy support policies in developing and emerging countries. By analyzing policies already implemented in industrialized countries, we focus on the diffusion but not the invention of climate-relevant policies. We look at four different types of policies (renewable energy targets, feed-in tariffs, other financial incentives and framework policies) and consider both domestic factors and international diffusion mechanisms utilizing a discrete-time events history model with a logit link on a self-compiled dataset of grid-based electricity policy adoption in 112 developing and emerging countries from 1998 to 2009. In general, we find stronger support for the domestic determinants of policy adoption, but also substantial influence of international factors. Countries with a larger population and more wealth have a higher probability of adopting renewable energy policies. Only in some specific cases do natural endowments for producing renewable energy encourage governments to adopt policies, and hydro power resources even correlate negatively with the adoption of targets. Among the international determinants, emulation from colonial peers and membership within the EU seem to facilitate policy adoption. International climate finance is less relevant, as the Global Environmental Facility and the Clean Development Mechanism may only increase the adoption of frameworks and targets, but they have no influence on tariffs and incentives.  相似文献